Potentiometric titration of long chain tertiary amine oxides and tertiary amines using a poly(vinyl chloride) membrane electrode

The Analyst ◽  
1994 ◽  
Vol 119 (10) ◽  
pp. 2201
Author(s):  
Brent Walton
2020 ◽  
Vol 40 (10) ◽  
pp. 842-847
Author(s):  
Shankar Suman ◽  
Ram Singh

AbstractA new poly (vinyl chloride) (PVC) membrane electrode using 2-benzoylpyridine semicarbazone as membrane carrier with dioctylphthalate as plasticizer and sodium tetraphenylborate (NaTBP) as anion excluder has been fabricated and investigated as Zn(II)-selective electrode. Best potential response is observed for the composition PVC 30%, plasticizer 58%, NaTBP 8% and ionophore 4% (w/w). The sensor showed a linear stable response over a concentration range of 1.0 × 10−2–4.56 × 10−6 M with a detection limit of 2.28 × 10−6 M and a response time <10 s. The electrode can be used for at least six months without any divergence in potential.


2007 ◽  
Vol 33 (1) ◽  
pp. 201-209 ◽  
Author(s):  
K. W. Small ◽  
F. Yearsley ◽  
J. C. Greaves

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