Complexation of uranyl ions by polyphenols. Crystal structures of two linear oligomers and one uranyl ion complex

Author(s):  
Pierre Thuéry ◽  
Martine Nierlich ◽  
Zouhair Asfari ◽  
Jacques Vicens
1993 ◽  
Vol 58 (8) ◽  
pp. 1813-1820 ◽  
Author(s):  
Jan Vácha ◽  
Lumír Sommer

The sorption of uranyl ions on columns with the macrophorus hydrophobic sorbent Amberlite XAD 4 modified with 1-(2-pyridylazo)-2-naphthol and sodium diethyldithiocarbamate was examined. Following elution of the uranyl ion with HNO3 (2 - 4 mol l-1) or of the diethyldithiocarbamate UO22+-chelate with a methanolic solution of HCl (0.1 mol l-1), uranium was determined spectrophotometrically with 4-(2-pyridylazo)resorcinol or with 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol. The preconcentration of uranium on Amberlite XAD 4 type sorbents is convenient for its spectrophotometric determination in waters.


2021 ◽  
Vol 290 ◽  
pp. 01007
Author(s):  
Jin Bai ◽  
Yang Yi ◽  
Xilin Xiao ◽  
Yi Ge

Ion imprinted polymer is a kind of three-dimensional material with special cavity structure. Its cavity site has the function of specifically recognizing and binding target ions. It is a kind of materials that can selectively combine, enrich and remove target ions in the environment. Uranium is an important radioactive element, which has been widely used in nuclear power, military industry, science and technology and other fields. However, the accumulation of uranyl ions in environmental water causes serious health hazards to human body. Therefore, the detection and enrichment of uranyl ions in water is of great significance. In this paper, the theory, technology and application status of ion imprinted polymer for micro detection and adsorption of uranyl particles in wastewater were reviewed, and the development of uranyl ion imprinted polymer was prospected.


Author(s):  
Ghada El-Gamal ◽  
Wael Mortada ◽  
Mohammed Hassanien ◽  
Amr Awad Ibrahim ◽  
Yasmeen Gaber Abou El-Reash

The accurate determination of thorium (Th4+) in the existence of uranyl ion (UO22+) is a challenge facing analytical chemists. In this article, a solidified floating organic drop microextraction procedure (SFODME)...


Langmuir ◽  
2000 ◽  
Vol 16 (19) ◽  
pp. 7368-7372 ◽  
Author(s):  
M. Francesca Ottaviani ◽  
Paolo Favuzza ◽  
Massimo Bigazzi ◽  
Nicholas J. Turro ◽  
Steffen Jockusch ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (12) ◽  
pp. 9563-9570 ◽  
Author(s):  
A. A. Elabd ◽  
O. A. Elhefnawy ◽  
A. M. El Nahrawy

A new organic-silica based nanocomposite has been prepared for uranyl ion (UO22+) determination based on the absorbance enhancement of tartrazine incorporated copper sodium silicate nanocomposites (T-CSS).


2003 ◽  
Vol 15 (5) ◽  
pp. 359-365 ◽  
Author(s):  
Pierre Thuéry ◽  
Jeong Tae Gil ◽  
Takehiko Yamato

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