From manganese(ii)-azido layers to a novel three-dimensional molecular magnet: spin canting and metamagnetism

2003 ◽  
pp. 1748 ◽  
Author(s):  
En-Qing Gao ◽  
Zhe-Ming Wang ◽  
Chun-Hua Yan
Keyword(s):  
Three Dimensional ◽  
Molecular Magnet ◽  
Spin Canting

Studying the Origin of the Antiferromagnetic to Spin-Canting Transition in the β-p-NCC6F4CNSSN. Molecular Magnet

2010 ◽  
Vol 16 (9) ◽  
pp. 2741-2750 ◽  
Author(s):  
Mercè Deumal ◽  
Jeremy M. Rawson ◽  
Andrés E. Goeta ◽  
Judith A. K. Howard ◽  
Royston C. B. Copley ◽  
...  
Keyword(s):  
Molecular Magnet ◽  
Spin Canting

scholarly journals Transverse profile and three-dimensional spin canting of a Majorana state in carbon nanotubes

2019 ◽  
Vol 100 (15) ◽  
Author(s):  
Lars Milz ◽  
Wataru Izumida ◽  
Milena Grifoni ◽  
Magdalena Marganska
Keyword(s):  
Carbon Nanotubes ◽  
Three Dimensional ◽  
Spin Canting ◽  
Transverse Profile

Heterometallic Hexanuclear [Ln4Cr2] Cluster-Based Three-Dimensional Sulfate Frameworks as a Magnetic Refrigerant and Single Molecular Magnet

2018 ◽  
Vol 18 (12) ◽  
pp. 7335-7342 ◽  
Author(s):  
Zhong-Yi Li ◽  
Jian-Jun Zhang ◽  
Shu-Qin Liu ◽  
Hui Zhang ◽  
Ying-Ji Sun ◽  
...  
Keyword(s):  
Three Dimensional ◽  
Molecular Magnet ◽  
Magnetic Refrigerant

Structure, photoluminescence, and magnetic properties of a Mn(ii)-based metal–organic framework

2020 ◽  
Vol 44 (43) ◽  
pp. 18694-18702
Author(s):  
Hyojin Kim ◽  
Sunhwi Eom ◽  
Sora Park ◽  
Dong Won Kang ◽  
Mengmeng Wang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Magnetic Anisotropy ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Nitroaromatic Compounds ◽  
Trigonal Bipyramid ◽  
Spin Canting ◽  
Metal Organic ◽  
Low Symmetry ◽  
Organic Framework

Fluorescence of a three-dimensional Mn-based framework compound is completely quenched by nitroaromatic compounds and Cu2+ ions. Spin canting is operative in this Mn(ii) system, resulting from the magnetic anisotropy of the Mn(ii) ion in a low-symmetry trigonal bipyramid.

Spin canting in an unprecedented three-dimensional pyrophosphate- and 2,2′-bipyrimidine-bridged cobalt(ii) framework

2008 ◽  
pp. 5152 ◽  
Author(s):  
Nadia Marino ◽  
Teresa F. Mastropietro ◽  
Donatella Armentano ◽  
Giovanni De Munno ◽  
Robert P. Doyle ◽  
...  
Keyword(s):  
Three Dimensional ◽  
Spin Canting

A nickel(ii)–manganese(ii)-azido layered coordination polymer showing a three-dimensional ferrimagnetic order at 35 K

2018 ◽  
Vol 47 (3) ◽  
pp. 836-844 ◽  
Author(s):  
Sagar Ghosh ◽  
Shuvayan Roy ◽  
Cai-Ming Liu ◽  
Sasankasekhar Mohanta
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Coordination Polymer ◽  
Hysteresis Loop ◽  
Long Range ◽  
Three Dimensional ◽  
Molecular Magnet ◽  
Two Dimensional ◽  
Ferrimagnetic Ordering

The synthesis, crystal structure and magnetic properties of a two-dimensional nickel(ii)–manganese(ii)–azido system are described. It is an interesting molecular magnet because it exhibits long-range ferrimagnetic ordering at a Tc of 35 K and a hysteresis loop up to 20 K.

scholarly journals Three new metal coordination polymers of bifunctional imidazolate/tetrazolate bridges: the only example of a three-dimensional framework based on rare [Co4(μ3-OH)2(μ2-Cl)2]4+ mixed oxo-chloro-clusters

RSC Advances ◽  
2019 ◽  
Vol 9 (23) ◽  
pp. 13082-13087
Author(s):  
Lili Yang ◽  
Jian Zhou ◽  
Hua-Hong Zou ◽  
Qiuling Tang
Keyword(s):  
Coordination Polymers ◽  
Three Dimensional ◽  
Metal Coordination ◽  
Spin Canting ◽  
Metal Coordination Polymers

The interconnection of rare [Co4(μ3-OH)2(μ2-Cl)2]4+ mixed oxo-chloro-clusters and bifunctional bridges gives a new three-dimensional framework with unusual spin-canting behavior.

scholarly journals Cover Picture: Studying the Origin of the Antiferromagnetic to Spin-Canting Transition in the β-p-NCC6F4CNSSN. Molecular Magnet (Chem. Eur. J. 9/2010)

2010 ◽  
Vol 16 (9) ◽  
pp. 2635-2635
Author(s):  
Mercè Deumal ◽  
Jeremy M. Rawson ◽  
Andrés E. Goeta ◽  
Judith A. K. Howard ◽  
Royston C. B. Copley ◽  
...  
Keyword(s):  
Molecular Magnet ◽  
Spin Canting

scholarly journals Proton switching molecular magnetoelectricity

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yong Hu ◽  
Scott Broderick ◽  
Zipeng Guo ◽  
Alpha T. N’Diaye ◽  
Jaspal S. Bola ◽  
...  
Keyword(s):  
Proton Transfer ◽  
Room Temperature ◽  
Ferroelectric Phase ◽  
Thermal Hysteresis ◽  
Three Dimensional ◽  
Design Strategy ◽  
Magnetoelectric Coupling ◽  
Molecular Magnet ◽  
Heterogeneous Solids ◽  
Hysteresis Width

AbstractThe convergence of proton conduction and multiferroics is generating a compelling opportunity to achieve strong magnetoelectric coupling and magneto-ionics, offering a versatile platform to realize molecular magnetoelectrics. Here we describe machine learning coupled with additive manufacturing to accelerate the design strategy for hydrogen-bonded multiferroic macromolecules accompanied by strong proton dependence of magnetic properties. The proton switching magnetoelectricity occurs in three-dimensional molecular heterogeneous solids. It consists of a molecular magnet network as proton reservoir to modulate ferroelectric polarization, while molecular ferroelectrics charging proton transfer to reversibly manipulate magnetism. The magnetoelectric coupling induces a reversible 29% magnetization control at ferroelectric phase transition with a broad thermal hysteresis width of 160 K (192 K to 352 K), while a room-temperature reversible magnetic modulation is realized at a low electric field stimulus of 1 kV cm−1. The findings of electrostatic proton transfer provide a pathway of proton mediated magnetization control in hierarchical molecular multiferroics.

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