An impurity compensated polarographic method for the determination of the gamma isomer in technical benzene hexachloride

The Analyst ◽  
1954 ◽  
Vol 79 (945) ◽  
pp. 735 ◽  
Author(s):  
J. Watt
1955 ◽  
Vol 4 (1) ◽  
pp. 30-34 ◽  
Author(s):  
TAKEJI NOTO ◽  
GAKU MATSUOKA

1965 ◽  
Vol 20 (4) ◽  
pp. 774-778 ◽  
Author(s):  
Domenic A. Maio ◽  
James R. Neville

A polarographic method was described in an earlier report which permits the accurate, rapid determination of oxygen content in small samples of blood. As with the Van Slyke technic, total oxygen capacity was formerly estimated by a separate determination of the oxygen content after complete saturation with oxygen of another portion of the blood sample. Further experience with the polarographic method has revealed the feasibility of estimating both content and capacity in a single blood sample. The capacity estimate is made possible by the polarographic observation of the quantity of potassium ferricyanide required to convert ferrohemoglobin to ferrihemoglobin. The measurement of oxygen content is performed, as previously described, by the polarographically determined increase in physically dissolved oxygen caused by the release of bound oxygen. By this means, one avoids sampling and random errors inherent in the use of two separate determinations. The method requires only a brief time for performance and ordinary technical proficiency. It is also simple in application. polarographic dropping mercury electrode; oxygen tension; digitonin; potassium ferricyanide; ferrohemoglobin; ferrihemoglobin Submitted on June 24, 1964


1950 ◽  
Vol 33 (4) ◽  
pp. 976-986
Author(s):  
L E Tufts ◽  
G W Darling ◽  
R H Kimball
Keyword(s):  

1965 ◽  
Vol 11 (4) ◽  
pp. 459-464 ◽  
Author(s):  
Gary D Christian

Abstract A polarographic method for the determination of as little as 1 µg. of gold in blood and serum samples is described. The relative error is 2.1%. After the sample is dry ashed at 550°, the gold is extracted into ether as the chloride, to separate it from interfering copper and iron. A polarogram of the gold sample is obtained in 2 M potassium hydroxide. The method should be applicable to the determination of gold in other biological samples containing interfering elements.


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