Carboxylic acid functionalized cobalt(iii) cyclen complexes for catalytic hydrolysis of phosphodiester bonds

2004 ◽  
pp. 2006 ◽  
Author(s):  
D. Andrew Knight ◽  
James B. Delehanty ◽  
Ellen R. Goldman ◽  
Jason Bongard ◽  
Frederick Streich ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Catalytic Hydrolysis ◽  
Phosphodiester Bonds ◽  
Hydrolysis Of

Carboxylic acid-catalysed hydrolysis of rhamnogalacturonan in subcritical water media

2021 ◽  
pp. 105268
Author(s):  
Carla S. Valdivieso Ramirez ◽  
Feral Temelli ◽  
Marleny D.A. Saldaña
Keyword(s):  
Carboxylic Acid ◽  
Subcritical Water ◽  
Water Media ◽  
Hydrolysis Of

Carboxylic acid-catalysed hydrolysis of polygalacturonic acid in subcritical water media

2020 ◽  
pp. 105103
Author(s):  
Carla S. Valdivieso Ramirez ◽  
Jose E. Sanchez Gallego ◽  
Michael Gänzle ◽  
Feral Temelli ◽  
Marleny D.A. Saldaña
Keyword(s):  
Carboxylic Acid ◽  
Subcritical Water ◽  
Polygalacturonic Acid ◽  
Water Media ◽  
Hydrolysis Of

The synthesis of norbornanes with functionalized carbon substituents at a bridgehead. 1-(3-Oxonorborn-1-yl)ethanone and 1-(3-oxonorborn-1-yl)-2-propanone

1992 ◽  
Vol 70 (5) ◽  
pp. 1492-1505 ◽  
Author(s):  
Peter Yates ◽  
Magdy Kaldas
Keyword(s):  
Acetic Acid ◽  
Carboxylic Acid ◽  
Hydrogen Bromide ◽  
Tertiary Alcohol ◽  
Ethyl Bromoacetate ◽  
Second Molar ◽  
Molar Equivalent ◽  
Acid Lactone ◽  
Basic Hydrolysis ◽  
Hydrolysis Of

Treatment of 2-norobornene-1-carboxylic acid (7) with one equivalent of methyllithium in ether followed by a second molar equivalent after dilution with tetrahydrofuran gave 1-(norborn-2-en-lyl)ethanone (10) and only a trace of the tertiary alcohol 11. Reaction of 7 with formic acid followed by hydrolysis gave a 4:3 mixture of exo-3- and exo-2-hydroxynorbornane-1-carboxylic acid (16 and 17), whereas oxymercuration–demercuration gave only the exo-3-hydroxy isomer 16. Oxidation of 16 and 17 gave 3- and 2-oxonorbornane-1-carboxylic acid (27 and 29), respectively. Oxymercuration–demercuration of 10 gave exclusively 1-(exo-3-hydroxynorborn-1-yl)ethanone (30), which was also prepared by treatment of 16 with methyllithium in analogous fashion to that used for the conversion of 7 to 10. Oxidation of 30 gave 1-(3-oxonorborn-1-yl)ethanone (1). Dehydrobromination of exo-2-bromonorbornane-1-acetic acid and dehydration of 2-hydroxy-norbornane-2-acetic acid derivatives gave 1-(norborn-2-ylidene) acetic acid derivatives to the exclusion of norborn-2-ene-1 -acetic acid derivatives. Treatment of exo-5-acetyloxy-2-norobornanone (52) with ethyl bromoacetate and zinc gave ethyl exo-5-acetyloxy-2-hydroxynorbornane-(exo- and endo-2-acetate (53 and 54). Reaction of 53 with hydrogen bromide gave initially ethyl endo-3-acetyloxy-exo-6-bromonorbornane-1-acetate (59), which was subsequently converted to a mixture of 59 and its exo-3-acetyloxy epimer 61. Catalytic hydrogenation of this mixture gave a mixture of ethyl endo- and exo-3-acetyloxynorbornane-1 -acetate (62 and 63). Basic hydrolysis of this gave a mixture of the corresponding hydroxy acids, 70 and 71; the former was slowly converted to the latter at pH 5. Oxidation of the mixture of 70 and 71 gave 3-oxonorbornane-1-acetic acid (72). Treatment of the mixture with methyllithium as for 16 gave a mixture of 1-(endo- and exo-3-hydroxynorborn-1-yl)-2-propanone (73 and 74), which was oxidized to 1-(3-oxo-norborn-1-yl)-2-propanone (2). Reaction of exo-2-hydroxynorbornane-1-acetic acid lactone (75) with methyllithium in ether gave (1-(exo-2-hydroxynorborn-1-yl)-2-propanone (76), which on oxidation gave the 2-oxo isomer 78 of 2.

scholarly journals Catalytic hydrolysis of s-triazine compounds over Al2O3

1996 ◽  
Vol 27 (1-2) ◽  
pp. 167-173 ◽  
Author(s):  
Zhaoqi Zhan ◽  
Martin Müllner ◽  
Johannes A. Lercher
Keyword(s):  
Catalytic Hydrolysis ◽  
Hydrolysis Of

Catalytic Hydrolysis of 4-Nitrophenyl Phosphate by Lanthanum(III)-Hectorite

Langmuir ◽  
2003 ◽  
Vol 19 (6) ◽  
pp. 2188-2192 ◽  
Author(s):  
Steven T. Frey ◽  
Benjamin M. Hutchins ◽  
Brian J. Anderson ◽  
Teresa K. Schreiber ◽  
Michael E. Hagerman
Keyword(s):  
Catalytic Hydrolysis ◽  
Nitrophenyl Phosphate ◽  
Hydrolysis Of

Thermodynamics Study on Catalytic Hydrolysis of CCl2F2 over Solid Acid MoO3/ZrO2

2013 ◽  
Vol 726-731 ◽  
pp. 535-538
Author(s):  
Tian Cheng Liu ◽  
Yu Jiao Guo ◽  
Ping Ning ◽  
Guang Yang Tang ◽  
Ming Long Yuan
Keyword(s):  
Water Vapor ◽  
Solid Acid ◽  
Exothermic Reaction ◽  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Catalytic Hydrolysis ◽  
Chemical Adsorption ◽  
Freundlich Model ◽  
Hydrolysis Of

Catalytic hydrolysis decomposition of dichlorodifluoromethane (CCl2F2) in the presence of water vapor and oxygen was studied over solid acid MoO3/ZrO2 using a fixed-bed reactor. The CCl2F2 adsorption was multilayer chemical adsorption and its process was corresponding with Freundlich model. Its heat was from 56.3 to 73.2 KJ.mol-1, and it was exothermic reaction and chemical adsorption.

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