Cooperative effect of multiple hydrogen bonding involving the nitro group: solid state dimeric self-assembly of o-, m- and p-hydroxyphenyl-2,4-dinitrophenylhydrazones

2002 ◽  
Vol 26 (2) ◽  
pp. 243-249 ◽  
Author(s):  
Beata Szczęsna ◽  
Zofia Urbańczyk-Lipkowska
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Nitro Group ◽  
Self Assembly ◽  
Cooperative Effect ◽  
Multiple Hydrogen Bonding

Self-Assembly of Porphyrin Arrays by Hydrogen Bonding in the Solid State: An Orthogonal Porphyrin-Bisresorcinol System

1998 ◽  
Vol 4 (3) ◽  
pp. 417-424 ◽  
Author(s):  
Kenji Kobayashi ◽  
Masayuki Koyanagi ◽  
Ken Endo ◽  
Hideki Masuda ◽  
Yasuhiro Aoyama
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Self Assembly

scholarly journals {N 1-[2-(Butylselanyl)benzyl]-N 2,N 2-dimethylethane-1,2-diamine}dichloridomercury(II)

2018 ◽  
Vol 74 (8) ◽  
pp. 1151-1154
Author(s):  
Pushpendra Singh ◽  
Harkesh B. Singh ◽  
Ray J. Butcher
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Self Assembly ◽  
Title Compound ◽  
Supramolecular Assembly ◽  
Molecular Geometry ◽  
The Self ◽  
Intermolecular Hydrogen Bonding ◽  
Hydrogen Bonding Interactions ◽  
Donor Acceptor

In the title compound, [HgCl2(C16H28N2Se)], the primary geometry around the Se and Hg atoms is distorted trigonal–pyramidal and distorted square-pyramidal, respectively. The distortion of the molecular geometry in the complex is caused by the steric demands of the ligands attached to the Se atom. The Hg atom is coordinated through two chloride anions, an N atom and an Se atom, making up an unusual HgNSeCl2 coordination sphere with an additional long Hg...N interaction. Intermolecular C—H...Cl interactions are the only identified intermolecular hydrogen-bonding interactions that seem to be responsible for the self assembly. These relatively weak C—H...Cl hydrogen bonds possess the required linearity and donor–acceptor distances. They act as molecular associative forces that result in a supramolecular assembly along the b-axis direction in the solid state of the title compound.

Helical self-assembly of 2-(1,4,7,10-tetraazacyclododecan-1-yl)cyclohexan-1-ol (cycyclen)

2012 ◽  
Vol 68 (10) ◽  
pp. o383-o386 ◽  
Author(s):  
Alvaro S. de Sousa ◽  
Denzel Sannasy ◽  
Manuel A. Fernandes ◽  
Helder M. Marques
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Self Assembly ◽  
Amino Alcohol ◽  
Inner Core ◽  
Molecular Conformation ◽  
Tubular Structure ◽  
Macrocyclic Ring ◽  
Compound C ◽  
Hydrogen Bonding Interactions

The title macrocyclic amino alcohol compound, C14H30N4O, is investigated as a solid-state synthon for the design of a self-assembled tubular structure. It crystallizes in a helical column constructed by stereospecific O—H...N and N—H...N interactions. The hydrogen-bonding interactions, dependent upon macrocyclic ring helicity and molecular conformation, linkR,RandS,Senantiomers in a head-to-tail fashion, forming a continuous hydrophilic inner core.

Hydrogen-bonding control of molecular self-assembly: formation of a 2 + 2 complex in solution and in the solid state

1993 ◽  
Vol 115 (12) ◽  
pp. 5314-5315 ◽  
Author(s):  
Ji Yang ◽  
Erkang Fan ◽  
Steven J. Geib ◽  
Andrew D. Hamilton
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Self Assembly

Fibril formation through self-assembly of a simple glycine derivative and X-ray diffraction study

2020 ◽  
Vol 235 (1-2) ◽  
pp. 47-51
Author(s):  
Arpita Dutta ◽  
Suven Das ◽  
Purak Das ◽  
Suvendu Maity ◽  
Prasanta Ghosh
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
High Resolution ◽  
Diffraction Study ◽  
Self Assembly ◽  
Van Der Waals Interactions ◽  
Base Catalyst ◽  
X Ray Diffraction ◽  
X Ray ◽  
Sheet Structure

AbstractN-(N-benzoyl glycinyl)-N,N′-dicyclohexylurea was synthesised by conjugating N-benzoyl glycine and dicyclohexylcarbodiimide (DCC) using triethylamine as base catalyst. A single crystal X-ray diffraction study reveals that the compound self-assembles into a supramolecular sheet structure by intermolecular N–H · · · O, C–H · · · O hydrogen bonding and non-bonding van der Waals interactions. A high resolution transmission electronic microscopic (HR-TEM) image of the compound exhibits formation of fibrils in the solid state.

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