Improved detection of low vapor pressure compounds in air by serial combination of single-sided membrane introduction with fiber introduction mass spectrometry (SS-MIMS-FIMS)

The Analyst ◽  
2005 ◽  
Vol 130 (5) ◽  
pp. 679-686 ◽  
Author(s):  
Ismael Cotte-Rodríguez ◽  
Eric Handberg ◽  
Robert J. Noll ◽  
David P. A. Kilgour ◽  
R. Graham Cooks
1999 ◽  
Vol 77 (2) ◽  
pp. 243-248
Author(s):  
Komla Oscar Awitor ◽  
Laurent Bernard ◽  
Olivier Bonnin ◽  
Bernard Coupat ◽  
Jean Paul Fournier ◽  
...  

Mercurous chloride (Hg2Cl2), or calomel, was prepared by direct synthesis from commercial mercury and mercuric chloride. The mercuric chloride mass fraction in the synthesized material is particularly small. The mercurous chloride vapor pressure was measured between 353 and 453 K by the Knudsen cell method. In order to obtain the mercurous chloride vapor pressure, we took into account the dissociation in the vapor phase into mercury and mercuric chloride. Our results are compared with those in the literature.Key words: mercurous chloride, calomel, vapor pressure, mass spectrometry, Knudsen cell.


2005 ◽  
Vol 19 (4) ◽  
pp. 1548-1560 ◽  
Author(s):  
Sócrates Acevedo ◽  
Luis B. Gutierrez ◽  
Gabriel Negrin ◽  
Juan Carlos Pereira ◽  
Bernardo Mendez ◽  
...  

2012 ◽  
Vol 57 (2) ◽  
pp. 219-225 ◽  
Author(s):  
S. I. Lopatin ◽  
V. L. Stolyarova ◽  
V. G. Sevast’yanov ◽  
P. Ya. Nosatenko ◽  
V. V. Gorskii ◽  
...  

Radiocarbon ◽  
1986 ◽  
Vol 28 (2A) ◽  
pp. 186-190 ◽  
Author(s):  
Gert Hut ◽  
H Göte Östlund ◽  
Klaas van der Borg

With Fe powder as a catalyst, CO2 is completely converted to graphite within 90 minutes. The reaction proceeds at 650°C with an excess of H2. The reaction rate is enlarged by forced circulation and by keeping the water vapor pressure very low. The graphite samples obtained, consisting of 5mg of carbon, almost immediately produce stable 12C− currents of the order of 20–30μA in the sputter source of a Van de Graaff accelerator. The currents can be maintained for at least 10 hours and are comparable to those from commercial graphite. No memory effects in the preparation system have been observed.


1997 ◽  
Vol 32 (12) ◽  
pp. 1299-1304 ◽  
Author(s):  
R. C. Johnson ◽  
K. Koch ◽  
N. Kasthurikrishnan ◽  
W. Plass ◽  
J. S. Patrick ◽  
...  

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