The first asymmetrically ??-polysubstituted porphyrin-based hexagonal columnar liquid crystal

2002 ◽  
pp. 2348-2349 ◽  
Author(s):  
M. Castella ◽  
F. L??pez-Calahorra ◽  
D. Velasco ◽  
H. Finkelmann
2021 ◽  
Author(s):  
Mingguang Zhu ◽  
Meihui Chen ◽  
Hongyu Guo ◽  
Fafu Yang

Abstract A novel fluorescein-bridged perylene bisimide (PBI) dimer for liquid crystal (LC) with geometrically symmetric structure was developed. The mesomorphic results indicated that the energetically stable and unstable conformers of fluorescein fragments could lead to the transformation of mesophases from a hexagonal columnar mesophase to an uncertain phase at 136.9 °C in heating, whilst a stable hexagonal columnar mesophase maintained between 175.6 °C and 58.6 °C in cooling. The selectively excited fluorescence characters in THF solution demonstrated that the fluorescence resonance energy transfer (FRET) effect between fluorescein fragments and PBI unites could provide a means to effectively impose strong fluorescence of the dimeric PBIs modified with suitable chromophore at the N-imide position, which alternatively serves as a platform for the further study of multi-functional PBI-based LCs.


2007 ◽  
Author(s):  
F. Sanaa^ ◽  
M. Gharbia ◽  
Mourad Telmini ◽  
Najeh Thabet Mliki ◽  
Ezeddine Sediki

ChemInform ◽  
2003 ◽  
Vol 34 (9) ◽  
Author(s):  
M. Castella ◽  
F. Lopez-Calahorra ◽  
D. Velasco ◽  
H. Finkelmann

2011 ◽  
Vol 239-242 ◽  
pp. 2620-2623 ◽  
Author(s):  
Yan Ming Dong ◽  
Ya Qing Zhao ◽  
Er Man Zeng ◽  
Liu Lin Yang ◽  
Qiang Ge ◽  
...  

A novel dendronized cellulose,ethyl cellulose grafted 3,4,5-tris[4-(dodecyloxy) benzyloxy] benzoate (EC-g-DOBOB), which is comprised of ethyl cellulose (EC) backbone with mesogenic moiety DOBOB (3,4,5-tris(4-(dodecyloxy)benzyloxy)benzoic acid) dendron grafted, was designed and synthesized. The structure of EC-g-DOBOB was investigated by means of FTIR, Both thermotropic liquid crystal and lyotropic liquid crystal behaviors of EC-g-DOBOB were studied by combination of DSC, POM and XRD. At room temperature EC-g-DOBOB demonstrated hexagonal columnar mesophase (Φh), with the column diameter 5.8 nm, besides it formed lyotropic cholesteric liquid crystal in concentrated chloroform solution with a planar texture.


1999 ◽  
Vol 31 (6) ◽  
pp. 617-620 ◽  
Author(s):  
D. Knight ◽  
F. Vollrath

2021 ◽  
Vol 125 (10) ◽  
pp. 2761-2770
Author(s):  
Camille Bishop ◽  
Zhenxuan Chen ◽  
Michael F. Toney ◽  
Harald Bock ◽  
Lian Yu ◽  
...  

2011 ◽  
Vol 94 (10) ◽  
pp. 3267-3275 ◽  
Author(s):  
Hui Li ◽  
Yu Zhang ◽  
Hongfei Liu ◽  
John Wang

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