Flame-made nanocrystalline ceria/zirconia doped with alumina or silica: structural properties and enhanced oxygen exchange capacity

2003 ◽  
Vol 13 (12) ◽  
pp. 2979 ◽  
Author(s):  
Heiko Schulz ◽  
Wendelin J. Stark ◽  
Marek Maciejewski ◽  
Sotiris E. Pratsinis ◽  
Alfons Baiker
RSC Advances ◽  
2021 ◽  
Vol 11 (37) ◽  
pp. 23095-23104
Author(s):  
Asim Riaz ◽  
Wojciech Lipiński ◽  
Adrian Lowe

Cerium doping into the V2O5 lattice forms a reversible V2O3/VO redox pair after sequential methane partial oxidation and CO2/H2O splitting reactions and produces syngas (H2, CO) with fast rates and high oxygen exchange capacity.


2019 ◽  
Vol 7 (48) ◽  
pp. 27347-27360 ◽  
Author(s):  
Asim Riaz ◽  
Muhammad Umair Ali ◽  
Wojciech Lipiński ◽  
Adrian Lowe

Developing an efficient redox material is a fundamental and crucial step in sustainable hydrocarbon fuel production via solar energy-driven thermochemical redox cycles.


2002 ◽  
Vol 12 (3) ◽  
pp. 368-378 ◽  
Author(s):  
Ronald L. Terjung ◽  
Ryszard Zarzeczny ◽  
H.T. Yang

Skeletal muscle mitochondrial capacity (mito), tissue blood flow (BF) capacity, and oxygen exchange capacity (e.g., DO2) appear to be well matched. The different skeletal muscle fiber types and muscle remodeled, due to inactivity >(e.g., related to aging or disease) or exercise training, exhibit widely differing aerobics capacities (V̇O2max). Yet, there are remarkably coordinated alterations in these 3 parameters in each of these conditions. With such a balance, there is likely shared control among these parameters in limiting (V̇O2max) of muscle, although this is a matter of considerable debate. The reduction in aerobic capacity in elderly can be improved by submaximal aerobic exercise training; this is related to increases in muscle mitochondria concentration and capillarity, but probably not BF capacity, as this is limited by central cardiovascular function. Thus, exercise-induced biochemical adaptations and angiogenesis occur in the elderly. The increase in muscle capillarity likely contributes to the increased oxygen exchange capacity, typical of endurance type training. The increase in [mito] appears essential to realize the increased in muscle V̇O2max with training and amplifies the rate-limiting influence of the muscle’s oxygen exchange capacity. Further, vascular remodeling induced by exercise in the elderly could be effective at improving flow capacity, if limited by peripheral obstruction. Thus, the limits to aerobic function specific to aged muscle appear most influenced by inactivity, whereas central cardiovascular changes impact whole body performance. Some may consider the aged myocyte as a small, inactive, normal myocyte in need of activity!


2017 ◽  
Vol 5 (37) ◽  
pp. 19901-19913 ◽  
Author(s):  
Roger Jacot ◽  
René Moré ◽  
Ronald Michalsky ◽  
Aldo Steinfeld ◽  
Greta R. Patzke

Screening of tetravalent dopants correlates dopant radius and oxygen exchange capacity for ceria optimization in solar thermochemical CO2 reduction.


2021 ◽  
Vol 1 (1) ◽  
pp. 26-29
Author(s):  
Siti Nabihan Ishak ◽  
Nik Ahmad Nizam Nik Malek

Layered double hydroxide (LDH) is one of the promising clay minerals that show great potential in various applications owing to its versatile structural properties. Prominently known for its high anion exchange capacity, this allows LDH to be considered as one of the most effective adsorbents in removing anionic toxic. However, the structural property of LDH hinders it from removing cationic toxic. Therefore, LDH have been functionalized to enhance its adsorption properties. In the present work, we aim to summarize the recent progress of functionalized LDH with different compounds for removal of both anionic and cationic toxics. The adsorption isotherm and effect of pH on absorption capacity also have been briefly reviewed.


2018 ◽  
Vol 6 (14) ◽  
pp. 5807-5816 ◽  
Author(s):  
R. Jacot ◽  
J. Madhusudhan Naik ◽  
R. Moré ◽  
R. Michalsky ◽  
A. Steinfeld ◽  
...  

This work reports an improved and stable oxygen exchange capacity (OEC) of optimized doped ceria Ce1−xMxO2−δ (M = Zr, Hf, Nb) materials for two-step thermochemical CO2 splitting over 50 consecutive redox cycles (7 days).


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