Thermodynamic stereoselectivity assisted by weak interactions in metal complexes. Chiral recognition of L/D-amino acids by the copper(II) complex of 6-deoxy-6-[4-(2-aminoethyl)imidazolyl]cyclomaltoheptaose

2001 ◽  
pp. 1366-1373 ◽  
Author(s):  
Raffaele P. Bonomo ◽  
Vincenzo Cucinotta ◽  
Giuseppe Maccarrone ◽  
Enrico Rizzarelli ◽  
Graziella Vecchio
Keyword(s):  
Amino Acids ◽  
Metal Complexes ◽  
Chiral Recognition ◽  
Weak Interactions

scholarly journals Functionalised Terpyridines and Their Metal Complexes—Solid-State Interactions

Chemistry ◽  
2021 ◽  
Vol 3 (1) ◽  
pp. 199-227
Author(s):  
Young Hoon Lee ◽  
Jee Young Kim ◽  
Sotaro Kusumoto ◽  
Hitomi Ohmagari ◽  
Miki Hasegawa ◽  
...  
Keyword(s):  
Solid State ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Weak Interactions ◽  
Dispersion Interactions ◽  
Derivatives Of

Analysis of the weak interactions within the crystal structures of 33 complexes of various 4′-aromatic derivatives of 2,2′:6′,2″-terpyridine (tpy) shows that interactions that exceed dispersion are dominated, as expected, by cation⋯anion contacts but are associated with both ligand–ligand and ligand–solvent contacts, sometimes multicentred, in generally complicated arrays, probably largely determined by dispersion interactions between stacked aromatic units. With V(V) as the coordinating cation, there is evidence that the polarisation of the ligand results in an interaction exceeding dispersion at a carbon bound to nitrogen with oxygen or fluorine, an interaction unseen in the structures of M(II) (M = Fe, Co, Ni, Cu, Zn, Ru and Cd) complexes, except when 1,2,3-trimethoxyphenyl substituents are present in the 4′-tpy.

Chiral Recognition and Separation of Amino Acids by Means of a Copper(II) Complex of Histamine Monofunctionalized .beta.-Cyclodextrin

1994 ◽  
Vol 116 (22) ◽  
pp. 10267-10274 ◽  
Author(s):  
Roberto Corradini ◽  
Arnaldo Dossena ◽  
Giuseppe Impellizzeri ◽  
Giuseppe Maccarrone ◽  
Rosangela Marchelli ◽  
...  
Keyword(s):  
Amino Acids ◽  
Chiral Recognition ◽  
Beta Cyclodextrin

The Use of Chiral Recognition in a Bioorganic System for Determination of Optical Purity of Labelled Amino Acids

2010 ◽  
Vol 91 (5) ◽  
pp. 491-491
Author(s):  
G. Bergson ◽  
C. Halldin ◽  
H. Lundqvist ◽  
B. Långström ◽  
M. Malmqvist
Keyword(s):  
Amino Acids ◽  
Chiral Recognition ◽  
Optical Purity

ChemInform Abstract: HOST-GUEST COMPLEXATION. 22. RECIPROCAL CHIRAL RECOGNITION BETWEEN AMINO ACIDS AND DILOCULAR SYSTEMS

1980 ◽  
Vol 11 (25) ◽  
Author(s):  
S. S. PEACOCK ◽  
D. M. WALBA ◽  
F. C. A. GAETA ◽  
R. C. HELGESON ◽  
D. J. CRAM
Keyword(s):  
Amino Acids ◽  
Chiral Recognition

Metallkomplexe mit biologisch wichtigen Liganden, CXLVI [1]. Bis(allyl)-N,O-α-Aminocarboxylat-Rhodium-Komplexe / Metal Complexes of Biologically Important Ligands, CXLVI [1]. Bis(allyl)-N,O-α-Aminocarboxylate-Rhodium Complexes

2002 ◽  
Vol 57 (7) ◽  
pp. 810-818 ◽  
Author(s):  
Walter Ponikwar ◽  
Peter Mayer ◽  
Wolfgang Beck
Keyword(s):  
Amino Acids ◽  
Metal Complexes ◽  
Dynamic Behaviour ◽  
Rhodium Complexes ◽  
X Ray Diffraction ◽  
X Ray ◽  
H Nmr

The reactions of [(η3-C3H5)2Rh-μ-Cl]2 with the anions of α-amino acids (glycine, L-alanine, L-valine, L-isoleucine, L-proline, L-phenylalanine, L-phenylglycine, L-thyrosine) afford the N,O-chelates (η3-C3H5)2Rh(α-amino carboxylate). For complex (η3-C3H5)2Rh(glycinate) dynamic behaviour in solution could be observed by 1H NMR. The structure of (η3-C3H5)2Rh(L-prolinate) was determined by X-ray diffraction.

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