Green process for hydrogen production from cellulose derivative using visible light-harvesting function of Mg chlorophyll-a

2005 ◽  
Vol 7 (10) ◽  
pp. 742 ◽  
Author(s):  
Noriko Himeshima ◽  
Yutaka Amao
Author(s):  
Parul Verma ◽  
Ashish Singh ◽  
Faruk Ahamed Rahimi ◽  
Tapas Kumar Maji

Colocalization of essential molecular components in the solvated soft supramolecular assembly towards realizing visible-light-driven hydrogen evolution would be an exciting approach for sustainable energy by generating clean solar fuel. In...


2017 ◽  
Vol 53 (97) ◽  
pp. 13051-13054 ◽  
Author(s):  
H. AlGhamdi ◽  
K. Katsiev ◽  
A. K. Wahab ◽  
J. Llorca ◽  
H. Idriss

The conversion of infrared light to visible-light which allows a larger fraction of sunlight to be used is needed to improve light-harvesting.


RSC Advances ◽  
2014 ◽  
Vol 4 (105) ◽  
pp. 60626-60635 ◽  
Author(s):  
Sunil R. Kadam ◽  
Vivek R. Mate ◽  
Rajendra P. Panmand ◽  
Latesh K. Nikam ◽  
Milind V. Kulkarni ◽  
...  

Simultaneous photocatalytic hydrogen production (water splitting) and waste lignin (biomass) degradation under visible light has been demonstrated using C, N, S-doped ZnO/ZnS.


Author(s):  
Werner Kühlbrandt ◽  
Da Neng Wang ◽  
K.H. Downing

The light-harvesting chlorophyll-a/b protein complex (LHC-II) is the most abundant membrane protein in the chloroplasts of green plants where it functions as a molecular antenna of solar energy for photosynthesis. We have grown two-dimensional (2d) crystals of the purified, detergent-solubilized LHC-II . The crystals which measured 5 to 10 μm in diameter were stabilized for electron microscopy by washing with a 0.5% solution of tannin. Electron diffraction patterns of untilted 2d crystals cooled to 130 K showed sharp spots to 3.1 Å resolution. Spot-scan images of 2d crystals were recorded at 160 K with the Berkeley microscope . Images of untilted crystals were processed, using the unbending procedure by Henderson et al . A projection map of the complex at 3.7Å resolution was generated from electron diffraction amplitudes and high-resolution phases obtained by image processing .A difference Fourier analysis with the same image phases and electron diffraction amplitudes recorded of frozen, hydrated specimens showed no significant differences in the 3.7Å projection map. Our tannin treatment therefore does not affect the structural integrity of the complex.


2020 ◽  
Vol 16 ◽  
Author(s):  
Yuxue Wei ◽  
Honglin Qin ◽  
Jinxin Deng ◽  
Xiaomeng Cheng ◽  
Mengdie Cai ◽  
...  

Introduction: Solar-driven photocatalytic hydrogen production from water splitting is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. In this review, recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. In particular, the factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Background: Photocatalytic hydrogen evolution from water splitting using photocatalyst semiconductors is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. Methods: This review summarizes the recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation. Results: Recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. The factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Conclusion: The state-of-the-art CdS for producing hydrogen from photocatalytic water splitting under visible light is discussed. The future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are also described.


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