[meso-Tetrakis(pentafluorophenyl)porphyrinato]platinum(ii) as an efficient, oxidation-resistant red phosphor: spectroscopic properties and applications in organic light-emitting diodesElectronic supplementary information available: details of photoluminescence measurements, transient absorption spectra of PtF20TPP, photophysical properties of PtF20TPP in different solvents, EL spectra and performances of OLEDs using PtF20TPP as emitters at various doping levels and crystallographic data for PtF20TPP. See http://www.rsc.org/suppdata/jm/b2/b212204a/

2003 ◽  
Vol 13 (6) ◽  
pp. 1362 ◽  
Author(s):  
Chi-Ming Che ◽  
Yuan-Jun Hou ◽  
Michael C. W. Chan ◽  
Jianhua Guo ◽  
Yu Liu ◽  
...  
2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
A. A. Chernonosov ◽  
E. A. Ermilov ◽  
B. Röder ◽  
L. I. Solovyova ◽  
O. S. Fedorova

Water solubility of phthalocyanines (Pcs) usually increases by the introduction of charged or carboxy substituents in the peripheral positions of the macrocycle. As a result, such structural changes influence their photophysical and photochemical properties as photosensitizers. Phthalocyanines substituted with four or eight terminal carboxyl groups and having in some cases additional eight positive charges (water soluble phthalocyanines) were studied in order to evaluate the spectroscopic and photophysical effects of these side residues on the chromophore properties. The quantum yield of singlet oxygen (O12) generation, the triplet-triplet absorption, and the transient absorption spectra were measured and linked to the structure of the substituents. It was shown that charged substituents did not change the quantum yields ofO12generation but decrease its lifetimes. The introduction of the charged substituents not only increases the water solubility but also significantly changes absorption, fluorescence, and transient absorption spectra of water soluble Pcs.


1990 ◽  
Vol 68 (12) ◽  
pp. 2164-2170 ◽  
Author(s):  
Bohdan Skalski ◽  
Stefan Paszyc ◽  
Ryszard W. Adamiak ◽  
Ronald P. Steer ◽  
Ronald E. Verrall

The absorption spectra, fluorescence spectra, fluorescence lifetimes, fluorescence quenching, phosphorescence spectra, phosphorescence lifetimes, and picosecond transient absorption spectra of several purinyl-pyridinium salts have been measured in several solvents at room temperature and in ethanol glasses at 77 K. It is concluded that the previously observed photochemical transformation of N-[9-(2′,3′,5′-tri-O-acetyl-β-D-ribofuranosyl)purin-6-yl]pyridinium chloride 1 into the highly fluorescent tri-O-acetylluminarosine 6 occurs via an excited triplet state. It is also shown that intersystem crossing in purinyl-pyridinium salts is induced by an intermolecular charge-transfer interaction with the counter ions. Keywords: purinyl-pyridinium salts, fluorescence, phosphorescence.


Nanoscale ◽  
2021 ◽  
Author(s):  
Jayanta Dana ◽  
Omer Haggag ◽  
Morin Mor ◽  
Joanna Dehnel ◽  
E Liftschitz ◽  
...  

Numerous studies have reported that transient absorption spectra in core CdSe nanocrystals do not register state filling in 1Sh, an absence which has profound consequences in light emitting applications. It...


Author(s):  
Julian Hniopek ◽  
Carolin Müller ◽  
Thomas Bocklitz ◽  
Michael Schmitt ◽  
Benjamin Dietzek ◽  
...  

2015 ◽  
Vol 32 (8) ◽  
pp. 1693
Author(s):  
Hong Liu ◽  
Yulei Bai ◽  
Yun Zhang ◽  
Shuangli Ye ◽  
Weichao Xu ◽  
...  

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