[VIII(H2O)]3O(O2CC6H4CO2)3·(Cl, 9H2O) (MIL-59): a rare example of vanadocarboxylate with a magnetically frustrated three-dimensional hybrid framework

2002 ◽  
pp. 1492-1493 ◽  
Author(s):  
K. Barthelet ◽  
D. Riou ◽  
G. Férey
Keyword(s):  
Three Dimensional ◽  
Hybrid Framework

Synthesis and Characterisation of the First Three-Dimensional Mixed-Metal-Center Inorganic-Organic Hybrid Framework withN-(Phosphonomethyl)iminodiacetate

2004 ◽  
Vol 2004 (13) ◽  
pp. 2759-2768 ◽  
Author(s):  
Filipe A. Almeida Paz ◽  
Fa-Nian Shi ◽  
Jacek Klinowski ◽  
João Rocha ◽  
Tito Trindade
Keyword(s):  
Three Dimensional ◽  
Metal Center ◽  
Mixed Metal ◽  
Organic Hybrid ◽  
Hybrid Framework

A three-dimensional hybrid framework based on novel [Co4Mo4] bimetallic oxide clusters with 3,5-bis(3-pyridyl)-1,2,4-triazole ligands

2009 ◽  
Vol 65 (3) ◽  
pp. m128-m130 ◽  
Author(s):  
Quan-Guo Zhai ◽  
Shu-Ni Li ◽  
Man-Cheng Hu ◽  
Yu-Cheng Jiang
Keyword(s):  
Water Molecule ◽  
Three Dimensional ◽  
Hybrid Architecture ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Inorganic Hybrid ◽  
Solvent Water ◽  
Hybrid Complex ◽  
Hybrid Framework ◽  
Inorganic Layers

In the title organic–inorganic hybrid complex, poly[[[μ-3,5-bis(3-pyridyl)-1,2,4-triazole]tri-μ3-oxido-tetra-μ2-oxido-oxidodicobalt(II)dimolybdenum(VI)] monohydrate], {[Co2Mo2O8(C12H9N5)]·H2O}n, the asymmetric unit is composed of two CoIIcenters, two [MoVIO4] tetrahedral units, one neutral 3,5-bis(3-pyridyl)-1,2,4-triazole (BPT) ligand and one solvent water molecule. The cobalt centers both exhibit octahedral [CoO5N] coordination environments. Four CoIIand four MoVIcenters are linked by μ2-oxide and/or μ3-oxide bridges to give an unprecedented bimetallic octanuclear [Co4Mo4O22N4] cluster, which can be regarded as the first example of a metal-substituted octamolybdate and exhibits a structure different from those of the eight octamolybdate isomers reported to date. The bimetallic oxide clusters are linked to each other through corner-sharing to give two-dimensional inorganic layers, which are further bridged bytrans-BPT ligands to generate a three-dimensional organic–inorganic hybrid architecture with six-connected distorted α-Po topology.

Interface coassembly of mesoporous MoS2 based-frameworks for enhanced near-infrared light driven photocatalysis

2016 ◽  
Vol 52 (38) ◽  
pp. 6431-6434 ◽  
Author(s):  
Lihua Zhi ◽  
Haoli Zhang ◽  
Zhengyin Yang ◽  
Weisheng Liu ◽  
Baodui Wang
Keyword(s):  
Photocatalytic Activity ◽  
Room Temperature ◽  
Near Infrared ◽  
Three Dimensional ◽  
Infrared Light ◽  
Direct Arylation ◽  
Near Infrared Light ◽  
Nir Light ◽  
Hybrid Framework ◽  
First Time

The three-dimensional porous Fe3O4@Cu2−xS–MoS2 framework is reported for the first time. Such a hybrid framework exhibits excellent NIR-light photocatalytic activity and stable cycling for the direct arylation of heteroaromatics at room temperature.

scholarly journals A Hybrid Framework for High-Performance Modeling of Three-Dimensional Pipe Networks

2019 ◽  
Vol 8 (10) ◽  
pp. 441 ◽  
Author(s):  
Shaohua Wang ◽  
Yeran Sun ◽  
Yinle Sun ◽  
Yong Guan ◽  
Zhenhua Feng ◽  
...  
Keyword(s):  
Spatial Data ◽  
Data Model ◽  
High Performance ◽  
3D Model ◽  
Performance Modeling ◽  
Three Dimensional ◽  
Network Data ◽  
Pipe Network ◽  
Pipe Networks ◽  
Hybrid Framework

Three-dimensional (3D) pipe network modeling plays an essential part in high performance-based smart city applications. Given that massive 3D pipe networks tend to be difficult to manage and to visualize, we propose in this study a hybrid framework for high-performance modeling of a 3D pipe network, including pipe network data model and high-performance modeling. The pipe network data model is devoted to three-dimensional pipe network construction based on network topology and building information models (BIMs). According to the topological relationships of the pipe point pipelines, the pipe network is decomposed into multiple pipe segment units. The high-performance modeling of 3D pipe network contains a spatial 3D model, the instantiation, adaptive rendering, and combination parallel computing. Spatial 3D model (S3M) is proposed for spatial data transmission, exchange, and visualization of massive and multi-source 3D spatial data. The combination parallel computing framework with GPU and OpenMP was developed to reduce the processing time for pipe networks. The results of the experiments showed that the hybrid framework achieves a high efficiency and the hardware resource occupation is reduced.

scholarly journals Structure and Magnetic Properties of Three-Dimensional Gadolinium-Based Hybrid Framework

2014 ◽  
Vol 126 (1) ◽  
pp. 308-309 ◽  
Author(s):  
M. Almáši ◽  
A. Zeleňáková ◽  
I. Císařová ◽  
J. Bednarčík ◽  
V. Zeleňák
Keyword(s):  
Magnetic Properties ◽  
Three Dimensional ◽  
Hybrid Framework

A Hybrid Particle-Continuum Framework

2008 ◽  
Author(s):  
Matthew K. Borg ◽  
Jason M. Reese
Keyword(s):  
Three Dimensional ◽  
Computational Modelling ◽  
Numerical Code ◽  
Test Cases ◽  
Cfd Simulations ◽  
Hybrid Particle ◽  
Hybrid Framework ◽  
Computational Fluid Dynamics Cfd ◽  
Polyhedral Cells ◽  
The Individual

A new hybrid particle-continuum numerical code is currently being developed as an engineering tool for accurate and fast computational modelling of nanoflows. Molecular Dynamics (MD) and Computational Fluid Dynamics (CFD) are the components/solvers used within the particle and continuum zones respectively. In this paper the development of a two-component hybrid framework, based on domain-decomposition, is described. The main objective of the framework is to facilitate hybrid MD-CFD simulations within complex geometries, using a mesh of structured/unstructured arbitrary polyhedral cells, identical to that used in engineering CFD. This requires complex three-dimensional (3D) interfaces and overlap regions (comprising user-defined sub-regions) to be constructed between adjacent zones. The individual sub-regions serve as an appropriate means of exchanging information between components (i.e. coupling or boundary condition imposition), in 3D, during the hybrid simulation. The global domain is decomposed appropriately into MD and CFD sub-domains such that internal boundaries within the overlap regions become the external boundaries on the separate meshes, prior to commencing the hybrid simulations. The hybrid framework is implemented in OpenFOAM [1], an open source C++ CFD toolbox, using a general, case-independent approach and is parallelised. Two nanochannel test cases are investigated to show that the hybrid environment is flexible and well-suited for engineering design applications as well for the development of new hybrid codes and coupling models.

A novel three-dimensional hybrid framework based on fishbone-like copper halide inorganic units

2005 ◽  
Vol 358 (8) ◽  
pp. 2571-2574 ◽  
Author(s):  
Xiuli Bai ◽  
Yangguang Li ◽  
Enbo Wang ◽  
Lin Xu
Keyword(s):  
Three Dimensional ◽  
Copper Halide ◽  
Hybrid Framework

Three-Dimensional Hybrid Framework Containing U2O13Dimers Connected via Cation–Cation Interactions

2011 ◽  
Vol 50 (17) ◽  
pp. 7931-7933 ◽  
Author(s):  
Rachel C. Severance ◽  
Mark D. Smith ◽  
Hans-Conrad zur Loye
Keyword(s):  
Three Dimensional ◽  
Hybrid Framework
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