The glass transition relaxation in a side-chain liquid crystalline polymer studied by modulated temperature differential scanning calorimetry

2000 ◽  
Vol 2 (20) ◽  
pp. 4743-4747 ◽  
Author(s):  
Cristina Alvarez ◽  
Joaquim J. Moura-Ramos
2011 ◽  
Vol 181-182 ◽  
pp. 47-50
Author(s):  
Xin De Tang ◽  
Ye Chen ◽  
Xin Wang ◽  
Fa Qi Yu ◽  
Mei Shan Pei

A novel liquid crystalline polymer bearing azobenzene groups in both main chain and side chain has been successfully synthesized by atom transfer radical polymerization (ATRP). Dual bromide-terminated azobenzene was used as the initiator for the ATRP of azobenzene-containing monomer (M6C). The structure of the resulting polymer was confirmed by nuclear magnetic resonance (NMR), and the molecular weight and its dispersity was characterized by gel permeation chromatography (GPC). The mesomorphic properties of this novel polymer were characterized by means of polarized optical microscopy (POM) and differential scanning calorimetry (DSC). The results demonstrated that this polymer can form mesophases.


2010 ◽  
Vol 428-429 ◽  
pp. 98-101
Author(s):  
Chen Xi Zhang ◽  
Shao Rong Lu ◽  
Jian Feng Ban

Hyperbranched liquid crystalline polymer (HLCP) were prepared by pentaerythritol with 1,2,4-benzenetricarboxylic anhydride(BTCA) and p-hydroxy benzoic acid. The thermotropic properties, the melting point (Tm) and the isotropization temperature (Ti) of the synthesized HLCP were characterized by differential scanning calorimetry (DSC), fourier transform infrared spectroscopy (FTIR) and polarizing optical microscopy (POM). It showed that the new reactive thermotropic liquid polymer containing polyester mesogenic units exhibited thermotropic liquid crystalline properties between 140°C and 230°C.


Polymer ◽  
2000 ◽  
Vol 41 (8) ◽  
pp. 2907-2914 ◽  
Author(s):  
C. Alvarez ◽  
N.T. Correia ◽  
J.J. Moura Ramos ◽  
A.C. Fernandes

2012 ◽  
Vol 1 (5) ◽  
pp. 641-645 ◽  
Author(s):  
Jun-Feng Zheng ◽  
Xin Liu ◽  
Xiao-Fang Chen ◽  
Xiang-Kui Ren ◽  
Shuang Yang ◽  
...  

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