Highly efficient and recyclable heterogeneous asymmetric transfer hydrogenation of ketones in waterElectronic supplementary information (ESI) available: Experimental procedure for the transfer hydrogenation of ketones in water and the analytical data for the obtained chiral aromatic alcohols. See http://www.rsc.org/suppdata/cc/b4/b408533g/

2004 ◽  
pp. 2070 ◽  
Author(s):  
Pei Nian Liu ◽  
Jin Gen Deng ◽  
Yong Qiang Tu ◽  
Shao Hua Wang
Keyword(s):  
Analytical Data ◽  
Transfer Hydrogenation ◽  
Supplementary Information ◽  
Asymmetric Transfer Hydrogenation ◽  
Experimental Procedure ◽  
Highly Efficient ◽  
Aromatic Alcohols

Facile assembly of bifunctional, magnetically retrievable mesoporous silica for enantioselective cascade reactions

2019 ◽  
Vol 55 (90) ◽  
pp. 13578-13581 ◽  
Author(s):  
Zhongrui Zhao ◽  
Fengwei Chang ◽  
Tao Wang ◽  
Lijian Wang ◽  
Lingbo Zhao ◽  
...  
Keyword(s):  
Mesoporous Silica ◽  
Cross Coupling ◽  
Bifunctional Catalyst ◽  
Cascade Reactions ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Aromatic Alcohols ◽  
Hydrogenation Reactions ◽  
Successive Reduction

A magnetically recyclable bifunctional catalyst enables synergistic Suzuki cross-coupling/asymmetric transfer hydrogenation and successive reduction/asymmetric transfer hydrogenation reactions for the preparation of chiral aromatic alcohols.

Highly efficient chiral PNNP ligand for asymmetric transfer hydrogenation of aromatic ketones in water

2006 ◽  
Vol 47 (26) ◽  
pp. 4501-4503 ◽  
Author(s):  
Yan Xing ◽  
Jian-Shan Chen ◽  
Zhen-Rong Dong ◽  
Yan-Yun Li ◽  
Jing-Xing Gao
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Aromatic Ketones ◽  
Highly Efficient ◽  
Chiral Pnnp Ligand

Highly Efficient and Recyclable Heterogeneous Asymmetric Transfer Hydrogenation of Ketones in Water.

ChemInform ◽  
2005 ◽  
Vol 36 (11) ◽  
Author(s):  
Pei Nian Liu ◽  
Jin Gen Deng ◽  
Yong Qiang Tu ◽  
Shao Hua Wang
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Highly Efficient

A pH-Responsive Soluble-Polymer-Based Homogeneous Ruthenium Catalyst for Highly Efficient Asymmetric Transfer Hydrogenation (ATH)

ChemPlusChem ◽  
2016 ◽  
Vol 81 (6) ◽  
pp. 541-549 ◽  
Author(s):  
Yinzheng Xie ◽  
Mengpan Wang ◽  
Xiaohui Wu ◽  
Chen Chen ◽  
Wenbo Ma ◽  
...  
Keyword(s):  
Ruthenium Catalyst ◽  
Transfer Hydrogenation ◽  
Ph Responsive ◽  
Asymmetric Transfer Hydrogenation ◽  
Soluble Polymer ◽  
Highly Efficient

Efficient asymmetric transfer hydrogenation of ketones in ethanol with chiral iridium complexes of spiroPAP ligands as catalysts

2015 ◽  
Vol 51 (28) ◽  
pp. 6123-6125 ◽  
Author(s):  
Wei-Peng Liu ◽  
Ming-Lei Yuan ◽  
Xiao-Hui Yang ◽  
Ke Li ◽  
Jian-Hua Xie ◽  
...  
Keyword(s):  
Hydrogen Donor ◽  
Transfer Hydrogenation ◽  
Chiral Alcohols ◽  
Iridium Complexes ◽  
Asymmetric Transfer Hydrogenation ◽  
Highly Efficient

Highly efficient iridium catalyzed asymmetric transfer hydrogenation of simple ketones with ethanol as a hydrogen donor has been developed, providing chiral alcohols with up to 98% ee.

scholarly journals Preparation of Mesoporous Silica-Supported Chiral Amino Alcohols for the Enantioselective Addition of Diethylzinc to Aldehyde and Asymmetric Transfer Hydrogenation to Ketones

2015 ◽  
Vol 2015 ◽  
pp. 1-6
Author(s):  
Shaheen M. Sarkar ◽  
Md. Eaqub Ali ◽  
Md. Lutfor Rahman ◽  
Mashitah Mohd Yusoff
Keyword(s):  
Mesoporous Silica ◽  
Amino Alcohols ◽  
Optically Active ◽  
Transfer Hydrogenation ◽  
Catalytic Process ◽  
Asymmetric Transfer Hydrogenation ◽  
Chiral Catalyst ◽  
Aromatic Alcohols ◽  
Enantioselective Addition ◽  
Cubic Mesoporous

Optically active (−)-ephedrine, (−)-norephedrine, and (−)-prolinol were immobilized onto cubic mesoporous MCM-48 silica. The immobilized amino alcohols served as a heterogeneous chiral catalyst for the asymmetric addition of diethylzinc to aldehydes and transfer hydrogenation to ketones. The developed catalytic process yielded optically enriches secondary aromatic alcohols with 92–99% conversion and 70–82% enantioselectivity.

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