Synthesis and gas permeation properties of an NaA zeolite membrane

2000 ◽  
pp. 603-604 ◽  
Author(s):  
Xiaochun Xu ◽  
Weishen Yang ◽  
Jie Liu ◽  
Xiaobo Chen ◽  
Liwu Lin ◽  
...  
2005 ◽  
Vol 249 (1-2) ◽  
pp. 51-64 ◽  
Author(s):  
Xiaochun Xu ◽  
Yun Bao ◽  
Chunshan Song ◽  
Weishen Yang ◽  
Jie Liu ◽  
...  

2020 ◽  
Vol 6 (2) ◽  
pp. 146-155
Author(s):  
Asep Hadian Hadinata ◽  
Agnes Rezky Siahaan ◽  
Mohamad Ghifary ◽  
Dewi Agustina Iryani ◽  
Engela Evy Ernawati

Ramie (Boehmeria nivea) is one type of plant used to produce high quality cellulose fiber. Its fiber is convertible to cellulose acetate (CA), which is commonly used as membrane’s material. Dense CA membrane is used in gas permeation process and the performance is improvable by mineral blending and annealing. This study aims to determine the characteristics of modified CA membranes and the performance in separation of CO2/CH4 gases. Membrane preparation was carried out by using phase inversion technique, while annealing was carried out at 60oC. Furthermore, NaA zeolite was added with various concentrations, which include 5, 10, 15 and 20%. Gas permeation was carried out at 4 barrer for an hour. The performance of the membrane was measured based on its permeability and selectivity. The results showed that CA membrane with 10% zeolite yielded the best performance with CO2 and CH4 permeability of 140.55 and 22.25 barrer respectively and selectivity of CO2/CH4 6.32.


2017 ◽  
Vol 204 (10) ◽  
pp. 1157-1166 ◽  
Author(s):  
Nong Xu ◽  
Sang Moon Lee ◽  
Sung Su Kim ◽  
Anwu Li ◽  
C. Jim Lim ◽  
...  

Membranes ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 249
Author(s):  
Yasuhisa Hasegawa ◽  
Chie Abe ◽  
Mayumi Natsui ◽  
Ayumi Ikeda

The polycrystalline CHA-type zeolite layer with Si/Al = 18 was formed on the porous α-Al2O3 tube in this study, and the gas permeation properties were determined using single-component H2, CO2, N2, CH4, n-C4H10, and SF6 at 303–473 K. The membrane showed permeation behavior, wherein the permeance reduced with the molecular size, attributed to the effect of molecular sieving. The separation performances were also determined using the equimolar mixtures of N2–SF6, CO2–N2, and CO2–CH4. As a result, the N2/SF6 and CO2/CH4 selectivities were as high as 710 and 240, respectively. However, the CO2/N2 selectivity was only 25. These results propose that the high-silica CHA-type zeolite membrane is suitable for the separation of CO2 from CH4 by the effect of molecular sieving.


2014 ◽  
Vol 1053 ◽  
pp. 389-393
Author(s):  
Zhi Lin Cheng ◽  
Ying Ying Liu

The highly intergrown NaA zeolite membranes on seeded α-Al2O3substrate were synthesized by microwave heating method. The preparation of seeds with the size of ca.120nm employed the vapor phase transport method (VPT). The XRD patterns indicated that the pure NaA zeolite membranes formed on the seeded α-Al2O3substrate for varied synthesis times. However, the peak intensity of NaA zeolite membrane with synthesis time of 50min obviously decreased, suggesting that the NaA membrane could take place the dissolution at that time. The SEM images indicated that the NaA zeolite membranes with synthesis time of 15-30min had a good integrity and consisted of highly intergrown zeolite crystals, but the NaA membrane with synthesis time of 50min appeared some large defects, further verifying the result of XRD pattern. The gas permeability showed that the maximum of H2/N2and H2/C3H8permselectivities attained 4.23 and 8.24, respectively, higher than those of the corresponding Knudsen diffusion. These results suggested that the diffusion of gases, at least in part, are affected by the pore size of zeolite and the function of molecular sieving can be embodied on the synthesized membrane.


1998 ◽  
Vol 41 (3) ◽  
pp. 325-330 ◽  
Author(s):  
Xiaochun Xu ◽  
Mojie Cheng ◽  
Weishen Yang ◽  
Liwu Lin

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