Toward a qualitative understanding of the initial electron transfer site in Dawson-type heteropolyanions

2002 ◽  
Vol 26 (10) ◽  
pp. 1314-1319 ◽  
Author(s):  
Bineta Keita ◽  
Yves Jean ◽  
Bernard Levy ◽  
Louis Nadjo ◽  
Roland Contant
Science ◽  
2007 ◽  
Vol 316 (5825) ◽  
pp. 747-750 ◽  
Author(s):  
H. Wang ◽  
S. Lin ◽  
J. P. Allen ◽  
J. C. Williams ◽  
S. Blankert ◽  
...  

1992 ◽  
Vol 2 (6) ◽  
pp. 836-842 ◽  
Author(s):  
Theodore J DiMagno ◽  
Zhiyu Wang ◽  
James R Norris

1990 ◽  
Vol 87 (13) ◽  
pp. 5168-5172 ◽  
Author(s):  
W. Holzapfel ◽  
U. Finkele ◽  
W. Kaiser ◽  
D. Oesterhelt ◽  
H. Scheer ◽  
...  

1992 ◽  
Vol 2 (12) ◽  
pp. 664
Author(s):  
Theodore J. DiMagno ◽  
Zhiyu Waniz ◽  
James R. Norris

Synthesis ◽  
2017 ◽  
Vol 50 (03) ◽  
pp. 617-624 ◽  
Author(s):  
Mariappan Periasamy ◽  
Gunda Rao

Tertiary cyclic N-arylamines react with nitromethane in the presence of the tert-butyl hydroperoxide (T-HYDRO)/t-BuOK system to give β-nitroamines in up to 90% yield. When TMSCN is used in place of nitromethane, α-aminonitriles are obtained in up to 96% yield. The method is suitable for several unactivated cyclic arylamine substrates. These transformations are rationalized considering the formation of the corresponding iminium ion intermediates via an initial electron transfer process.


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