Alumina: a cheap, active and selective catalyst for epoxidations with (aqueous) hydrogen peroxide

2001 ◽  
Vol 3 (5) ◽  
pp. 243-246 ◽  
Author(s):  
Michiel C. A. van Vliet ◽  
Dalmo Mandelli ◽  
Isabel W. C. E. Arends ◽  
Ulf Schuchardt ◽  
Roger A. Sheldon
Keyword(s):  
Hydrogen Peroxide ◽  
Aqueous Hydrogen Peroxide ◽  
Selective Catalyst

scholarly journals Metal-Organic Frameworks in Oxidation Catalysis with Hydrogen Peroxide

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 283
Author(s):  
Oxana Kholdeeva ◽  
Nataliya Maksimchuk
Keyword(s):  
Hydrogen Peroxide ◽  
Liquid Phase ◽  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Short Review ◽  
Catalytic Performance ◽  
Oxidation Catalysis ◽  
Catalyst Stability ◽  
Aqueous Hydrogen Peroxide ◽  
Metal Organic

In recent years, metal–organic frameworks (MOFs) have received increasing attention as selective oxidation catalysts and supports for their construction. In this short review paper, we survey recent findings concerning use of MOFs in heterogeneous liquid-phase selective oxidation catalysis with the green oxidant–aqueous hydrogen peroxide. MOFs having outstanding thermal and chemical stability, such as Cr(III)-based MIL-101, Ti(IV)-based MIL-125, Zr(IV)-based UiO-66(67), Zn(II)-based ZIF-8, and some others, will be in the main focus of this work. The effects of the metal nature and MOF structure on catalytic activity and oxidation selectivity are analyzed and the mechanisms of hydrogen peroxide activation are discussed. In some cases, we also make an attempt to analyze relationships between liquid-phase adsorption properties of MOFs and peculiarities of their catalytic performance. Attempts of using MOFs as supports for construction of single-site catalysts through their modification with heterometals will be also addressed in relation to the use of such catalysts for activation of H2O2. Special attention is given to the critical issues of catalyst stability and reusability. The scope and limitations of MOF catalysts in H2O2-based selective oxidation are discussed.

Farringtonite as an efficient catalyst for linear-chain α-olefin epoxidation with aqueous hydrogen peroxide

2021 ◽  
Author(s):  
Xingyu Yang ◽  
Xu Li ◽  
Jinxiang Dong
Keyword(s):  
Hydrogen Peroxide ◽  
Transition Metals ◽  
Linear Chain ◽  
Olefin Epoxidation ◽  
Aqueous Hydrogen Peroxide ◽  
Efficient Catalyst ◽  
First Time

A convenient, scalable, benign, and efficient epoxidation method based on farringtonite, without the use of transition metals, was developed for the first time.

Titanium Dioxide-Supported Sulfonated Low Rank Coal as Catalysts in the Oxidation of Styrene with Aqueous Hydrogen Peroxide

2014 ◽  
Vol 69 (5) ◽  
Author(s):  
Mukhamad Nurhadi ◽  
Jon Efendi ◽  
Lee Siew Ling ◽  
Teuku Meurah Indra Mahlia ◽  
Ho Chin Siong ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Titanium Dioxide ◽  
Catalytic Activity ◽  
Diffuse Reflectance Spectroscopy ◽  
Low Rank ◽  
Bet Surface Area ◽  
High Catalytic Activity ◽  
Low Rank Coal ◽  
X Ray Diffraction ◽  
Aqueous Hydrogen Peroxide

Titanium dioxide supported sulfonated low rank coal catalyst possesses high catalytic activity in liquid phase oxidation of styrene with aqueous hydrogen peroxide at room temperature. The catalysts were prepared by sulfonation with concentrated sulfuric acid and impregnation of titanium dioxide (500-2500 µmol). The effect of titanium dioxide impregnation and calcinations on the catalysts were studied by X-ray diffraction, UV-vis diffuse reflectance spectroscopy, Fourier transform infrared spectroscopy, BET surface area, field emission scanning electron microscopy and hydrophobicity measurement. The catalytic activity of the catalysts in the oxidation of styrene by aqueous H2O2 without calcination increased when the amount of titanium dioxide increased. Meanwhile, the catalytic activity of the catalyst calcined at 500oC for 2 h was lower than before calcination. It is suggested that the agglomeration of titanium dioxide and hydrophobicity play important role in the catalytic activity of titanium dioxide-supported sulfonated low rank coal in the oxidation of styrene with aqueous H2O2. 

scholarly journals A bottom up approach towards artificial oxygenases by combining iron coordination complexes and peptides

2017 ◽  
Vol 8 (5) ◽  
pp. 3660-3667 ◽  
Author(s):  
Olaf Cussó ◽  
Michael W. Giuliano ◽  
Xavi Ribas ◽  
Scott J. Miller ◽  
Miquel Costas
Keyword(s):  
Hydrogen Peroxide ◽  
Coordination Complexes ◽  
Asymmetric Epoxidation ◽  
Coordination Complex ◽  
High Yield ◽  
Aqueous Hydrogen Peroxide ◽  
Bottom Up ◽  
Iron Coordination

The combination of peptides and a chiral iron coordination complex catalyzes high yield highly asymmetric epoxidation with aqueous hydrogen peroxide.

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