Unprecedented carbon dioxide effect on a Pd-catalysed oxidative carbonylation reaction: a new synthesis of pyrrole-2-acetic esters

2002 ◽  
pp. 1408-1409 ◽  
Author(s):  
Bartolo Gabriele ◽  
Giuseppe Salerno ◽  
Alessia Fazio ◽  
Fausto Bruno Campana
Keyword(s):  
Carbon Dioxide ◽  
Oxidative Carbonylation ◽  
Carbonylation Reaction ◽  
New Synthesis

Palladium-catalyzed carbonylation of 1,5-cyclooctadiene. Effects of temperature and pressure

1991 ◽  
Vol 56 (3) ◽  
pp. 663-672 ◽  
Author(s):  
Curtis B. Anderson ◽  
Rade Marković
Keyword(s):  
Carbon Monoxide ◽  
Oxidative Carbonylation ◽  
Influence Of Temperature ◽  
Carbonylation Reaction ◽  
Palladium Catalyzed ◽  
Effects Of Temperature ◽  
Temperature And Pressure

The influence of temperature and carbon monoxide pressure on the course of oxidative carbonylation reaction of 1,5-cyclooctadiene in the presence of the palladium(II) salts as a catalyst, was investigated.

Palladium-catalyzed synthesis of symmetrical urea derivatives by oxidative carbonylation of primary amines in carbon dioxide medium

2011 ◽  
Vol 282 (1) ◽  
pp. 120-127 ◽  
Author(s):  
Nicola Della Ca’ ◽  
Paolo Bottarelli ◽  
Angela Dibenedetto ◽  
Michele Aresta ◽  
Bartolo Gabriele ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Primary Amines ◽  
Oxidative Carbonylation ◽  
Urea Derivatives ◽  
Palladium Catalyzed

scholarly journals Catalyst Initiation in the Oscillatory Carbonylation Reaction

2011 ◽  
Vol 2011 ◽  
pp. 1-11 ◽  
Author(s):  
Katarina Novakovic ◽  
Julie Parker
Keyword(s):  
Carbon Monoxide ◽  
Chemical Reactions ◽  
Potassium Iodide ◽  
Significant Role ◽  
Reaction Network ◽  
Oxidative Carbonylation ◽  
Heat Of Reaction ◽  
Oscillatory Reaction ◽  
Oscillatory Behaviour ◽  
Carbonylation Reaction

Palladium(II) iodide is used as a catalyst in the phenylacetylene oxidative carbonylation reaction that has demonstrated oscillatory behaviour in both pH and heat of reaction. In an attempt to extract the reaction network responsible for the oscillatory nature of this reaction, the system was divided into smaller parts and they were studied. This paper focuses on understanding the reaction network responsible for the initial reactions of palladium(II) iodide within this oscillatory reaction. The species researched include methanol, palladium(II) iodide, potassium iodide, and carbon monoxide. Several chemical reactions were considered and applied in a modelling study. The study revealed the significant role played by traces of water contained in the standard HPLC grade methanol used.

scholarly journals Oxidative Carbonylation of Methanol to Dimethyl Carbonate in Ionic Liquid 1-Butyl-3-Methylimidazolium Hexafluorophosphate

2003 ◽  
Vol 2003 (9) ◽  
pp. 549-551 ◽  
Author(s):  
Tao Jiang ◽  
Buxing Han ◽  
Guoying Zhao ◽  
Yanhong Chang ◽  
Liang Gao ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquid ◽  
Supercritical Carbon Dioxide ◽  
Room Temperature ◽  
Dimethyl Carbonate ◽  
Room Temperature Ionic Liquid ◽  
Oxidative Carbonylation ◽  
Enhanced Selectivity ◽  
Supercritical Carbon

The synthesis of dimethyl carbonate (DMC) by oxidative carbonylation of methanol with PdCl2 as a catalyst was investigated in the room temperature ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]). The products were recovered in situ using supercritical carbon dioxide. Enhanced selectivity of DMC over this catalyst was observed in the synthesis in [bmim][PF6] compared with the situation without the ionic liquid (IL). The mixture of catalyst and [bmim][PF6] could be recycled.

ChemInform Abstract: The Reaction of 1,2-Amino Alcohols with Carbon Dioxide in the Presence of 2-Pyrrolidone Electrogenerated Base. New Synthesis of Chiral Oxazolidin-2-ones.

ChemInform ◽  
2000 ◽  
Vol 31 (47) ◽  
pp. no-no
Author(s):  
M. Antonietta Casadei ◽  
Marta Feroci ◽  
Achille Inesi ◽  
Leucio Rossi ◽  
Giovanni Sotgiu
Keyword(s):  
Carbon Dioxide ◽  
Amino Alcohols ◽  
New Synthesis

Novel Ring Closure Carbonylation Reaction of 1,5-Cyclooctadiene in the Presence of Pd(II)-Catalysts

1992 ◽  
Vol 57 (11) ◽  
pp. 2374-2382 ◽  
Author(s):  
Curtis B. Anderson ◽  
Rade Marković
Keyword(s):  
Carbon Monoxide ◽  
Double Bond ◽  
Methylene Chloride ◽  
Ring Closure ◽  
Oxidative Carbonylation ◽  
Experimental Conditions ◽  
Carbonylation Reaction ◽  
Methanol Mixture

Oxidative carbonylation of 1,5-cyclooctadiene in methylene chloride-methanol mixture, catalyzed by Pd(II)-salts, gave rise to a bicyclic, bifunctional product under mild experimental conditions. The mechanism, involving multiple carbon monoxide and double bond insertions into the Pd(II)-carbon σ-bond, has been proposed, as being consistent with the outcome of this novel ring closure reaction.

Sign in / Sign up

Export Citation Format

Share Document