Synthesis and properties of tetra-alkyl-dimethylguanidinium salts as a potential new generation of ionic liquids

2003 ◽  
Vol 5 (3) ◽  
pp. 347-352 ◽  
Author(s):  
Nuno M. M. Mateus ◽  
Luís C. Branco ◽  
Nuno M. T. Lourenço ◽  
Carlos A. M. Afonso
Keyword(s):  
Ionic Liquids ◽  
New Generation

Biocompatibility of Dicationic Imidazolium-Based Ionic Liquids: A New Generation of Multifunctional Coatings for Titanium Implants

2019 ◽  
Author(s):  
Sutton E. Wheelis ◽  
Claudia C. Biguetti ◽  
Shruti Natarajan ◽  
Lidia Guida ◽  
Brian Hedden ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Titanium Implants ◽  
New Generation

scholarly journals Molecular-Level Investigation of Cycloaliphatic Epoxidised Ionic Liquids as a New Generation of Monomers for Versatile Poly(Ionic Liquids)

Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1512
Author(s):  
Baris Demir ◽  
Gabriel Perli ◽  
Kit-ying Chan ◽  
Jannick Duchet-Rumeau ◽  
Sébastien Livi
Keyword(s):  
Ionic Liquids ◽  
Molecular Level ◽  
Computational Approach ◽  
Polymer Materials ◽  
Chemical Structures ◽  
Cycloaliphatic Epoxy ◽  
Polymer Models ◽  
Mechanical Performances ◽  
Dynamics Simulations ◽  
New Generation

Recently, a new generation of polymerised ionic liquids with high thermal stability and good mechanical performances has been designed through novel and versatile cycloaliphatic epoxy-functionalised ionic liquids (CEILs). From these first promising results and unexplored chemical structures in terms of final properties of the PILs, a computational approach based on molecular dynamics simulations has been developed to generate polymer models and predict the thermo–mechanical properties (e.g., glass transition temperature and Young’s modulus) of experimentally investigated CEILs for producing multi-functional polymer materials. Here, a completely reproducible and reliable computational protocol is provided to design, test and tune poly(ionic liquids) based on epoxidised ionic liquid monomers for future multi-functional thermoset polymers.

scholarly journals Synthesis of random copolymer of isobutylene with p-methylstyrene by cationic polymerization in ionic liquids

e-Polymers ◽  
2018 ◽  
Vol 18 (5) ◽  
pp. 423-431 ◽  
Author(s):  
Xiaoqian Zhang ◽  
Wenli Guo ◽  
Yibo Wu ◽  
Yuwei Shang ◽  
Shuxin Li ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Random Copolymer ◽  
Monomer Conversion ◽  
High Viscosity ◽  
Feed Ratio ◽  
Copolymer Composition ◽  
Ionization Time ◽  
Cationic Copolymerization ◽  
Monomer Feed ◽  
New Generation

AbstractPoly(isobutylene-co-p-methylstyrene) (IB/p-MeSt) random copolymer is a new generation of polyisobutylene-based elastomer. The cationic copolymerization of IB with p-MeSt was thoroughly examined by using various initiating systems in [Hmim][NTf2] at −30°C. The effects of initiating systems and monomer feed ratio on the monomer conversion, molecular weight and copolymer composition are discussed. The polymers were characterized by 1H-nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR) spectroscopy and matrix-assisted laser desorption/ionization-time-of-flight-mass spectroscopy (MALDI-TOF-MS) to determine their chemical composition and molecular structure. The results show that high polarity, high viscosity and ionic environment of ionic liquids (ILs) influenced the copolymerization. The corresponding mechanism of cationic copolymerization in ILs is also proposed.

New Generation Ionic Liquids: Cations Derived from Amino Acids.

ChemInform ◽  
2005 ◽  
Vol 36 (50) ◽  
Author(s):  
Guo-hong Tao ◽  
Ling He ◽  
Ning Sun ◽  
Yuan Kou
Keyword(s):  
Amino Acids ◽  
Ionic Liquids ◽  
New Generation

scholarly journals The Structure and Characteristics of Tribological Systems with Diamond Like Carbon Coatings under Ionic Liquid Lubrication Conditions

2016 ◽  
Vol 61 (2) ◽  
pp. 1169-1174 ◽  
Author(s):  
M. Madej ◽  
D. Ozimina ◽  
J. Kasińska ◽  
J. Hawlena
Keyword(s):  
Ionic Liquids ◽  
Vapour Deposition ◽  
Chemical Vapour ◽  
Diamond Like Carbon ◽  
Instrumented Indentation ◽  
Diamond Coatings ◽  
Carbon Coatings ◽  
New Generation ◽  
Lubrication Conditions ◽  
Ball On Disc

Abstract The results from the tests on tribological a-C:H diamond coatings deposited by PACVD (plasma assisted chemical vapour deposition) on 100Cr6 steel components are presented in this work. Mechanical properties - nanohardness and Young’s modulus - were assessed by instrumented indentation. Tribological tests were conducted with T-01M tester in a ball-on-disc test under dry and boundary friction conditions. Selected ionic liquids - synthetic new generation lubricants - were used for lubrication. The results from the experiments indicate that diamond-like coatings improved tribological characteristics of the friction pairs tested, with the ionic liquids intensifying this effect.

New Generation Carbon Capture Ionic Liquids Regulated by Metal‐Ion Coordination

ChemSusChem ◽  
2021 ◽  
Author(s):  
Xian Suo ◽  
Zhenzhen Yang ◽  
Yuqing Fu ◽  
Chi-Linh Do-Thanh ◽  
Dmitry Maltsev ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Metal Ion ◽  
Carbon Capture ◽  
New Generation

Dynamic Air-Brush Deposition Method for the New Generation of Graphene Based Supercapacitors

MRS Advances ◽  
2018 ◽  
Vol 3 (1-2) ◽  
pp. 79-84 ◽  
Author(s):  
Paolo Bondavalli ◽  
Gregory Pognon ◽  
Elias Koumoulos ◽  
Costas Charitidis
Keyword(s):  
Ionic Liquids ◽  
Point Of View ◽  
Harsh Environment ◽  
Deposition Method ◽  
Carbon Nanofibres ◽  
Roll To Roll ◽  
Reduced Graphene ◽  
The World ◽  
New Generation ◽  
Spray Gun

ABSTRACTThis contribution deals with the fabrication of a new generation of supercapacitors for harsh environment (avionics) based on nanostructures layers fabricated by spray-gun deposition method. Thanks to the fabrication of electrodes using spray-gun and the utilization of specific ionic liquids developed at Thales, we were able to achieve a capacitance of 20F/g (for a whole cell) and a power of 40kW/kg using carbon nanofibres (CNFs) mixed with reduced graphene oxide (RGO). These results are not the higher values obtained in literature but they are extremely interesting considering that the final device needs to stand temperature between -55°C and +105°C for avionics applications and that no commercial supercaps in the world are able to work in this interval. Only using these ionic liquids and the specific electrodes, it is possible. These supercapacitors were fabricated using spray-gun deposition method which is an extremely interesting technique from an industrial point of view considering that it can be easily implemented in roll-to-roll fabrication.

Analysis of essential oils and fragrances with a new generation of highly inert gas chromatographic columns coated with ionic liquids

2017 ◽  
Vol 1495 ◽  
pp. 64-75 ◽  
Author(s):  
Cecilia Cagliero ◽  
Carlo Bicchi ◽  
Chiara Cordero ◽  
Erica Liberto ◽  
Patrizia Rubiolo ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Essential Oils ◽  
Inert Gas ◽  
Chromatographic Columns ◽  
New Generation
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