How hydrogen bonding affects ligand binding and fluxionality in transition metal complexes: a DFT study on interligand hydrogen bonds involving HF and H2O

2001 ◽  
Vol 25 (1) ◽  
pp. 66-72 ◽  
Author(s):  
Eric Clot ◽  
Odile Eisenstein ◽  
Robert H. Crabtree
Keyword(s):  
Hydrogen Bonding ◽  
Transition Metal ◽  
Hydrogen Bonds ◽  
Ligand Binding ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Dft Study

Endo- and exohedral chloro-fulleride as η5 ligands: A DFT study on the first-row transition metal complexes

2021 ◽  
Author(s):  
Sebastian Anila ◽  
Cherumuttathu Hariharan Suresh
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Dft Study ◽  
C60 Fullerene ◽  
Ring Fusion ◽  
Coordination Modes

C60 fullerene coordinates to transition metals in η2-fashion through its C-C bond at [6,6] ring fusion whereas other coordination modes η3, η4, η5 and η6 are rarely observed. The coordination...

Synthesis, crystal structure, hydrogen bonding and spectroscopy of transition-metal complexes with the ligand (N,N′-bis(2-pyridylmethyl)-1,3-propanediamine)

Polyhedron ◽  
2009 ◽  
Vol 28 (14) ◽  
pp. 2813-2820 ◽  
Author(s):  
Aminou Mohamadou ◽  
Gerard A. van Albada ◽  
Ilpo Mutikainen ◽  
Urho Turpeinen ◽  
Jérôme Marrot ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes

Theoretical investigation of the coordination of dibenzazepine to transition-metal complexes: A DFT study

Polyhedron ◽  
2010 ◽  
Vol 29 (13) ◽  
pp. 2722-2730 ◽  
Author(s):  
Sara Farah ◽  
Saïda Ababsa ◽  
Nora Benhamada ◽  
Bachir Zouchoune
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Theoretical Investigation ◽  
Dft Study

Synthesis and Ligand Binding of η6-(2β-Carbomethoxy-3β-phenyltropane) Transition Metal Complexes

1996 ◽  
Vol 39 (7) ◽  
pp. 1560-1563 ◽  
Author(s):  
Blake Aronson ◽  
Jennifer L. Enmon ◽  
Sari Izenwasser ◽  
Jonathan L. Katz ◽  
Shreekrishna V. Kelkar ◽  
...  
Keyword(s):  
Transition Metal ◽  
Ligand Binding ◽  
Metal Complexes ◽  
Transition Metal Complexes

scholarly journals Template Synthesis, Characterization and Reactivities of Anionic Transition Metal Complexes with Tetraaza Protonated 11,13-Dimethyl-1,4,7,10- tetraazacyclotrideca-4,6,10,13-tetraene-5,6-Diol as Cation

2019 ◽  
Vol 31 (12) ◽  
pp. 2924-2930
Author(s):  
B. Vimala ◽  
S.R. Jayapradha ◽  
A. Selvan
Keyword(s):  
Hydrogen Bonding ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Template Synthesis ◽  
Spectral Studies ◽  
Ph Variation ◽  
Anionic Complexes

Template synthesis, characterization and reactivities of anionic transition metal complexes with tetraazaprotonated 11,13-dimethyl-1,4,7,10-tetraazacyclotrideca-4,6,10,13-tetraene-5,6-diol as cation has been achieved. By magnetic and spectral studies, hexachlorometallate(II) anionic complexes have been found to be octahedral. It is envisioned that the cationic macrocycle may be associating with both the complex and chloride anions through hydrogen bonding thereby rendering the molecule as a whole neutral. Deprotonation, protonation analysis and chemosensor behaviour have been showed by pH variation studies and relevant anionic additions, respectively. All of these data supports the newly synthesized anionic complexes in a strange manner.

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