Synthesis, structure and heterogeneous catalytic activity of a coordination polymer containing tetranuclear Cu(ii)-btp units connected by nitrates

2003 ◽  
pp. 1454-1456 ◽  
Author(s):  
Sang-Kun Yoo ◽  
Ji Young Ryu ◽  
Jun Yong Lee ◽  
Cheal Kim ◽  
Sung-Jin Kim ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Coordination Polymer ◽  
Heterogeneous Catalytic

scholarly journals A platinum(ii)–palladium(ii)–nickel(ii) heterotrimetallic coordination polymer showing a cooperative effect on catalytic hydrogen evolution

2017 ◽  
Vol 53 (5) ◽  
pp. 846-849 ◽  
Author(s):  
Naoto Kuwamura ◽  
Yoshinari Kurioka ◽  
Takumi Konno
Keyword(s):  
Catalytic Activity ◽  
Coordination Polymer ◽  
Metal Ions ◽  
Hydrogen Evolution ◽  
Cooperative Effect ◽  
Heterogeneous Catalytic ◽  
Catalytic Hydrogen ◽  
Group 10 ◽  
Catalytic Hydrogen Evolution

Stepwise construction of a 1D heterotrimetallic coordination polymer containing all three group 10 metal ions and its heterogeneous catalytic activity for electrochemical hydrogen evolution are reported.

Hydrogen peroxide decomposition on a two-component CuO-Cr2O3 catalyst

1988 ◽  
Vol 53 (8) ◽  
pp. 1636-1646 ◽  
Author(s):  
Viliam Múčka ◽  
Kamil Lang
Keyword(s):  
Hydrogen Peroxide ◽  
Catalytic Activity ◽  
Extreme Values ◽  
Catalytic Properties ◽  
Active Components ◽  
Catalytic Systems ◽  
Heterogeneous Catalytic ◽  
Peroxide Decomposition ◽  
Two Component ◽  
Catalytically Active

Some physical and catalytic properties of the two-component copper(II)oxide-chromium(III)oxide catalyst with different content of both components were studied using the decomposition of the aqueous solution of hydrogen peroxide as a testing reaction. It has been found that along to both basic components, the system under study contains also the spinel structure CuCr2O4, chromate washable by water and hexavalent ions of chromium unwashable by water. The soluble chromate is catalytically active. During the first period of the reaction the equilibrium is being established in both homogeneous and heterogeneous catalytic systems. The catalytic activity as well as the specific surface area of the washed solid is a non-monotonous function of its composition. It seems highly probable that the extreme values of both these quantities are not connected with the detected admixtures in the catalytic system. The system under study is very insensitive with regard to the applied doses of gamma radiation. Its catalytic properties are changed rather significantly after the thermal treatment and particularly after the partial reduction to low degree by hydrogen. The observed changes of the catalytic activity of the system under study are very probably in connection with the changes of the valence state of the catalytically active components of the catalyst.

A novel 2D vanadium(V)-isonicotinohydrazide coordination polymer, C15H16AgN4O8V: Synthesis, structure, catalytic activity and DFT calculation

Polyhedron ◽  
2011 ◽  
Vol 30 (11) ◽  
pp. 1842-1848 ◽  
Author(s):  
Hassan Hosseini Monfared ◽  
Sohaila Alavi ◽  
Afsaneh Farrokhi ◽  
Morteza Vahedpour ◽  
Peter Mayer
Keyword(s):  
Catalytic Activity ◽  
Coordination Polymer ◽  
Dft Calculation

Construction of solvent-dependent self-assembled porous Ni(ii)-coordinated frameworks as effective catalysts for chemical transformation of CO2

RSC Advances ◽  
2016 ◽  
Vol 6 (109) ◽  
pp. 108010-108016 ◽  
Author(s):  
Zhen Zhou ◽  
Lu Yang ◽  
Yefei Wang ◽  
Cheng He ◽  
Tao Liu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Chemical Transformation ◽  
Self Assembly ◽  
Ambient Conditions ◽  
Heterogeneous Catalytic ◽  
Self Assembled

Two types of Ni(ii)-based coordinated frameworks have been solvothermally synthesized via solvent driven self-assembly, showing efficient heterogeneous catalytic activity toward cycloaddition of CO2 with epoxides under ambient conditions.

A cyano-bridged copper(ii)–copper(i) mixed-valence coordination polymer as a source of copper oxide nanoparticles with catalytic activity in C–N, C–O and C–S cross-coupling reactions

2014 ◽  
Vol 38 (9) ◽  
pp. 4267-4274 ◽  
Author(s):  
Manoj Trivedi ◽  
Sanjeev kumar Ujjain ◽  
Raj Kishore Sharma ◽  
Gurmeet Singh ◽  
Abhinav Kumar ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Coordination Polymer ◽  
Copper Oxide ◽  
Mixed Valence ◽  
Cross Coupling ◽  
Copper Oxide Nanoparticles ◽  
Cuo Nanoparticles ◽  
Oxide Nanoparticles ◽  
Coupling Reactions ◽  
Cross Coupling Reactions

A cyano-bridged Cu(ii)–Cu(i) complex was synthesized and transformed into CuO nanoparticles. Their catalytic activity in C–N, C–O, and C–S cross-coupling reactions was explored.

Selective recognition of Fe3+ and CrO42− ions using a Zn(ii) metallacycle and a Cd(ii) coordination polymer and their heterogeneous catalytic application

CrystEngComm ◽  
2019 ◽  
Vol 21 (48) ◽  
pp. 7447-7459 ◽  
Author(s):  
Pooja Rani ◽  
Anjali Sharma ◽  
Ahmad Husain ◽  
Gulshan Kumar ◽  
Harpreet Kaur ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Selective Recognition ◽  
Heterogeneous Catalytic ◽  
Multifunctional Material ◽  
Catalytic Application

A Zn(ii) metallacycle [Zn2{(L)2(DMF)2(NO3)2}]·(NO3)2 (1) along with a Cd(ii) coordination polymer [{Cd(L)2(DMF)2}·(NO3)2]n (2) have been synthesized, structurally characterized and exploited as a multifunctional material.

A Manganese-Based Coordination Polymer; Synthesis, Structure and Catalytic Activity

2016 ◽  
Vol 40 (7) ◽  
pp. 422-427 ◽  
Author(s):  
Samir Alghool ◽  
Carla Slebodnick ◽  
Khaled F. Khaled
Keyword(s):  
Catalytic Activity ◽  
Coordination Polymer ◽  
Polymer Synthesis

scholarly journals Ni(ii)-based coordination polymers for efficient electrocatalytic oxygen evolution reaction

RSC Advances ◽  
2018 ◽  
Vol 8 (67) ◽  
pp. 38562-38565 ◽  
Author(s):  
Zhi-Qiang Jiang ◽  
Yu-Feng Li ◽  
Xue-Jun Zhu ◽  
Jin Lu ◽  
Lei Zhang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Coordination Polymer ◽  
Oxygen Evolution ◽  
Coordination Polymers ◽  
Oxygen Evolution Reaction ◽  
Fe Ions

An alkaline-stable cationic Ni(ii) coordination polymer showed remarkable oxygen evolution reaction (OER) catalytic activity due to capturing Fe ions.

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