Characteristic interface point defects at transition metal–oxide interfaces

2003 ◽  
Vol 5 (11) ◽  
pp. 2174-2182 ◽  
Author(s):  
Monika Backhaus-Ricoult
Keyword(s):  
Transition Metal ◽  
Metal Oxide ◽  
Point Defects ◽  
Transition Metal Oxide ◽  
Oxide Interfaces ◽  
Interface Point

Optimisation of Adhesion at Transition Metal-Oxide Interfaces by Processing at Well-Chosen Oxygen Activity

1999 ◽  
Vol 586 ◽  
Author(s):  
M. Backhaus-Ricoult
Keyword(s):  
Transition Metal ◽  
Metal Oxide ◽  
Interfacial Energy ◽  
Transition Metal Oxide ◽  
Adhesion Energy ◽  
Oxygen Activity ◽  
Oxide Interface ◽  
Stability Range ◽  
Oxide Interfaces ◽  
Adsorption Energies

ABSTRACTTransition metal-oxide interfaces suffer within their thermodynamic stability range Gibbs' adsorption and show important changes in chemical composition with oxygen activity. As a consequence, specific free interfacial energy and adhesion energy also vary with oxygen activity. Adhesion at a given non-reactive transition metal-oxide interface can then be optimised by establishing the proper oxygen activity during processing or by a post-treatment at the interface.In the present work, the approach of Gibbs' adsorption is extended to crystalline, anisotropic (special) transition metal-oxide interfaces. It is demonstrated that interfacial energy varies with oxygen activity. The variation in energy is studied for different adsorption energies, temperatures and interfacial planes.

Electronic structure at transition metal phthalocyanine-transition metal oxide interfaces: Cobalt phthalocyanine on epitaxial MnO films

2015 ◽  
Vol 142 (10) ◽  
pp. 101918 ◽  
Author(s):  
Mathias Glaser ◽  
Heiko Peisert ◽  
Hilmar Adler ◽  
Umut Aygül ◽  
Milutin Ivanovic ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Transition Metal ◽  
Metal Oxide ◽  
Transition Metal Oxide ◽  
Cobalt Phthalocyanine ◽  
Metal Phthalocyanine ◽  
Oxide Interfaces
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