Determination of calcium in unused lubricating oil blends by direct small-scale complexometric titration

The Analyst ◽  
1980 ◽  
Vol 105 (1254) ◽  
pp. 877 ◽  
Author(s):  
S. T. Holding ◽  
G. Williams
2020 ◽  
Vol 86 (10) ◽  
pp. 18-22
Author(s):  
K. N. Vdovin ◽  
K. G. Pivovarova ◽  
N. A. Feoktistov ◽  
T. B. Ponamareva

Zinc sulfate is the main component in the composition of the acidic zinc plating electrolyte. Deviation in the electrolyte composition from the optimum content leads to destabilization of the electrolysis process and deteriorate the quality of the resulting zinc coating. The proper quality of a zinc coating obtained by galvanic deposition can be ensured only with timely monitoring and adjustment of the electrolyte composition. A technique of X-ray fluorescence determination of zinc (in terms of zinc sulfate) in an acidic zinc plating electrolyte is proposed. The study was carried out using an ARL Quant’X energy dispersive spectrometer (Thermo Fisher Scientific, USA) with a semiconductor silicon-lithium detector. The features of the spectrometer design are presented. The optimal parameters of excitation and detection of zinc radiation were specified when the electrolyte sample was diluted 1:1000. The ZnKα1 line was used as an analytical line. The plotted calibration graph is linear, the correlation coefficient being 0.999234. The results of zinc determination according to the developed method were compared with the data of the reference method of complexometric titration to prove the reliability of the procedure. The results are characterized by good convergence and accuracy. The proposed method of X-ray fluorescence zinc determination in a zinc plating electrolyte equals complexometric titration in the limiting capabilities and even exceeds the latter in terms of the simplicity of sample preparation and rapidity. The developed method of X-ray fluorescence determination of zinc is implemented in analysis of the electrolyte used in the continuous galvanizing unit at «METSERVIS LLC».


1968 ◽  
Vol 239 (1) ◽  
pp. 33-36 ◽  
Author(s):  
K. S. Anand ◽  
Prabhu Dayal ◽  
O. N. Anand

2004 ◽  
Vol 17 (6) ◽  
pp. 749-765 ◽  
Author(s):  
M. Ryynänen ◽  
A.-M. Lampi ◽  
P. Salo-Väänänen ◽  
V. Ollilainen ◽  
V. Piironen

DISPERSION MODELS FOR EMISSIONS FROM AGRICULTURAL SOURCES G.-J. MEJER and K.-H. KRAUSE Institut fiir landtechnische Grundlagenforschung der Bundesforschungsanstalt fiir Landwirtschaft Summary The aim of dispersion models is the prediction of atmospheric dilution of pollutants in order to prevent or avoid nuisance. Established dispersion models, designed for the large scale of industrial air pol­ lution have to be modified to the small scale of agricultural pol­ lutions. An experimental setup is described to measure atmospheric dilution of tracer gas under agricultural conditions. The experimental results deliver the data base to identify the parameters of the models. For undisturbed airflow modified Gaussian models are applicable. For the consideration of obstacles more sophisticated models are necessary. 1. INTRODUCTION The aim of dispersion models is to develop reliable methods for calcu­ lating the atmospheric dilution of airborne pollutants under practical conditions. One application in agriculture is the determination of that distance, at which i.g. odouriferous pollutants of an animal farm are diluted in the atmosphere to a concentration below a certain threshold, in order to allow the farmer a profitable production and likewise to prevent odour nuisance from the neighbourhood. Another application is the prediction of the effectiveness of changes in the emission source configuration, in order to reduce the odour nuisance in the existent vicinity. That could help to avoid expensive misinvestments. In air pollution control it is useful! to subdivide this large problem into three main divisions /1/, fig. 1:


Buildings ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 363
Author(s):  
Liang Xiao ◽  
Kunhui Ye ◽  
Junhong Zhou ◽  
Xiaoting Ye ◽  
Ramadhani Said Tekka

Collusive bidding has been an insidious issue in the construction industry. Bidders initiate collusive networks of various sizes to win market shares. The popularity of collusive bidding networks affects market fairness and erodes the interests of market players. Although considerable research efforts were made to diagnose collusive bidding networks, there remains a gap in knowledge regarding the relationships bid riggers use to engage in the networks. Therefore, this study used the social network method, where two hundred sixteen collusion cases were collected from China to test these relationships. The results show that collusive bidding networks were characterized by sparseness, a small scale, a high concentration, and strong randomness. Three types of collusive bidding networks were also detected: contractual, spontaneous, and shadow. Furthermore, these collusive bidding networks had discrepancies regarding participants’ identities, forms of collusive bids, and the determination of bid winners. It was found that the proposed social network model of deliberating bid riggers’ relationships lays a solid foundation for the detection of collusive bidding in the construction sector.


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