Quasi-solid-state dye sensitized solar cells with 1,3:2,4-di-O-benzylidene-d-sorbitol derivatives as low molecular weight organic gelators

2004 ◽  
Vol 14 (12) ◽  
pp. 1905-1909 ◽  
Author(s):  
Nils Mohmeyer ◽  
Peng Wang ◽  
Hans-Werner Schmidt ◽  
Shaik M. Zakeeruddin ◽  
Michael Grätzel
Nanomaterials ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 2516
Author(s):  
Minseon Kong ◽  
Kyeong Seok Kim ◽  
Nguyen Van Nga ◽  
Yeonju Lee ◽  
Yu Seong Jeon ◽  
...  

The leakage and volatilization of liquid electrolytes limit the commercialization of dye-sensitized solar cells (DSCs). As solid-state (ss) hole-transporting materials, free from leakage and volatilization, biscarbazole-based polymers with different molecular weights (PBCzA-H (21,200 g/mol) and PBCzA-L (2450 g/mol)) were applied in combination with additives to produce ssDSCs. An ssDSC with PBCzA-H showed a better short-circuit current (Jsc), open-circuit voltage (Voc), and fill factor (FF) than a device with PBCzA-L, resulting in 38% higher conversion efficiency. Compared to the PBCzA-L, the PBCzA-H with a higher molecular weight showed faster hole mobility and larger conductivity, leading to elevations in Jsc via rapid hole transport, Voc via rapid hole extraction, and FF via lowered series and elevated shunt resistances. Thus, it is believed that PBCzA-H is a useful candidate for replacing liquid electrolytes.


RSC Advances ◽  
2013 ◽  
Vol 3 (33) ◽  
pp. 14037 ◽  
Author(s):  
Yibo Zhang ◽  
Kun Cao ◽  
Xiaoguang Zhu ◽  
Xian Li ◽  
Xianfeng Qiao ◽  
...  

2010 ◽  
Vol 25 (2) ◽  
pp. 218-222 ◽  
Author(s):  
Xiaolin Shen ◽  
Weilin Xu ◽  
Guijie Liang ◽  
Jie Xu ◽  
Hongjun Yang ◽  
...  

2006 ◽  
Vol 90 (5) ◽  
pp. 549-573 ◽  
Author(s):  
Bin Li ◽  
Liduo Wang ◽  
Bonan Kang ◽  
Peng Wang ◽  
Yong Qiu

Molecules ◽  
2020 ◽  
Vol 25 (1) ◽  
pp. 198 ◽  
Author(s):  
Michèle Chevrier ◽  
Alberto Fattori ◽  
Laurent Lasser ◽  
Clément Kotras ◽  
Clémence Rose ◽  
...  

Chlorophyll a derivatives were integrated in “all solid-state” dye sensitized solar cells (DSSCs) with a mesoporous TiO2 electrode and 2′,2′,7,7′-tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9′-spirobifluorene as the hole-transport material. Despite modest power conversion efficiencies (PCEs) between 0.26% and 0.55% achieved for these chlorin dyes, a systematic investigation was carried out in order to elucidate their main limitations. To provide a comprehensive understanding of the parameters (structure, nature of the anchoring group, adsorption …) and their relationship with the PCEs, density functional theory (DFT) calculations, optical and photovoltaic studies and electron paramagnetic resonance analysis exploiting the 4-carboxy-TEMPO spin probe were combined. The recombination kinetics, the frontier molecular orbitals of these DSSCs and the adsorption efficiency onto the TiO2 surface were found to be the key parameters that govern their photovoltaic response.


2019 ◽  
Vol 7 (7) ◽  
pp. 7403-7411 ◽  
Author(s):  
Shanmuganathan Venkatesan ◽  
I-Ping Liu ◽  
Chiao-Wei Li ◽  
Chih-Mei Tseng-Shan ◽  
Yuh-Lang Lee

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