Ni/SiO2 catalyst with hierarchical pore structure prepared by phase separation in sol–gel process

2000 ◽  
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pp. 4983-4990 ◽  
Author(s):  
Norifumi Nakamura ◽  
Ryoji Takahashi ◽  
Satoshi Sato ◽  
Toshiaki Sodesawa ◽  
Satoshi Yoshida
2001 ◽  
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pp. 197-202 ◽  
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Satoshi Sato ◽  
Toshiaki Sodesawa ◽  
Miyuki Yabuki

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Edith Mawunya Kutorglo ◽  
Jakub Kovačovič ◽  
Dan Trunov ◽  
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Anna Fučíková ◽  
...  

Nano Letters ◽  
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...  

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Vol 768 ◽  
pp. 211-217 ◽  
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Yu Kun Sun ◽  
Bao Jia Qi Jiang ◽  
Hui Yang ◽  
Xing Zhong Guo

Macroporous Ca12Al14O33(C12A7) mayenite monoliths have been successfully prepared via a sol-gel process in the presence of propylene oxide (PO) and poly (ethyleneoxide) (PEO). Gelation of CaO-Al2O3binary system with nitrates salts as additional precursors is accelerated by PO as an acid scavenger, while PEO works as a phase separation inducer to mediate the phase separation of the system. Appropriate PO and PEO amounts allow the formation of monolithic xerogel with interconnected macropores and co-continuous skeletons. The resultant dried gels are amorphous and the single crystalline phase Ca12Al14O33mayenite forms after heat-treatment at 1100 °C in air, while the macrostructure is preserved with a porosity as high as 78% and smoother and denser skeletons.


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