Binding sites on the outside of metallo-supramolecular architectures; engineering coordination polymers from discrete architectures

2004 ◽  
pp. 1546-1555 ◽  
Author(s):  
Mirela Pascu ◽  
Floriana Tuna ◽  
Edyta Kolodziejczyk ◽  
Gabriel I. Pascu ◽  
Guy Clarkson ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Binding Sites ◽  
Supramolecular Architectures

Supramolecular Architectures and Magnetic Properties of Coordination Polymers Based on Pyrazinedicarboxylato Ligands Showing Embedded Water Clusters

2006 ◽  
Vol 45 (14) ◽  
pp. 5367-5382 ◽  
Author(s):  
Garikoitz Beobide ◽  
Oscar Castillo ◽  
Antonio Luque ◽  
Urko García-Couceiro ◽  
Juan P. García-Terán ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymers ◽  
Water Clusters ◽  
Supramolecular Architectures

Precursory disilver(I) macrocycle with pendent binding sites: a new building block for targeting coordination polymers based on solvent-controlled conformational variation

CrystEngComm ◽  
2009 ◽  
Vol 11 (4) ◽  
pp. 576 ◽  
Author(s):  
Wei Wei ◽  
Mingyan Wu ◽  
Yougui Huang ◽  
Qiang Gao ◽  
Qingfu Zhang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Building Block ◽  
Binding Sites

scholarly journals Investigating the geometrical preferences of a flexible benzimidazolone-based linker in the synthesis of coordination polymers

2017 ◽  
Vol 4 (12) ◽  
pp. 171064 ◽  
Author(s):  
Corey L. Jones ◽  
Elizabeth A. Marsden ◽  
Adam C. Nevin ◽  
Benson M. Kariuki ◽  
Mohan M. Bhadbhade ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Binding Sites ◽  
Metal Salts ◽  
Diacetic Acid ◽  
X Ray Diffraction ◽  
X Ray ◽  
Carboxylate Groups ◽  
Square Planar ◽  
Transition Metal Salts ◽  
Group 2

A series of new group 2 coordination polymers, MgL  ={MgL(H 2 O)(DMF) 0.75 } ∞ , CaL  = {CaL(DMF) 2 } ∞ , SrL  = {SrL(H 2 O) 0.5 } ∞ and BaL  = {BaL(H 2 O) 0.5 } ∞ , were synthesized using a flexible benzimidazolone diacetic acid linker ( H 2 L ) in which the two carboxylic acid binding sites are connected to a planar core via {–CH 2 –} spacers that can freely rotate in solution. In a ‘curiosity-led' diversion from group 2 metals, the first row transition metal salts Mn 2+ , Cu 2+ and Zn 2+ were also reacted with L to yield crystals of MnL = {MnL(DMF)(H 2 O) 3.33 } ∞ , Cu 3 L 2  = {Cu 3 L 2 (DMF) 2 (CHO 2 ) 2 } ∞ and ZnL  = {ZnL(DMF)} ∞ . Crystal structures were obtained for all seven materials. All structures form as two-dimensional sheets and contain six-coordinate centres, with the exception of ZnL, which displays tetrahedrally coordinated metal centres, and Cu 3 L 2 , which contains square planar coordinated metal centres and Cu paddle-wheels. In each structure, the linker adopts one of two distinct conformations, with the carboxylate groups either cis or trans with respect to the planar core. All materials were also characterized by powder X-ray diffraction and thermogravimetric analysis.

scholarly journals [M(C5O5)2(H2O)n]2−as a Building Block for Hetero- and Homo-bimetallic Coordination Polymers: From 1D Chains to 3D Supramolecular Architectures

2009 ◽  
Vol 9 (2) ◽  
pp. 1013-1019 ◽  
Author(s):  
Chih-Chieh Wang ◽  
Meu-Ju Ke ◽  
Cheng-Hsiao Tsai ◽  
I-Hsuan Chen ◽  
Shin-I Lin ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Building Block ◽  
Supramolecular Architectures ◽  
1D Chains

scholarly journals Synthesis, Crystal Structures, and Magnetic Properties of Three Cobalt(II) Coordination Polymers Constructed from 3,5-Pyridinedicarboxylic Acid or 3,4-Pyridinedicarboxylic Acid Ligands

Crystals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 166
Author(s):  
Xiaojing Zhou ◽  
Xiaolei Guo ◽  
Lili Liu ◽  
Zhan Shi ◽  
Yan Pang ◽  
...  
Keyword(s):  
Dicarboxylic Acid ◽  
Coordination Polymers ◽  
Exchange Interactions ◽  
Cobalt Nitrate ◽  
Solvothermal Reaction ◽  
X Ray Diffraction ◽  
Pyridine Carboxylic Acid ◽  
Supramolecular Architectures ◽  
Pyridinedicarboxylic Acid ◽  
Pyridine Carboxylic

Three 2D new coordination polymers Co2(L1)2(1,10-Phenanthroline)2(DMF)0.5(H2O) (1), (H2L1 = Pyridine-3,5-dicarboxylic acid) Co(L1)(2,2-bipyridine) (2), and Co(L2)(2,2-bipyridine) (DMF) (3) (H2L2 = Pyridine-3,4-dicarboxylic acid) were synthesized through a solvothermal reaction of cobalt nitrate and pyridine carboxylic acid ligand with the auxiliary ligand (1,10-Phenanthroline or 2,2-bipyridine). They were characterized by X-ray diffraction and elemental analysis, infrared spectroscopy, thermogravimetry analysis, and magnetism. Compounds 1–3 featured 2D hexagonal (6,3) networks which linked into 3D supramolecular architectures through π–π interaction. In addition, compounds 1 and 2 showed the antiferromagnetic exchange interactions, and the magnetic property of compound 3 exhibited ferromagnetic exchange interactions.

Supramolecular architectures of metal-oxalato coordination polymers bearing N-tethered adenine nucleobases

Polyhedron ◽  
2019 ◽  
Vol 171 ◽  
pp. 53-64
Author(s):  
Juan P. García-Terán ◽  
Garikoitz Beobide ◽  
Oscar Castillo ◽  
Javier Cepeda ◽  
Antonio Luque ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Supramolecular Architectures
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