Diastereoselective formation of a dipalladium(i) complex supported by a bridging tetradentate ligand, and oxidative addition of RS–H across a phosphine-bridged PdI–PdI bondElectronic supplementary information (ESI) available: full synthetic methods and characterisation data for compound 1 and the 2a–2f salts. See http://www.rsc.org/suppdata/cc/b3/b300177f/
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