Mixed alkylthiophene-based heterocyclic polymers containing oxadiazole units via electrochemical polymerisation: spectroscopic, electrochemical and spectroelectrochemical properties

2005 ◽  
Vol 29 (5) ◽  
pp. 707 ◽  
Author(s):  
Alexander S. FisyukPermanent address: Department ◽  
Renaud Demadrille ◽  
Claudia Querner ◽  
Malgorzata Zagorska ◽  
Joël Bleuse ◽  
...  
Keyword(s):  
Heterocyclic Polymers ◽  
Electrochemical Polymerisation ◽  
Spectroelectrochemical Properties

Synthesis and characterization of poly(pyrrole-co-2-nitrocinnamaldehyde) (PPNC), a new copolymer for solar cells applications

2019 ◽  
Vol 28 (4) ◽  
pp. 265-272 ◽  
Author(s):  
Hamou Gherras ◽  
Ahmed Yahiaoui ◽  
Aicha Hachemaoui ◽  
Abdelkader Belfedal ◽  
Abdelkader Dehbi ◽  
...  
Keyword(s):  
Proton Nuclear Magnetic Resonance ◽  
Synthesis And Characterization ◽  
Important Class ◽  
Visible Spectroscopy ◽  
Electrical Stability ◽  
Efficient Catalyst ◽  
Heterocyclic Polymers ◽  
Conjugated Copolymer ◽  
Aromatic Heterocyclic

The use of conductive polymers as a substitute for metallic conductors and semiconductors has attracted much attention in the literature. In particular, aromatic heterocyclic polymers constitute an important class since they possess chemical and electrical stability in both the oxidized (doped) and neutral (undoped) state. A series of poly(pyrrole- co-2-nitrocinnamaldehyde) were obtained via the condensation of pyrrole and 2-nitrocinnamaldehyde in chloroform using acid exchanged montmorillonite clay called maghnite-H+ as an efficient catalyst. The conjugated copolymer was characterized using proton nuclear magnetic resonance, ultraviolet–visible spectroscopy, Fourier transform infrared spectroscopy, and scanning electron microscopy.

Chemical and electrochemical polymerisation of pyrrole in the presence of N-substituted carbazoles

1999 ◽  
Vol 107 (1) ◽  
pp. 7-17 ◽  
Author(s):  
Esma Sezer ◽  
Belkis Ustamehmetoǧlu ◽  
A.Sezai Saraç
Keyword(s):  
Electrochemical Polymerisation

In Situ Generation of Heterocyclic Polymers by Triple‐Bond Based Polymerizations

2021 ◽  
pp. 2100524
Author(s):  
Xinnan Wang ◽  
Ting Han ◽  
Jacky W. Y. Lam ◽  
Ben Zhong Tang
Keyword(s):  
Triple Bond ◽  
Heterocyclic Polymers ◽  
In Situ Generation

Surface Attachment of Functional Peptides by Electrochemical Polymerisation

1996 ◽  
pp. 135-146
Author(s):  
Peter Heiduschka ◽  
Werner Beck ◽  
Wolfgang Kraas ◽  
Stefan Kienle ◽  
Günther Jung ◽  
...  
Keyword(s):  
Surface Attachment ◽  
Functional Peptides ◽  
Electrochemical Polymerisation

The electrochemical and spectroelectrochemical properties of metal free and metallophthalocyanines containing triazole/piperazine units

2016 ◽  
Vol 153 ◽  
pp. 478-487 ◽  
Author(s):  
Ümit Demirbaş ◽  
Duygu Akyüz ◽  
Arif Mermer ◽  
Hakkı Türker Akçay ◽  
Neslihan Demirbaş ◽  
...  
Keyword(s):  
Metal Free ◽  
Spectroelectrochemical Properties

scholarly journals Poly(3,4-ethylenedioxythiophene) Electrosynthesis in the Presence of Mixtures of Flexible-Chain and Rigid-Chain Polyelectrolytes

Polymers ◽  
2021 ◽  
Vol 13 (22) ◽  
pp. 3866
Author(s):  
Varvara Kabanova ◽  
Oxana Gribkova ◽  
Alexander Nekrasov
Keyword(s):  
Additive Effect ◽  
Potential Cycling ◽  
Flexible Chain ◽  
Chain Component ◽  
Ammonia Sensing ◽  
Rigid Chain ◽  
Vis Spectroscopy ◽  
Polyaniline Films ◽  
Spectroelectrochemical Properties

The electrochemical synthesis of poly(3,4-ethylenedioxythiophene) (PEDOT) was first carried out in the presence of mixtures of flexible-chain and rigid-chain polyacids and their Na-salts. Earlier on with the example of polyaniline, we have shown the non-additive effect of the rigid-chain component of polyacid mixtures on the electrodeposition of polyaniline films, their morphology and spectroelectrochemical properties. In this study, we confirmed the non-additive effect and showed that such mixed PEDOT–polyelectrolyte films possess unique morphology, spectroelectrochemical and ammonia sensing properties. The electrosynthesis was carried out in potential cycling, galvanostatic and potentiostatic regimes and monitored by in situ UV–Vis spectroscopy. UV–Vis spectroelectrochemistry of the obtained PEDOT–polyelectrolyte films revealed the dominating influence of the rigid-chain polyacid on the electronic structure of the mixed complexes. The mixed PEDOT–polyacid films demonstrated the best ammonia sensing performance (in the range of 5 to 25 ppm) as compared to the films of individual PEDOT–polyelectrolyte films.

scholarly journals Synthesis of New Chiral Inducer and Preparation of Semi-Conducting Polymer Films Showing Fingerprint Structure

2014 ◽  
Vol 27 ◽  
pp. 6-12 ◽  
Author(s):  
Hiroki Hayashi ◽  
Kohsuke Kawabata ◽  
Hiromasa Goto
Keyword(s):  
Thin Film ◽  
Liquid Crystal ◽  
Surface Morphology ◽  
Optical Microscopy ◽  
Conducting Polymer ◽  
Electrolyte Solution ◽  
Cholesteric Liquid Crystal ◽  
Chiral Liquid Crystal ◽  
Conducting Polymer Films ◽  
Electrochemical Polymerisation

We synthesised a rod like shaped new chiral inducer to construct chiral liquid crystal electrolyte solution. Next, electrochemical polymerisation was carried out in the chiral liquid crystal electrolyte solution. The surface morphology of the polymers were observed with polarising optical microscopy. Synthesis of the new chiral inducer and preparation of semi-conducting thin film in the cholesteric liquid crystal electrolyte solution were performed.

scholarly journals Preparation of a Ferroelectric Liquid Crystal Electrolyte Solution

2015 ◽  
Vol 46 ◽  
pp. 1-8
Author(s):  
Tomonori Ito ◽  
Tomoaki Jo ◽  
Jiuchao Dong ◽  
Hitoshi Hayashi ◽  
Hiromasa Goto
Keyword(s):  
Liquid Crystal ◽  
Electrolyte Solution ◽  
Ferroelectric Liquid Crystal ◽  
Electrochemical Polymerisation

A ferroelectric liquid crystal was synthesised. We attempted electrochemical polymerisation in ferroelectric liquid crystal.

scholarly journals Investigations of electrochemical and spectroelectrochemical properties (UV-Vis, EPR) of thiophene trimer derivatives substituted with phenylvinyl groups

Polimery ◽  
2009 ◽  
Vol 54 (03) ◽  
pp. 209-215
Author(s):  
MIECZYSLAW LAPKOWSKI ◽  
MALGORZATA JADAMIEC ◽  
DAVID L. OFFICER ◽  
PAWEL WAGNER ◽  
AGNIESZKA STOLARCZYK ◽  
...  
Keyword(s):  
Spectroelectrochemical Properties
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