A highly stereoselective synthesis of β-olivosides by glycosidations of 2-iodo-olivosyl fluoride using montmorillonite K-10 as an environmentally benign solid acid

2002 ◽  
Vol 4 (1) ◽  
pp. 27-29 ◽  
Author(s):  
Kazunobu Toshima ◽  
Keizou Uehara ◽  
Hideyuki Nagai ◽  
Shuichi Matsumura
Keyword(s):  
Stereoselective Synthesis ◽  
Solid Acid ◽  
Environmentally Benign

scholarly journals Palm Frond and Spikelet as Environmentally Benign Alternative Solid Acid Catalysts for Biodiesel Production

BioResources ◽  
2015 ◽  
Vol 10 (2) ◽  
Author(s):  
Yahaya Muhammad Sani ◽  
Aisha Olatope Raji-Yahya ◽  
Peter Adeniyi Alaba ◽  
Abdul Raman Abdul Aziz ◽  
Wan Mohd Ashri Wan Daud
Keyword(s):  
Solid Acid ◽  
Biodiesel Production ◽  
Solid Acid Catalysts ◽  
Environmentally Benign ◽  
Acid Catalysts ◽  
Palm Frond

Sorbitol dehydration into isosorbide over a cellulose-derived solid acid catalyst

RSC Advances ◽  
2016 ◽  
Vol 6 (55) ◽  
pp. 49528-49536 ◽  
Author(s):  
Jie Zou ◽  
Dong Cao ◽  
Weitong Tao ◽  
Shaoyin Zhang ◽  
Li Cui ◽  
...  
Keyword(s):  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
Environmentally Benign

The dehydration of sorbitol to isosorbide over an environmentally benign cellulose-derived solid acid catalyst (CCS) has been investigated in order to develop a sustainable process for isosorbide production.

scholarly journals Synthesis, Characterization and Catalytic Performance ofH3SiW12O40/SiO2Prepared by Sol-Gel Technique

2011 ◽  
Vol 2011 ◽  
pp. 1-6 ◽  
Author(s):  
W. N. R. W. Isahak ◽  
M. Ismail ◽  
N. M. Nordin ◽  
J. M. Jahim ◽  
M. A. Yarmo
Keyword(s):  
Heteropoly Acid ◽  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Sol Gel ◽  
Acid Catalyst ◽  
Catalytic Performance ◽  
Environmentally Benign ◽  
Esterification Reaction ◽  
Silicotungstic Acid ◽  
Gel Technique

The purpose of this work is to study the synthesis, characterization, and catalytic performance of two types of solid heteropoly acid catalysts, namely, silicotungstic acid bulk (STAB) and STA-silica sol-gel (STA-SG) compared with sulfuric acid. From the XPS analyses, there was a significant formation of W-O-Si, W-O-W, and Si-O-Si bonding in STA-SG compared to that in STAB. The main spectra of O1s (90.74%, 531.5 eV) followed by other O1s peak (9.26%, 532.8 eV) were due to the presence of W-O-W and W-O-Si bonds, respectively. The STA-SG catalyst was found to be the more environmentally benign solid acid catalyst for the esterification reaction between oleic acid and glycerol due to its lower toxicity supported by silica via sol-gel technique. In addition, the ease of separation for STA-SG catalyst was attributed to its insoluble state in the product phase. The esterification products were then analysed by FTIR and HPLC. Both the H2SO4and the STAB gave high conversion of 100% and 98% but at a lower selectivity of GME with 81.6% and 89.9%, respectively. On the contrary, the STA-SG enabled a conversion of 94% but with a significantly higher GME selectivity of 95%, rendering it the more efficient solid acid catalyst.

Envirocat EPZ-10: An Efficient Catalyst for the Synthesis of 1,2,4- Triazolidine-3-thiones

2020 ◽  
Vol 17 (4) ◽  
pp. 321-326
Author(s):  
Pradeep M. Mhaldar ◽  
Dattaprasad M. Pore
Keyword(s):  
Present Method ◽  
Room Temperature ◽  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
Environmentally Benign ◽  
Temperature Synthesis ◽  
Efficient Catalyst ◽  
Green Catalyst ◽  
Catalyst Reusability

A simple and environmentally benign room temperature synthesis of 1,2,4-triazolidine-3- thiones is described using Envirocat EPZ-10R as a solid acid catalyst in the aqueous medium. The use of Envirocat EPZ-10R as a green catalyst, reusability of the catalyst, water as a universal solvent and good yields of the product are the attractive features of the present method.

Environmentally benign aryl C-glycosidations of unprotected sugars using montmorillonite K-10 as a solid acid

1997 ◽  
Vol 38 (42) ◽  
pp. 7375-7378 ◽  
Author(s):  
Kazunobu Toshima ◽  
Yasunobu Ushiki ◽  
Goh Matsuo ◽  
Shuichi Matsumura
Keyword(s):  
Solid Acid ◽  
Environmentally Benign

scholarly journals An Efficient One-Pot Green Protocol for the Synthesis of 5-Unsubstituted 3,4-Dihydropyrimidin-2(1H)-Ones Using Recyclable Amberlyst 15 DRY as a Heterogeneous Catalyst via Three-Component Biginelli-Like Reaction

2012 ◽  
Vol 2012 ◽  
pp. 1-8 ◽  
Author(s):  
Srinivasa Rao Jetti ◽  
Divya Verma ◽  
Shubha Jain
Keyword(s):  
Heterogeneous Catalyst ◽  
Solid Acid ◽  
Environmentally Benign ◽  
Chemical Waste ◽  
One Pot ◽  
Efficient Catalyst ◽  
Amberlyst 15 ◽  
Green Protocol ◽  
Recyclable Heterogeneous Catalyst ◽  
Work Up

An environmentally benign green protocol for the synthesis of 5-unsubstituted 3,4-dihydropyrimidin-2(1H)-ones using Amberlyst 15 DRY as a recyclable catalyst has been developed. The use of resinous, nontoxic, thermally stable, and inexpensive Amberlyst 15 DRY, as a recyclable heterogeneous catalyst, makes the process simple with negligible chemical waste. Among the various solid acid catalysts Amberlyst 15 DRY was found to be the most efficient catalyst with regard to reaction time, yield, and ease of work-up procedure.

BF3/nano-sawdust as a green, biodegradable and inexpensive catalyst for the synthesis of highly substituted dihydro-2-oxopyrroles

RSC Advances ◽  
2015 ◽  
Vol 5 (20) ◽  
pp. 15566-15571 ◽  
Author(s):  
Bi Bi Fatemeh Mirjalili ◽  
Reza Zare Reshquiyea
Keyword(s):  
Solid Acid ◽  
Solid Acid Catalyst ◽  
Acid Catalyst ◽  
Environmentally Benign ◽  
One Pot ◽  
The One ◽  
Heterogeneous Solid

BF3/nano-sawdust was used as a readily available, inexpensive, biodegradable and environmentally benign heterogeneous solid acid catalyst for the one-pot cascade synthesis of highly functionalized dihydro-2-oxypyrroles.

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