The coordination chemistry of copper(i) in liquid ammonia, trialkyl and triphenyl phosphite, and tri-n-butylphosphine solution

2004 ◽  
pp. 1312-1319 ◽  
Author(s):  
Kersti B. Nilsson ◽  
Ingmar Persson
Keyword(s):  
Coordination Chemistry ◽  
Liquid Ammonia ◽  
Triphenyl Phosphite

scholarly journals Speciation of Be2+ in acidic liquid ammonia and formation of tetra- and octanuclear beryllium amido clusters

2020 ◽  
Vol 11 (21) ◽  
pp. 5415-5422 ◽  
Author(s):  
Matthias Müller ◽  
Antti J. Karttunen ◽  
Magnus R. Buchner
Keyword(s):  
Coordination Chemistry ◽  
Liquid Ammonia ◽  
Metal Oxidation ◽  
Beryllium Metal

The boundaries of beryllium metal oxidation in acidic ammonia have been explored. This enabled the isolation of the tetra- and octa-nuclear beryllium amide complexes. The latter exhibits a completely new structural motive in coordination chemistry.

Ammonolysis of titanium tetrachloride in liquid ammonia

1976 ◽  
Vol 73 ◽  
pp. 849-851 ◽  
Author(s):  
Thomas Kottarathil ◽  
Gérard Lepoutre
Keyword(s):  
Liquid Ammonia ◽  
Titanium Tetrachloride

Fine-Tuning Electronic Properties of Luminescent Pt(II) Complexes via Vertex-Differentiated Coordination of Sterically Invariant Carborane-Based Ligands

2018 ◽  
Author(s):  
Kent O. Kirlikovali ◽  
Jonathan C. Axtell ◽  
Kierstyn Anderson ◽  
Peter I. Djurovich ◽  
Arnold L. Rheingold ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Fine Tuning ◽  
Fine Tune

We report the synthesis of two isomeric Pt(II) complexes ligated by doubly deprotonated 1,1′-bis(<i>o</i>-carborane) (<b>bc</b>). This work provides a potential route to fine-tune the electronic properties of luminescent metal complexes by virtue of vertex-differentiated coordination chemistry of carborane-based ligands.

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