Carbon–oxygen and carbon–sulfur bond activation of vinyl esters, ethers and sulfides by low valent ruthenium complexes †

2000 ◽  
pp. 2613-2625 ◽  
Author(s):  
Jose Giner Planas ◽  
Tsuyoshi Marumo ◽  
Yoichi Ichikawa ◽  
Masafumi Hirano ◽  
Sanshiro Komiya
Keyword(s):  
Bond Activation ◽  
Ruthenium Complexes ◽  
Vinyl Esters ◽  
Low Valent ◽  
Sulfur Bond

C–O and C–S bond activation of allyl esters, ethers, and sulfides by low valent ruthenium complexes

1999 ◽  
Vol 147 (1-2) ◽  
pp. 137-154 ◽  
Author(s):  
Jose Giner Planas ◽  
Tsuyoshi Marumo ◽  
Yoichi Ichikawa ◽  
Masafumi Hirano ◽  
Sanshiro Komiya
Keyword(s):  
Bond Activation ◽  
Ruthenium Complexes ◽  
Low Valent ◽  
Allyl Esters

Bond activation by low valent ruthenium complexes

2003 ◽  
pp. 1439-1453 ◽  
Author(s):  
Sanshiro Komiya ◽  
Masafumi Hirano
Keyword(s):  
Bond Activation ◽  
Ruthenium Complexes ◽  
Low Valent

Bond Activation by Low Valent Ruthenium Complexes

ChemInform ◽  
2004 ◽  
Vol 35 (1) ◽  
Author(s):  
Sanshiro Komiya ◽  
Masafumi Hirano
Keyword(s):  
Bond Activation ◽  
Ruthenium Complexes ◽  
Low Valent

Selective Bond Cleavage Reactions by Low-Valent Ruthenium Complexes

ChemInform ◽  
2003 ◽  
Vol 34 (18) ◽  
Author(s):  
Masafumi Hirano ◽  
Nobuyuki Komine ◽  
Sanshiro Komiya
Keyword(s):  
Bond Cleavage ◽  
Ruthenium Complexes ◽  
Cleavage Reactions ◽  
Low Valent

Low-Valent Ruthenium Complexes of the Non-innocent 2,6-Bis(imino)pyridine Ligand

2010 ◽  
Vol 29 (3) ◽  
pp. 591-603 ◽  
Author(s):  
Michelle Gallagher ◽  
Noah L. Wieder ◽  
Vladimir K. Dioumaev ◽  
Patrick J. Carroll ◽  
Donald H. Berry
Keyword(s):  
Ruthenium Complexes ◽  
Pyridine Ligand ◽  
Low Valent

Novel Intramolecular CAryl–S Bond Activation by an Electron Rich, Ring-Expanded-NHC-Rh centre: A Combined Experimental and DFT Study

2011 ◽  
Vol 64 (8) ◽  
pp. 1141 ◽  
Author(s):  
Abeer Binobaid ◽  
Kingsley J. Cavell ◽  
Mikhail S. Nechaev ◽  
Benson M. Kariuki
Keyword(s):  
Bond Activation ◽  
Reaction Pathway ◽  
Heterocyclic Carbenes ◽  
Dft Study ◽  
Dft Studies ◽  
X Ray ◽  
Carbene Complex ◽  
Donor Capacity ◽  
Insight Into ◽  
Sulfur Bond

The reaction of (o-MeSPh)-N-functionalized tetrahydropyrimidinium salts with KN(SiMe3)2 and [Rh(COD)Cl]2 in THF leads to the formation of a novel dimeric RhIII bis-carbene complex. The reaction involves the unexpected cleavage/oxidative addition of the aryl-sulfur bond to give dimeric metallated RhIII with bridging MeS< moieties. This unusual reaction is probably a consequence of the sterically imposing structure and strong donor capacity of ring-expanded N-heterocyclic carbenes (RE-NHCs). An X-ray structure of the [(Ph,DIPP-NHC)Rh(Cl)(SMe)2] product complex has been obtained, and DFT studies were undertaken to gain an insight into the reaction pathway.

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