Ambient temperature reversible addition–fragmentation chain transfer polymerisation

2001 ◽  
pp. 1044-1045 ◽  
Author(s):  
John F. Quinn ◽  
Thomas P. Davis ◽  
Ezio Rizzardo
Keyword(s):  
Ambient Temperature ◽  
Chain Transfer ◽  
Reversible Addition

A facile route to segmented copolymers by fusing ambient temperature step-growth and RAFT polymerization

2017 ◽  
Vol 53 (77) ◽  
pp. 10648-10651 ◽  
Author(s):  
Thomas Gegenhuber ◽  
Alexander M. Schenzel ◽  
Anja S. Goldmann ◽  
Per B. Zetterlund ◽  
Christopher Barner-Kowollik
Keyword(s):  
Ambient Temperature ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Diels Alder ◽  
Facile Synthesis ◽  
Segmented Copolymers ◽  
Reversible Addition ◽  
Step Growth ◽  
Step Growth Polymerization ◽  
Facile Route

We introduce the facile synthesis of segmented copolymers via a catalyst-free Diels–Alder (DA) reaction at ambient temperature via step-growth polymerization and subsequent reversible addition fragmentation chain transfer (RAFT) polymerization.

Reversible addition–fragmentation chain transfer polymerization initiated with γ-radiation at ambient temperature: an overview

2003 ◽  
Vol 39 (3) ◽  
pp. 449-459 ◽  
Author(s):  
Leonie Barner ◽  
John F Quinn ◽  
Christopher Barner-Kowollik ◽  
Philipp Vana ◽  
Thomas P Davis
Keyword(s):  
Ambient Temperature ◽  
Chain Transfer ◽  
Γ Radiation ◽  
Reversible Addition ◽  
Chain Transfer Polymerization

Tailored Design of Au Nanoparticle-siRNA Carriers Utilizing Reversible Addition−Fragmentation Chain Transfer Polymers∥

2010 ◽  
Vol 11 (4) ◽  
pp. 1052-1059 ◽  
Author(s):  
Stacey Kirkland-York ◽  
Yilin Zhang ◽  
Adam E. Smith ◽  
Adam W. York ◽  
Faqing Huang ◽  
...  
Keyword(s):  
Chain Transfer ◽  
Au Nanoparticle ◽  
Reversible Addition ◽  
Tailored Design

Self-Healing Hydrophobic POSS-functionalized Fluorinated Copolymer via RAFT Polymerization and dynamic Diels-Alder Reaction

2021 ◽  
Author(s):  
Siva Ponnupandian ◽  
Prantik Mondal ◽  
Thomas Becker ◽  
Richard Hoogenboom ◽  
Andrew B Lowe ◽  
...  
Keyword(s):  
Chain Transfer ◽  
Raft Polymerization ◽  
Alder Reaction ◽  
Diels Alder ◽  
Self Healing ◽  
Diels Alder Reaction ◽  
Reversible Addition

This investigation reports the preparation of a tailor-made copolymer of furfuryl methacrylate (FMA) and trifluoroethyl methacrylate (TFEMA) via reversible addition-fragmentation chain transfer (RAFT) polymerization. The furfuryl groups of the copolymer...

scholarly journals Synthesis of aminated polystyrene and its self-assembly with nanoparticles at oil/water interface

e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 317-327
Author(s):  
Chenliang Shi ◽  
Ling Lin ◽  
Yukun Yang ◽  
Wenjia Luo ◽  
Maoqing Deng ◽  
...  
Keyword(s):  
Interfacial Tension ◽  
Self Assembly ◽  
Carbon Dots ◽  
Chain Transfer ◽  
Functionalized Polymers ◽  
Amino Groups ◽  
One Dimensional ◽  
Reversible Addition ◽  
Oil Water ◽  
Chain Transfer Polymerization

AbstractThe influence of density of amino groups, nanoparticles dimension and pH on the interaction between end-functionalized polymers and nanoparticles was extensively investigated in this study. PS–NH2 and H2N–PS–NH2 were prepared using reversible addition–fragmentation chain transfer polymerization and atom transfer radical polymerization. Zero-dimensional carbon dots with sulfonate groups, one-dimensional cellulose nanocrystals with sulfate groups and two-dimensional graphene with sulfonate groups in the aqueous phase were added into the toluene phase containing the aminated PS. The results indicate that aminated PS exhibited the strongest interfacial activity after compounding with sulfonated nanoparticles at a pH of 3. PS ended with two amino groups performed better in reducing the water/toluene interfacial tension than PS ended with only one amino group. The dimension of sulfonated nanoparticles also contributed significantly to the reduction in the water/toluene interfacial tension. The minimal interfacial tension was 4.49 mN/m after compounding PS–NH2 with sulfonated zero-dimensional carbon dots.

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