An unusual energy transfer process from free-base porphyrin guests to a zinc porphyrin host in self-assembled systems

2002 ◽  
Vol 1 (3) ◽  
pp. 190-197 ◽  
Author(s):  
Lucia Flamigni ◽  
Anna Maria Talarico ◽  
Francesco Barigelletti ◽  
Martin R. Johnston
Keyword(s):  
Energy Transfer ◽  
Transfer Process ◽  
Energy Transfer Process ◽  
Free Base ◽  
Zinc Porphyrin ◽  
Self Assembled

Heat, quantum mechanics and information

2015 ◽  
Vol 10 (2) ◽  
pp. 2692-2695
Author(s):  
Bhekuzulu Khumalo
Keyword(s):  
Information Theory ◽  
Quantum Mechanics ◽  
Energy Transfer ◽  
Transfer Process ◽  
Energy Transfer Process ◽  
Process Information ◽  
Double Slit Experiment ◽  
Slit Experiment ◽  
Double Slit

Heat has often been described as part of the energy transfer process. Information theory says everything is information. If everything is information then what type of information is heat, this question can be settled by the double slit experiment, but we must know what we are looking for. 

Synthesis and Photophysical Properties of a Conformationally Flexible Mixed Porphyrin Star-Pentamer

2009 ◽  
Vol 62 (7) ◽  
pp. 692 ◽  
Author(s):  
Toby D. M. Bell ◽  
Sheshanath V. Bhosale ◽  
Kenneth P. Ghiggino ◽  
Steven J. Langford ◽  
Clint P. Woodward
Keyword(s):  
Energy Transfer ◽  
Photophysical Properties ◽  
Fluorescence Decay ◽  
High Yield ◽  
Free Base ◽  
Time Resolved ◽  
Zinc Porphyrin ◽  
Relative Contribution ◽  
Synthetic Strategy ◽  
Decay Times

The synthesis of a porphyrin star-pentamer bearing a free-base porphyrin core and four zinc(ii) metalloporphyrins, which are tethered by a conformationally flexible linker about the central porphyrin’s antipody, is described. The synthetic strategy is highlighted by the use of olefin cross metathesis to link the five chromophores together in a directed fashion in high yield. Photoexcitation into the Soret absorption band of the zinc porphyrin chromophores at 425 nm leads to a substantial enhancement of central free-base porphyrin fluorescence, indicating energy transfer from the photoexcited zinc porphyrin (outer periphery) to central free-base porphyrin. Time-resolved fluorescence decay profiles required three exponential decay components for satisfactory fitting. These are attributed to emission from the central free-base porphyrin and to two different rates of energy transfer from the zinc porphyrins to the free-base porphyrin. The faster of these decay components equates to an energy-transfer rate constant of 3.7 × 109 s–1 and an efficiency of 83%, whereas the other is essentially unquenched with respect to reported values for zinc porphyrin fluorescence decay times. The relative contribution of these two components to the initial fluorescence decay is ~3:2, similar to the 5:4 ratio of cis and trans geometric isomers present in the pentamer.

White light emission from a two-component hybrid gel via an energy transfer process

2015 ◽  
Vol 17 (48) ◽  
pp. 32297-32303 ◽  
Author(s):  
Xinhua Cao ◽  
Haichuang Lan ◽  
Zhenhua Li ◽  
Yueyuan Mao ◽  
Liming Chen ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Transfer Process ◽  
White Light ◽  
Light Emission ◽  
Light Harvesting ◽  
Energy Transfer Process ◽  
White Light Emission ◽  
Light Emitting ◽  
Hybrid Gel ◽  
Two Component

A two-component light-harvesting organogel containing a naphthalimide-based gelator as a donor and a phosphorescent Ir(iii) complex as an acceptor was used to produce white-light-emitting organogels.

Conditions for efficient charge generation preceded by energy transfer process in non-fullerene organic solar cells

2021 ◽  
Author(s):  
L. Benatto ◽  
C. A. M. Moraes ◽  
G. Candiotto ◽  
K. R. A. Sousa ◽  
J. P. A. Souza ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Solar Cells ◽  
Binding Energy ◽  
Transfer Process ◽  
Organic Solar Cells ◽  
Driving Force ◽  
Energy Transfer Process ◽  
Simple Relationship ◽  
Charge Generation ◽  
Efficient Charge

Our results provide a simple relationship involving the driving force and binding energy of CT state to maximize charge generation in non-fullerene organic solar cells.

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