Molecular recognition. Self-assembly of molecular trigonal prisms and their host–guest adducts

2003 ◽  
pp. 2824-2825 ◽  
Author(s):  
James D. Crowley ◽  
Andrew J. Goshe ◽  
Brice Bosnich
Keyword(s):  
Molecular Recognition ◽  
Self Assembly ◽  
Trigonal Prisms

Self-Assembly of Selenium-Bridged Rhenium(I)-Based Metalla Rectangles: Synthesis, Characterization, and Molecular Recognition Studies

2014 ◽  
Vol 33 (2) ◽  
pp. 465-472 ◽  
Author(s):  
Bala. Manimaran ◽  
A. Vanitha ◽  
M. Karthikeyan ◽  
Buthanapalli Ramakrishna ◽  
Shaikh M. Mobin
Keyword(s):  
Molecular Recognition ◽  
Self Assembly

scholarly journals The macroscopic shape of assemblies formed from microparticles based on host–guest interaction dependent on the guest content

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Takahiro Itami ◽  
Akihito Hashidzume ◽  
Yuri Kamon ◽  
Hiroyasu Yamaguchi ◽  
Akira Harada
Keyword(s):  
Molecular Recognition ◽  
Smart Materials ◽  
Self Assembly ◽  
Early Stage ◽  
Contact Point ◽  
Sodium Acrylate ◽  
Contact Points ◽  
Assembly Behavior ◽  
Small Clusters ◽  
Macroscopic Shape

AbstractBiological macroscopic assemblies have inspired researchers to utilize molecular recognition to develop smart materials in these decades. Recently, macroscopic self-assemblies based on molecular recognition have been realized using millimeter-scale hydrogel pieces possessing molecular recognition moieties. During the study on macroscopic self-assembly based on molecular recognition, we noticed that the shape of assemblies might be dependent on the host–guest pair. In this study, we were thus motivated to study the macroscopic shape of assemblies formed through host–guest interaction. We modified crosslinked poly(sodium acrylate) microparticles, i.e., superabsorbent polymer (SAP) microparticles, with β-cyclodextrin (βCD) and adamantyl (Ad) residues (βCD(x)-SAP and Ad(y)-SAP microparticles, respectively, where x and y denote the mol% contents of βCD and Ad residues). Then, we studied the self-assembly behavior of βCD(x)-SAP and Ad(y)-SAP microparticles through the complexation of βCD with Ad residues. There was a threshold of the βCD content in βCD(x)-SAP microparticles for assembly formation between x = 22.3 and 26.7. On the other hand, the shape of assemblies was dependent on the Ad content, y; More elongated assemblies were formed at a higher y. This may be because, at a higher y, small clusters formed in an early stage can stick together even upon collisions at a single contact point to form elongated aggregates, whereas, at a smaller y, small clusters stick together only upon collisions at multiple contact points to give rather circular assemblies. On the basis of these observations, the shape of assembly formed from microparticles can be controlled by varying y.

Interconversion between Pd3L2 trigonal prism and Pd6L8 cube via anion exchange: binding affinity of monoatomic vs. polyatomic anions

2021 ◽  
Author(s):  
Haeri Lee ◽  
Jihun Han ◽  
Dongwon Kim ◽  
Ok-Sang Jung
Keyword(s):  
Anion Exchange ◽  
Binding Affinity ◽  
Self Assembly ◽  
Trigonal Prism ◽  
Trigonal Prisms

Systematic interconversion between trigonal prisms [Pd3X6L2] (X- = Cl-, Br-, and I-) and cubic cages [Pd6L8]12+(X-)12 (X- = BF4- with CF3SO3-) via anion exchange was established. Self-assembly of K2PdX4 (X-...

Molecular self-assembly of arene-Ru based interlocked catenane metalla-cages

2014 ◽  
Vol 50 (56) ◽  
pp. 7542-7544 ◽  
Author(s):  
Anurag Mishra ◽  
Abhishek Dubey ◽  
Jin Wook Min ◽  
Hyunuk Kim ◽  
Peter J. Stang ◽  
...  
Keyword(s):  
Self Assembly ◽  
Trigonal Prisms

Two interlocked and two simple trigonal prisms are formed through the coordination self-assembly of arene-Ru acceptors with a new tridentate donor.

Self-Assembly and Molecular Recognition in Water: Tubular Stacking and Guest-Templated Discrete Assembly of Water-Soluble, Shape-Persistent Macrocycles

2020 ◽  
Vol 142 (6) ◽  
pp. 2915-2924 ◽  
Author(s):  
Qiuhua Wang ◽  
Yulong Zhong ◽  
Daniel P. Miller ◽  
Xiaoxing Lu ◽  
Quan Tang ◽  
...  
Keyword(s):  
Molecular Recognition ◽  
Self Assembly ◽  
Water Soluble

A dual redox-responsive supramolecular amphiphile fabricated by selenium-containing pillar[6]arene-based molecular recognition

2018 ◽  
Vol 54 (91) ◽  
pp. 12856-12859 ◽  
Author(s):  
Yujuan Zhou ◽  
Kecheng Jie ◽  
Feihe Huang
Keyword(s):  
Molecular Recognition ◽  
Self Assembly ◽  
The Self ◽  
Redox Responsive ◽  
Assembly Behavior

A dual redox-responsive pillar[6]arene-based supramolecular amphiphile was fabricated in water. The self-assembly behavior of this supramolecular amphiphile in response to dual redox stimuli was investigated.

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