Carbocyclic molecular clefts incorporating hydrogen bonding features

2002 ◽  
Vol 26 (6) ◽  
pp. 720-725 ◽  
Author(s):  
Jeremy D. Field ◽  
Peter Turner ◽  
Margaret M. Harding ◽  
Theano Hatzikominos ◽  
Linda Kim
2006 ◽  
Vol 47 (36) ◽  
pp. 6385-6388 ◽  
Author(s):  
Kyoung-Jin Chang ◽  
Min Kyung Chae ◽  
Changsoon Lee ◽  
Ji-Yeon Lee ◽  
Kyu-Sung Jeong

CrystEngComm ◽  
2011 ◽  
Vol 13 (14) ◽  
pp. 4748 ◽  
Author(s):  
Juan Saulo González-González ◽  
Francisco Javier Martínez-Martínez ◽  
Ana Lilia Peraza Campos ◽  
Maria de Jesus Rosales-Hoz ◽  
Efrén V. García-Báez ◽  
...  

2021 ◽  
Vol 8 ◽  
Author(s):  
Utsab Manna ◽  
Bobby Portis ◽  
Tochukwu K. Egboluche ◽  
Muhammad Nafis ◽  
Md. Alamgir Hossain

Two rationally designed 4-nitrophenyl-based molecular clefts functionalized with thiourea (L1) and urea (L2) have been synthesized and studied for a variety of anions by UV-Vis and colorimetric techniques in DMSO. Results from the binding studies suggest that both L1 and L2 bind halides showing the order: fluoride > chloride > bromide > iodide; and oxoanions showing the order: dihydrogen phosphate > hydrogen sulfate > nitrate > perchlorate. Each receptor has been shown to form a 1:1 complex with an anion via hydrogen bonding interactions, displaying distinct color change for fluoride and dihydrogen phosphate in solution. As compared to the urea-based receptor L2, the thiourea-based receptor L1 exhibits stronger affinity for anions due the presence of more acidic thiourea functional groups.


2000 ◽  
Vol 98 (3) ◽  
pp. 125-134 ◽  
Author(s):  
T. Weitkamp, J. Neuefeind, H. E. Fisch

1968 ◽  
Vol 65 ◽  
pp. 1587-1589 ◽  
Author(s):  
Bithika Ghosh ◽  
Sadhan Basu
Keyword(s):  

10.1002/jcc.2 ◽  
1996 ◽  
Vol 17 (16) ◽  
pp. 1804-1819 ◽  
Author(s):  
Attila Kov�cs ◽  
Istv�n Kolossv�ry ◽  
G�bor I. Csonka ◽  
Istv�n Hargittai

2017 ◽  
Vol 5 (4) ◽  
pp. 26-32 ◽  
Author(s):  
Azaria Robiana ◽  
M. Yashin Nahar ◽  
Hamidah Harahap

Glycerin residue is waste oleochemical industry that still contain glycerin. To produce quality and maximum quantity of glycerin, then research the effect of pH acidification using phosphoric acid. Glycerin analysis includes the analysis of pH, Fatty Acid and Ester (FAE), and analysis of the levels of glycerin. The maximum yield obtained at pH acidification 2 is grading 91,60% glycerin and Fatty Acid and Ester (FAE) 3,63 meq/100 g. Glycerin obtained is used as a plasticizer in the manufacture of bioplastics. Manufacture of bioplastics using the method of pouring a solution with varying concentrations of starch banana weevil (5% w/v and 7% w/v), variations of the addition of glycerin (1 ml, 3 ml, 5 ml and 7 ml), and a variety of gelatinization temperature (60°C, 70°C, and 80°C). Analysis of bioplastics include FTIR testing, tensile strength that is supported by SEM analysis. The results obtained in the analysis of FTIR does not form a new cluster on bioplastics starch banana weevil, but only a shift in the recharge area only, it is due to the addition of O-H groups originating from water molecules that enter the polysaccharide through a mechanism gelatinitation that generates interaction hydrogen bonding strengthened. The maximum tensile strength of bioplastics produced at a concentration of starch 7% w/v, 1 ml glycerine and gelatinization temperature of 80°C is 3,430 MPa. While the tensile strength bioplastic decreased with increasing glycerin which can be shown from the results of SEM where there is a crack, indentations and lumps of starch insoluble.


1963 ◽  
Vol 119 (3-4) ◽  
pp. 252-256 ◽  
Author(s):  
Brahama D. Sharma ◽  
Richard E. Marsh ◽  
Jerry Donohue
Keyword(s):  

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