Yttrium alkyl complexes with a sterically demanding benzamidinate ligand: synthesis, structure and catalytic ethene polymerisationElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b2/b208502j/

2003 ◽  
pp. 522-523 ◽  
Author(s):  
Sergio Bambirra ◽  
Daan van Leusen ◽  
Auke Meetsma ◽  
Bart Hessen ◽  
Jan H. Teuben
2019 ◽  
Vol 55 (82) ◽  
pp. 12324-12327
Author(s):  
Deshuai Liu ◽  
Dahai Zhou ◽  
Hao Yang ◽  
Jianfeng Li ◽  
Chunming Cui

A four-coordinate yttrium dialkyl complex with a sterically demanding silaamidinate ligand exhibited high activity and excellent functional group tolerance for the catalysis of isocyanate cyclotrimerization.


2015 ◽  
Vol 39 (10) ◽  
pp. 7682-7687 ◽  
Author(s):  
Shiyu Long ◽  
Baoli Wang ◽  
Hongyan Xie ◽  
Changguang Yao ◽  
Chunji Wu ◽  
...  

The new rare-earth metal alkyl complexes bearing alkoxy NHC ligands were prepared, which showed moderate cis-1,4 selectivity for isoprene polymerization.


2017 ◽  
Vol 46 (40) ◽  
pp. 13628-13659 ◽  
Author(s):  
Reinhold Tacke ◽  
Tatjana Ribbeck

Silylenes 1–4 have great synthetic potential for the synthesis of higher coordinate silicon(ii) and silicon(iv) complexes with unprecedented structural motifs.


Author(s):  
Ahmad Fayoumi ◽  
Dmitry M. Lyubov ◽  
Andrey S. Shavyrin ◽  
Anton V. Cherkasov ◽  
Anatoly M. Ob’edkov ◽  
...  

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