Nitrate ion-selective electrodes based on quaternary phosphonium salts in plasticized poly(vinyl chloride) and influence of membrane homogeneity on their performance

The Analyst ◽  
1991 ◽  
Vol 116 (4) ◽  
pp. 361 ◽  
Author(s):  
Manassis G. Mitrakas ◽  
Costas A. Alexiades ◽  
Vissarion Z. Keramidas
Keyword(s):  
Vinyl Chloride ◽  
Ion Selective Electrodes ◽  
Phosphonium Salts ◽  
Nitrate Ion ◽  
Poly Vinyl Chloride ◽  
Quaternary Phosphonium Salts

Nitrate ion selective electrodes based on poly(vinyl chloride) matrix membranes

The Analyst ◽  
1972 ◽  
Vol 97 (1151) ◽  
pp. 87 ◽  
Author(s):  
J. E. W. Davies ◽  
G. J. Moody ◽  
J. D. R. Thomas
Keyword(s):  
Vinyl Chloride ◽  
Ion Selective Electrodes ◽  
Nitrate Ion ◽  
Poly Vinyl Chloride ◽  
Chloride Matrix ◽  
Matrix Membranes

scholarly journals Potentiometric Carboxylate Sensors Based on Carbazole-Derived Acyclic and Macrocyclic Ionophores

Chemosensors ◽  
2020 ◽  
Vol 9 (1) ◽  
pp. 4
Author(s):  
Ville Yrjänä ◽  
Indrek Saar ◽  
Mihkel Ilisson ◽  
Sandip A. Kadam ◽  
Ivo Leito ◽  
...  
Keyword(s):  
Detection Limit ◽  
Vinyl Chloride ◽  
Anion Exchanger ◽  
Linear Range ◽  
Ph Sensitivity ◽  
Ion Selective Electrodes ◽  
Solid Contact ◽  
Response Characteristics ◽  
Potentiometric Response ◽  
Poly Vinyl Chloride

Solid-contact ion-selective electrodes with carbazole-derived ionophores were prepared. They were characterized as acetate sensors, but can be used to determine a number of carboxylates. The potentiometric response characteristics (slope, detection limit, selectivity, and pH sensitivity) of sensors prepared with different membrane compositions (ionophore, ionophore concentration, anion exchanger concentration, and plasticizer) were evaluated. The results show that for the macrocyclic ionophores, a larger cavity provided better selectivity. The sensors exhibited modest selectivity for acetate but good selectivity for benzoate. The carbazole-derived ionophores effectively decreased the interference from lipophilic anions, such as bromide, nitrate, iodide, and thiocyanate. The selectivity, detection limit, and linear range were improved by choosing a suitable plasticizer and by reducing the ionophore and anion exchanger concentrations. The influence of the electrode body’s material upon the composition of the plasticized poly(vinyl chloride) membrane, and thus also upon the sensor characteristics, was also studied. The choice of materials for the electrode body significantly affected the characteristics of the sensors.

All solid-state poly(vinyl chloride) membrane ion-selective electrodes with poly(3-octylthiophene) solid internal contact

The Analyst ◽  
1994 ◽  
Vol 119 (9) ◽  
pp. 1985 ◽  
Author(s):  
Johan Bobacka ◽  
Mary McCarrick ◽  
Andrzej Lewenstam ◽  
Ari Ivaska
Keyword(s):  
Solid State ◽  
Vinyl Chloride ◽  
Ion Selective Electrodes ◽  
Poly Vinyl Chloride ◽  
Internal Contact

Comparison of the selectivity of propeller crowns in poly(vinyl chloride) membrane ion-selective electrodes

The Analyst ◽  
1988 ◽  
Vol 113 (6) ◽  
pp. 895 ◽  
Author(s):  
Arthur K. Covington ◽  
Howard Grey ◽  
Patricia M. Kelly ◽  
Kenneth I. Kinnear ◽  
Joyce C. Lockhart
Keyword(s):  
Vinyl Chloride ◽  
Ion Selective Electrodes ◽  
Poly Vinyl Chloride

Poly(vinyl chloride) ion-selective electrodes for Piribedil determination

2000 ◽  
Vol 23 (2-3) ◽  
pp. 493-502 ◽  
Author(s):  
Y.M Issa ◽  
M.M Hassouna ◽  
F.M Abdel-Gawad ◽  
E.M Hussien
Keyword(s):  
Vinyl Chloride ◽  
Chloride Ion ◽  
Ion Selective Electrodes ◽  
Poly Vinyl Chloride

Anion recognition through amide-based dendritic molecule: A poly(vinyl chloride) based sensor for nitrate ion

Talanta ◽  
2011 ◽  
Vol 85 (2) ◽  
pp. 970-974 ◽  
Author(s):  
Vinod Kumar Gupta ◽  
Lok Pratap Singh ◽  
Sudeshna Chandra ◽  
Sunita Kumar ◽  
Rakesh Singh ◽  
...  
Keyword(s):  
Vinyl Chloride ◽  
Anion Recognition ◽  
Nitrate Ion ◽  
Poly Vinyl Chloride
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