Al-MCM-41: its acidity and activity in cyclohexene conversion

2001 ◽  
Vol 3 (22) ◽  
pp. 5082-5086 ◽  
Author(s):  
Michal Rozwadowski ◽  
Jerzy Datka ◽  
Maria Lezanska ◽  
Jerzy Wloch ◽  
Krzysztof Erdmann ◽  
...  
Keyword(s):  
Cyclohexene Conversion ◽  
Mcm 41

The design and catalytic performance of molybdenum active sites on an MCM-41 framework for the aerobic oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran

2019 ◽  
Vol 9 (3) ◽  
pp. 811-821 ◽  
Author(s):  
Zhao-Meng Wang ◽  
Li-Juan Liu ◽  
Bo Xiang ◽  
Yue Wang ◽  
Ya-Jing Lyu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Active Sites ◽  
Aerobic Oxidation ◽  
Catalytic Performance ◽  
Mcm 41

The catalytic activity decreases as –(SiO)3Mo(OH)(O) > –(SiO)2Mo(O)2 > –(O)4–MoO.

Benzene confined in MCM-41 below its melting point : A proton NMR study

2000 ◽  
Vol 10 (PR7) ◽  
pp. Pr7-99-Pr7-102 ◽  
Author(s):  
G. Dosseh ◽  
D. Morineau ◽  
C. Alba-Simionesco
Keyword(s):  
Melting Point ◽  
Proton Nmr ◽  
Nmr Study ◽  
Mcm 41

A neutron scattering investigation of the structural properties of glassforming m-toluidine confined in MCM-41

2000 ◽  
Vol 10 (PR7) ◽  
pp. Pr7-95-Pr7-98 ◽  
Author(s):  
D. Morineau ◽  
F. Casas ◽  
C. Alba-Simionesco ◽  
A. Grosman ◽  
M.-C. Bellissent-Funel ◽  
...  
Keyword(s):  
Neutron Scattering ◽  
Structural Properties ◽  
Mcm 41

Conversion of Biomass-Derived Carbohydrates to Methyl Lactate Using Sn-MCM-41 and SnO2/SiO2

2013 ◽  
Vol 33 (10) ◽  
pp. 1696-1705
Author(s):  
Zhen LIU ◽  
Gang FENG ◽  
Chunyan PAN ◽  
Wang LI ◽  
Ping CHEN ◽  
...  
Keyword(s):  
Methyl Lactate ◽  
Mcm 41

Electric Properties of MCM-41 SmCl3 Nanohybrid Encapsulate

2020 ◽  
Vol 12 (3) ◽  
pp. 03014-1-03014-5
Author(s):  
Fedir Ivashchyshyn ◽  
◽  
Dariusz Calus ◽  
Anna Pidluzhna ◽  
Piotr Chabecki ◽  
...  
Keyword(s):  
Electric Properties ◽  
Mcm 41

Nickel (II) and oxovanadium (IV) complexes supported on MCM-41 mesoporous and their application in catalytic selective sulfide and thiol oxidation

2020 ◽  
Vol 23 ◽  
Author(s):  
Mohsen Nikoorazm ◽  
Maryam Khanmoradi ◽  
Masoumeh Sayadian
Keyword(s):  
Catalytic Activity ◽  
Room Temperature ◽  
Sol Gel ◽  
Reaction Times ◽  
Significant Loss ◽  
Spectral Studies ◽  
High Catalytic Activity ◽  
Catalytic Systems ◽  
Solvent Free Conditions ◽  
Mcm 41

Introduction:: MCM-41 was synthesized using the sol-gel method. Then two new transition metal complexes of Nickel (II) and Vanadium (IV), were synthesized by immobilization of adenine (6-aminopurine) into MCM-41 mesoporous. The compounds have been characterized by XRD, TGA, SEM, AAS and FT-IR spectral studies. Using these catalysts provided an efficient and enantioselective procedure for oxidation of sulfides to sulfoxides and oxidative coupling of thiols to their corresponding disulfides using hydrogen peroxide at room temperature. Materials and Methods:: To a solution of sulfide or thiol (1 mmol) and H2O2 (5 mmol), a determined amount of the catalyst was added. The reaction mixture was stirred at room temperature for the specific time under solvent free conditions. The progress of the reaction was monitored by TLC using n-hexane: acetone (8:2). Afterwards, the catalyst was removed from the reaction mixture by centrifugation and, then, washed with dichloromethane in order to give the pure products. Results:: All the products were obtained in excellent yields and short reaction times indicating the high activity of the synthesized catalysts. Besides, the catalysts can be recovered and reused for several runs without significant loss in their catalytic activity. Conclusion:: These catalytic systems furnish the products very quickly with excellent yields and VO-6AP-MCM-41 shows high catalytic activity compared to Ni-6AP-MCM-41.

Adsorption of safranine T from aqueous medium by nano mesoporous MCM-41: adsorption equilibrium, kinetics, and thermodynamics

2020 ◽  
Vol 10 ◽  
Author(s):  
Xiao-Dong Li ◽  
Qing-Zhou Zhai
Keyword(s):  
Electron Microscopy ◽  
Ph Value ◽  
Particle Diameter ◽  
Spherical Particles ◽  
Practical Significance ◽  
Average Particle ◽  
Average Pore ◽  
Kinetics And Thermodynamics ◽  
Safranine T ◽  
Mcm 41

Introduction: In industrial production, a small amount of saffron T emissions will cause increase of water color and increase of chemical oxygen consumption, so study of the decolorization of saffron T wastewater has an important practical significance. Methods: MCM (Mobil Composition of Matter)-41 molecular sieve was synthesized by hydrothermal method. Power Xray diffraction and scanning electron microscopy were used to characterize the sample. Safranine T dye was adsorbed from water by the MCM-41 prepared. Kinetics and thermodynamics of the adsorption were studied. Results: The MCM-41 sample presented spherical particles and regular. The BET (Brunner-Emmett-Teller) specific surface area of the sample determined by 77 K low temperature nitrogen adsorption-desorption isotherm was 932 m2 /g. Its average particle diameter was 110 nm. TEM (transmission electron microscopy) results showed that the sample structure presented a honeycomb pore structure and the average pore diameter was 3.0 nm. The results showed that when room temperature was 20 ± 1 ℃, adsorbate safranine T: adsorbent MCM-41 = 20 : 1，the optimum pH value of adsorption was 4.0 and contact time was 20 min, the adsorption rate reached 98.29% and the adsorption capacity was 19.66 mg/g. The entropy change and enthalpy change of the adsorption system are respectively ΔS0 = 157.5 J/(mol·K); ΔH0 = 21.544 kJ/mol. When temperature was 277.15, 293.15, 303.15 K，the free energy change was respectively △G1 0 = -22.107 kJ/mol, △G2 0 = -24.627 kJ/mol, △G3 0 = -26.202 kJ/mol. Conclusion: The adsorption of safranine T by MCM-41 belongs to a pseudo-second-order adsorption. This adsorption accords with the Freundlich equation and belongs to a heterogeneous adsorption. The adsorption is an endothermic reaction of entropy increase, being spontaneous.

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