Combination of ionic self-assembly and hydrogen bonding as a tool for the synthesis of liquid-crystalline materials and organogelators from a simple building blockElectronic supplementary information (ESI) available: IR, NMR, DSC and TGA data of the organic core and complexes. See http://www.rsc.org/suppdata/cc/b3/b303552b/

2003 ◽  
pp. 1958 ◽  
Author(s):  
Franck Camerel ◽  
Charl F. J. Faul
Keyword(s):  
Hydrogen Bonding ◽  
Self Assembly ◽  
Liquid Crystalline ◽  
Supplementary Information ◽  
Crystalline Materials ◽  
Liquid Crystalline Materials

Columnar self-assembly of novel benzylidenehydrazones and their difluoroboron complexes: structure–property correlations

2019 ◽  
Vol 43 (18) ◽  
pp. 7099-7108 ◽  
Author(s):  
D. R. Vinayakumara ◽  
K. Swamynathan ◽  
Sandeep Kumar ◽  
Airody Vasudeva Adhikari
Keyword(s):  
Self Assembly ◽  
Liquid Crystalline ◽  
Electronic Devices ◽  
Structure Property ◽  
Organic Electronic Devices ◽  
Organic Electronic ◽  
Crystalline Materials ◽  
Liquid Crystalline Materials ◽  
Property Correlations

A series of prospective columnar liquid crystalline materials derived from novel organoboron complexes has been developed by virtue of their application in organic electronic devices.

Dendritic and Multipodal Liquid-Crystalline Materials based on Silsesquioxane and Siloxane Cores

2000 ◽  
Vol 628 ◽  
Author(s):  
Georg H. Mehl ◽  
Ralf Elsäβer ◽  
Keith J. Shepperson ◽  
Adam Thornton ◽  
John W. Goodby
Keyword(s):  
Crystalline Phase ◽  
Self Assembly ◽  
Liquid Crystalline ◽  
Phase Behaviour ◽  
Liquid Crystalline Phase ◽  
Stability Range ◽  
Inorganic Hybrid ◽  
Crystalline Materials ◽  
Liquid Crystalline Materials ◽  
Made In

ABSTRACTIn recent years great advances have been made in the synthesis of organic-inorganic hybrid materials, whether they are oligomeric, multipodal, polymeric or dendritic in structure. Of particular interest are liquid-crystalline systems, as the control of the soft self-assembly behaviour of these systems allows for the addressing of the macroscopic properties of these materials.The investigations of silsesquioxane and siloxane cores decorated with suitable organic groups of linear and branched structures leading to liquid-crystalline phase behaviour is presented. The structural and chemical features which govern the phase behaviour will be discussed. Important features are the size, geometry, structure and flexibility of the inorganic core, the flexibility, branching and length of the spacer linking inorganic cores and the organic groups, which promote liquid-crystalline phase behaviour. The effects of a variety of mesogenic structures on the liquid-crystalline phase behaviour and stability range will be discussed.

Assembly of thioether-containing rod-like liquid crystalline materials assisted by hydrogen-bonding terminal carboxyl groups

RSC Advances ◽  
2015 ◽  
Vol 5 (11) ◽  
pp. 8056-8062 ◽  
Author(s):  
Yuki Arakawa ◽  
Sungmin Kang ◽  
Junji Watanabe ◽  
Gen-ichi Konishi
Keyword(s):  
Hydrogen Bonding ◽  
Long Range ◽  
Liquid Crystalline ◽  
Crystalline Material ◽  
Carboxyl Groups ◽  
Crystalline Materials ◽  
Liquid Crystalline Materials ◽  
Alkoxy Groups ◽  
Liquid Crystalline Material

A hydrogen-bonding-tolane-based liquid crystalline material with an alkylsulfanyl group was synthesized, which exhibited a long-range correlated mesophase compared with analogs with alkyl and alkoxy groups.

scholarly journals A columnar liquid crystal with permanent polar order

2015 ◽  
Vol 3 (5) ◽  
pp. 985-989 ◽  
Author(s):  
J. Guilleme ◽  
J. Aragó ◽  
E. Ortí ◽  
E. Cavero ◽  
T. Sierra ◽  
...  
Keyword(s):  
Liquid Crystal ◽  
Electric Fields ◽  
Self Assembly ◽  
Liquid Crystalline ◽  
The Self ◽  
Polar Order ◽  
Crystalline Materials ◽  
Liquid Crystalline Materials

The self-assembly of axial dipolar subphthalocyanine molecules in the presence of electric fields leads to uniaxially oriented columnar liquid crystalline materials that exhibit permanent polarization.

scholarly journals Optical and Geometrical Characterizations of Non-Linear Supramolecular Liquid Crystal Complexes

Crystals ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 701 ◽  
Author(s):  
Hoda A. Ahmed ◽  
Mohamed Hagar ◽  
Omaima A. Alhaddad ◽  
Ayman A. Zaki
Keyword(s):  
Self Assembly ◽  
Density Functional ◽  
Liquid Crystalline ◽  
Theoretical Calculations ◽  
Scanning Calorimetry ◽  
Crystalline Materials ◽  
The Density Functional Theory ◽  
Different Temperatures ◽  
Ft Ir ◽  
Liquid Crystalline Materials

Nonlinear architecture liquid crystalline materials of supramolecular 1:1 H-bonded complexes (I/II and I/III) were prepared through a self-assembly intermolecular interaction between azopyridine (I) and 4-n-alkoxybenzoic acid (II) as well as 4-n-alkoxyphenylazo benzoic acid (III). The H-bond formation of the prepared supramolecular hydrogen bonded (SMHB) complexes was confirmed by Fourier-transform infrared spectroscopy (FT-IR) and differential scanning calorimetry (DSC). Optical and mesomorphic behaviors of the prepared complexes were studied by polarized optical microscopy (POM) as well as DSC. Theoretical calculations were performed by the density functional theory (DFT) and used to predict the molecular geometries of the synthesized complexes, and the results were used to explain the experimental mesomorphic and optical properties in terms of their estimated thermal parameters. Ordinary and extraordinary refractive indices as well as birefringence at different temperatures were investigated for each sample using an Abbe refractometer and modified spectrophotometer techniques. Microscopic and macroscopic order parameters were calculated for individual compounds and their supramolecular complexes.

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