Photoswitching of the magnetic properties of one-dimensional π-electron systems. Part II. Conjugated polymers with di-hetarylethene and benzylidene-anthrone fragments in the elementary units

2001 ◽  
Vol 3 (20) ◽  
pp. 4600 ◽  
Author(s):  
Fritz Dietz ◽  
Nikolai Tyutyulkov
2003 ◽  
Vol 155 (1-3) ◽  
pp. 21-27 ◽  
Author(s):  
F. Dietz ◽  
A. Staykov ◽  
S. Karabunarliev ◽  
N. Tyutyulkov

Author(s):  
J. Fink

Conducting polymers comprises a new class of materials achieving electrical conductivities which rival those of the best metals. The parent compounds (conjugated polymers) are quasi-one-dimensional semiconductors. These polymers can be doped by electron acceptors or electron donors. The prototype of these materials is polyacetylene (PA). There are various other conjugated polymers such as polyparaphenylene, polyphenylenevinylene, polypoyrrole or polythiophene. The doped systems, i.e. the conducting polymers, have intersting potential technological applications such as replacement of conventional metals in electronic shielding and antistatic equipment, rechargable batteries, and flexible light emitting diodes.Although these systems have been investigated almost 20 years, the electronic structure of the doped metallic systems is not clear and even the reason for the gap in undoped semiconducting systems is under discussion.


Author(s):  
Mario Falsaperna ◽  
Gavin B G Stenning ◽  
Ivan da Silva ◽  
Paul James Saines

This study probes the structure and the magnetic properties of members of the Ln(HCO2)(C2O4) (Ln = Sm3+-Er3+) family of coordination frameworks. These frameworks adopt a Pnma orthorhombic structure with one-dimensional...


2009 ◽  
Vol 1183 ◽  
Author(s):  
Yôtarõ Nishio ◽  
Kôichirô Ishikawa ◽  
Shinji Kuroda ◽  
Masanori Mitome ◽  
Yoshio Bando

AbstractThe correlation between the Cr aggregation and magnetic properties are investigated for the series of Zn1-xCrxTe films grown by MBE with a systematic variation of growth conditions. Structural and chemical analyses using TEM and energy-dispersive X-ray spectroscopy (EDS) reveal that the crystallinity and the Cr distribution change significantly with the substrate temperature during the MBE growth. For a relatively low average Cr content x ≅ 0.05, it is found that the crystal quality is improved with the increase of the substrate temperature. For a higher average Cr content x ≅ 0.2, the shape of Cr-rich regions is transformed from isolated clusters into one-dimensional nanocolumns with the increase of the substrate temperature. The direction of the nanocolumn formation changes depending on the crystallographic orientation of the grown films. In the magnetization measurements, anisotropic magnetic properties are observed in the films in which Cr-rich nanocolumns are formed in the vertical direction, depending on the relation between the direction of the nanocolumns and the applied magnetic fields.


2007 ◽  
Vol 360 (8) ◽  
pp. 2523-2531 ◽  
Author(s):  
Young Sin You ◽  
Jung Hee Yoon ◽  
Jeong Hak Lim ◽  
Hyoung Chan Kim ◽  
Chang Seop Hong

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