Metal ions in hydrogen bonded solvents: a gas phase perspective

2001 ◽  
Vol 3 (11) ◽  
pp. 1935-1941 ◽  
Author(s):  
A. J. Stace
Keyword(s):  
Metal Ions ◽  
Gas Phase ◽  
Hydrogen Bonded

The effect of partial exchange of sulphonated macroporous styrene-divinylbenzene copolymers for different ions on their catalytic activity

1981 ◽  
Vol 46 (10) ◽  
pp. 2354-2363 ◽  
Author(s):  
Svatomír Kmošták ◽  
Karel Setínek
Keyword(s):  
Catalytic Activity ◽  
Transition Metal ◽  
Metal Ions ◽  
Gas Phase ◽  
Transition Metal Ions ◽  
Exchange Capacity ◽  
Total Exchange Capacity ◽  
Styrene Divinylbenzene ◽  
Na Ions ◽  
Type Of Transition

The catalytic activity of sulphonated macroporous styrene-divinylbenzene copolymers, the exchange capacity of which was neutralized from 30, 50 and 80% by Fe(III) ions and from 30% by Na ions and that of Wofatit Y-37 ion exchanger neutralized from 10% of its total exchange capacity by several transition metal ions and by sodium has been studied in isomerisation of cyclohexene and dehydration of 1-propanol in the gas phase at 130 °C. It was demonstrated that in both reactions transition metal ions exhibit additional effect to the expected neutralization of the polymer acid groups. In the case of cyclohexene isomerization, this effect depends on the degree of crosslinking of polymer mass of the catalyst. Such dependence has not been, however, observed in dehydration of 1-propanol. The type of transition metal ions did not exhibit any significant effect on the catalytic activity of the polymer catalysts studied.

scholarly journals PQQ-Aza-Crown Ether Complexes as Biomimetics for Lanthanide and Calcium Dependent Alcohol Dehydrogenases

2021 ◽  
Author(s):  
Violeta A. Vetsova ◽  
Katherine R. Fisher ◽  
Henning Lumpe ◽  
Alexander Schäfer ◽  
Erik K. Schneider ◽  
...  
Keyword(s):  
Metal Ions ◽  
Gas Phase ◽  
Ion Mobility ◽  
Paramagnetic Resonance ◽  
Calcium Dependent ◽  
Lower Charge ◽  
Crown Ether Complexes ◽  
Recent Group ◽  
Electron Paramagnetic

<div>Understanding the role of metal ions in biology can lead to the development of new catalysts for</div><div>several industrially important transformations. Lanthanides are the most recent group of metal ions</div><div>that have been shown to be important in biology i.e. - in quinone-dependent methanol</div><div>dehydrogenases (MDH). Here we evaluate a pyrroloquinoline quinone and 1-aza-15-crown-5 based</div><div>ligand platform as scaffold for Ca2+ , Ba2+ , La3+ and Lu3+ biomimetics of MDH and we evaluate the</div><div>importance of ligand design, charge, size, counterions and base for the alcohol oxidation reaction</div><div>using NMR spectroscopy. In addition, we report a new straightforward synthetic route (3 steps</div><div>instead of 11 and 33% instead of 0.6% yield) for biomimetic ligands based on PQQ. We show that</div><div>when studying biomimetics for MDH, larger metal ions and those with lower charge in this case</div><div>promote the dehydrogenation reaction more effectively and that this is likely an effect of the ligand</div><div>design which must be considered when studying biomimetics. To gain more information on the</div><div>structures and impact of counterions of the complexes, we performed collision induced dissociation</div><div>(CID) experiments and observe that the nitrates are more tightly bound than the triflates. To resolve</div><div>the structure of the complexes in the gas phase we combined DFT-calculations and ion mobility</div><div>measurements (IMS). Furthermore, we characterized the obtained complexes and reaction mixtures</div><div>using Electron Paramagnetic Resonance (EPR) spectroscopy and show the emergence of a quinone-</div><div>based radical during the reaction with substrate and base.</div>

Hydrogen-Bonded Complex between Ozone and Thioperoxy Radical in Gas-Phase

2008 ◽  
Vol 24 (11) ◽  
pp. 2065-2070
Author(s):  
YUAN Kun ◽  
◽  
◽  
LIU Yan-Zhi ◽  
ZHU Yuan-Cheng ◽  
...  
Keyword(s):  
Gas Phase ◽  
Hydrogen Bonded

Spectroscopic investigations of hydrogen bonding interactions in the gas phase. II. The determination of the geometry and potential constants of the hydrogen-bonded heterodimer CH 3 CN • • • HF from its microwave rotational spectrum

1980 ◽  
Vol 370 (1741) ◽  
pp. 239-255 ◽  
Keyword(s):  
Hydrogen Bonding ◽  
Gas Phase ◽  
Spectroscopic Constants ◽  
Rotational Spectrum ◽  
Hydrogen Bonding Interactions ◽  
Isotopic Species ◽  
Microwave Rotational Spectrum ◽  
Vibration Rotation ◽  
Hydrogen Bonded

The microwave rotational spectrum of the hydrogen-bonded heterodimer CH 3 CN • • • HF has been identified and shown to be characteristic of a symmetric top. A detailed analysis of several rotational transitions for a variety of isotopic species gives the spectroscopic constants summarized in the following table: Rotational constants/MHz, vibration-rotation constants/MHz and vibrational separations/cm -1 of CH 3 CN • • • HF

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