Light metal hydrides and complex hydrides for hydrogen storage

2004 ◽  
pp. 2249-2258 ◽  
Author(s):  
F. Schüth ◽  
B. Bogdanović ◽  
M. Felderhoff
Keyword(s):  
Hydrogen Storage ◽  
Metal Hydrides ◽  
Light Metal ◽  
Complex Hydrides

Light Metal Hydrides and Complex Hydrides for Hydrogen Storage

ChemInform ◽  
2005 ◽  
Vol 36 (2) ◽  
Author(s):  
F. Schueth ◽  
B. Bogdanovic ◽  
M. Felderhoff
Keyword(s):  
Hydrogen Storage ◽  
Metal Hydrides ◽  
Light Metal ◽  
Complex Hydrides

scholarly journals Industrial production of light metal hydrides for hydrogen storage

2007 ◽  
Vol 56 (10) ◽  
pp. 847-851 ◽  
Author(s):  
Nico Eigen ◽  
Claude Keller ◽  
Martin Dornheim ◽  
Thomas Klassen ◽  
Rüdiger Bormann
Keyword(s):  
Hydrogen Storage ◽  
Industrial Production ◽  
Metal Hydrides ◽  
Light Metal

Nanoconfined light metal hydrides for reversible hydrogen storage

MRS Bulletin ◽  
2013 ◽  
Vol 38 (6) ◽  
pp. 488-494 ◽  
Author(s):  
Petra E. de Jongh ◽  
Mark Allendorf ◽  
John J. Vajo ◽  
Claudia Zlotea
Keyword(s):  
Hydrogen Storage ◽  
Metal Hydrides ◽  
Light Metal ◽  
Image Position

Abstract

ChemInform Abstract: Nanoconfined Light Metal Hydrides for Reversible Hydrogen Storage

ChemInform ◽  
2014 ◽  
Vol 45 (16) ◽  
pp. no-no
Author(s):  
Petra E. de Jongh ◽  
Mark Allendorf ◽  
John J. Vajo ◽  
Claudia Zlotea
Keyword(s):  
Hydrogen Storage ◽  
Metal Hydrides ◽  
Light Metal

High Throughput Screening of Complex Hydrides for Hydrogen Storage

2005 ◽  
Vol 885 ◽  
Author(s):  
Gregory Lewis ◽  
J. W. Adriaan Sachtler ◽  
John J. Low ◽  
David A. Lesch ◽  
Syed A. Faheem ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Molecular Mechanics ◽  
High Throughput ◽  
High Throughput Screening ◽  
Metal Hydrides ◽  
Combinatorial Synthesis ◽  
Established Method ◽  
Mild Conditions ◽  
Complex Hydrides ◽  
Combinatorial Methods

ABSTRACTThe discovery that dopants, such as Ti, cause NaAlH4 to reversibly desorb H2 at mild conditions has spurred a great deal of research into complex metal hydrides. However, no complex hydride meets the targets for automotive hydrogen storage. Our approach is to accelerate the rate of discovery of improved hydrides and dopants through the combination of Virtual High Throughput Screening (VHTS) and Combinatorial Synthesis and Screening (CSS). Our CSS methods will allow us to screen thousands of samples in a year. These samples will be prepared by ball milling mixtures of hydrides and dopants similar to the established method of preparing Ti doped NaAlH4. VHTS exploits a molecular mechanics method to screen a thousand phases in a month. The combination of combinatorial methods and VHTS will help us discover the most promising complex hydrides for hydrogen storage. We will show the results of our medium throughput CSS and VHTS as applied to the NaAlH4–LiAlH4 – Mg(AlH4)2 mixed alanate compositions.

Light metal hydrides – Potential hydrogen storage materials

2008 ◽  
Vol 8 (3-4) ◽  
pp. 459-462 ◽  
Author(s):  
Hayley Woolf ◽  
Ian Brown ◽  
Mark Bowden
Keyword(s):  
Hydrogen Storage ◽  
Metal Hydrides ◽  
Light Metal ◽  
Hydrogen Storage Materials ◽  
Storage Materials

scholarly journals Light Weight Complex Metal Hydrides for Reversible Hydrogen Storage

2021 ◽  
Author(s):  
Sesha Srinivasan ◽  
Luis Rivera ◽  
Diego Escobar ◽  
Elias Stefanakos
Keyword(s):  
Hydrogen Storage ◽  
Metal Hydride ◽  
Metal Hydrides ◽  
Light Weight ◽  
X Ray Diffraction ◽  
Ambient Temperatures ◽  
Complex Metal ◽  
Complex Hydrides ◽  
Microstructural Surface ◽  
New Phase

We have investigated the complex metal hydrides involving light weight elements or compounds for the reversible hydrogen storage. The complex hydrides are prepared via an inexpensive solid state mechanochemical process under reactive atmosphere at ambient temperatures. The complex metal hydride, LiBH4 with different mole concentrations of ZnCl2 were characterized for the new phase formation and hydrogen decomposition characteristics of Zn(BH4)2. Furthermore, the complex metal hydride is destabilized using the addition of nano MgH2 for the reversible hydrogen storage characteristics. The structural, microstructural, surface, and other physicochemical behaviors of these lightweight complex metal hydrides have been studied via various metrological tools such as x-ray diffraction, Fourier transform infrared spectroscopy, thermal programed desorption, and PCT hydrogen absorption methods.

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