Rapid and selective retro-aldol condensation of glucose to glycolaldehyde in supercritical water

2002 ◽  
Vol 4 (3) ◽  
pp. 285-287 ◽  
Author(s):  
Mitsuru Sasaki ◽  
Kohtaro Goto ◽  
Kiyohiko Tajima ◽  
Tadafumi Adschiri ◽  
Kunio Arai
Keyword(s):  
Supercritical Water ◽  
Aldol Condensation

Kinetics and Mechanism of Cellobiose Hydrolysis and Retro-Aldol Condensation in Subcritical and Supercritical Water

2002 ◽  
Vol 41 (26) ◽  
pp. 6642-6649 ◽  
Author(s):  
Mitsuru Sasaki ◽  
Momoko Furukawa ◽  
Kimitaka Minami ◽  
Tadafumi Adschiri ◽  
Kunio Arai
Keyword(s):  
Supercritical Water ◽  
Aldol Condensation ◽  
Kinetics And Mechanism ◽  
Cellobiose Hydrolysis

Characterization of Chemical Impurities in Glutaraldehyde

1975 ◽  
Vol 33 ◽  
pp. 620-621
Author(s):  
B. J. Grenon ◽  
A. J. Tousimis
Keyword(s):  
Glutaric Acid ◽  
Spectroscopic Analysis ◽  
Aldol Condensation ◽  
Condensation Product ◽  
Amorphous Solid ◽  
Water Soluble ◽  
Impurity Component ◽  
Chemical Impurities ◽  
Soluble Liquid

Ever since the introduction of glutaraldehyde as a fixative in electron microscopy of biological specimens, the identification of impurities and consequently their effects on biologic ultrastructure have been under investigation. Several reports postulate that the impurities of glutaraldehyde, used as a fixative, are glutaric acid, glutaraldehyde polymer, acrolein and glutaraldoxime.Analysis of commercially available biological or technical grade glutaraldehyde revealed two major impurity components, none of which has been reported. The first compound is a colorless, water-soluble liquid with a boiling point of 42°C at 16 mm. Utilizing Nuclear Magnetic Resonance (NMR) spectroscopic analysis, this compound has been identified to be — dihydro-2-ethoxy 2H-pyran. This impurity component of the glutaraldehyde biological or technical grades has an UV absorption peak at 235nm. The second compound is a white amorphous solid which is insoluble in water and has a melting point of 80-82°C. Initial chemical analysis indicates that this compound is an aldol condensation product(s) of glutaraldehyde.

PENGGUNAAN AIR SUPER KRITIS PADA DEPOLIMERISASI NYLON-12 (BATCH PROCESS)

2018 ◽  
Vol 5 (3) ◽  
Author(s):  
Mohamad Yusman
Keyword(s):  
Supercritical Water ◽  
Scale Up ◽  
Experimental Studies ◽  
Reaction System ◽  
Batch Process ◽  
Chemical Recycling ◽  
Water Decomposition ◽  
Product Distributions ◽  
New Process ◽  
Nylon 12

Water at the supercritical state is a new process for the chemical recycling. At this thermodynamic state i.e. Pc = 218 atmospheres and Tc = 374oC , water behaves very differently from its everyday temperament and it is a very good solvent for organic components. Experimental studies show that supercritical water can decompose hydrocarbons/polymers and produce useful products like 2-Azacyclotridecanone /lactam-1 from Nylon-12 (batch process). The decomposition process itself was carried out in batch reaction system in order to get more information about product distributions, time dependence, and scale-up possibilities.Keywords: supercritical water, decomposition, batch, polymer, hydrocarbon

Kinetics of Supercritical Water Oxidation. SERDP Compliance Technical Thrust Area

1996 ◽  
Author(s):  
Steven F. Rice ◽  
Richard R. Steeper ◽  
Russell G. Hanush ◽  
Jason D. Aiken ◽  
Eric Croiset
Keyword(s):  
Supercritical Water ◽  
Water Oxidation ◽  
Supercritical Water Oxidation ◽  
Kinetics Of

Kinetics of Supercritical Water Oxidation

1995 ◽  
Author(s):  
Steven F. Rice ◽  
Jefferson W. Tester ◽  
Kenneth Brezinsky
Keyword(s):  
Supercritical Water ◽  
Water Oxidation ◽  
Supercritical Water Oxidation ◽  
Kinetics Of
Sign in / Sign up

Export Citation Format

Share Document