Reductive amination of aromatic aldehydes and ketones with nickel boride

Author(s):  
Ira Saxena ◽  
Ruli Borah ◽  
Jadab C. Sarma
Synthesis ◽  
2019 ◽  
Vol 51 (13) ◽  
pp. 2667-2677 ◽  
Author(s):  
Evgeniya Podyacheva ◽  
Oleg I. Afanasyev ◽  
Alexey A. Tsygankov ◽  
Maria Makarova ◽  
Denis Chusov

A comparative study of various widely used methods of reductive amination is reported. Specifically, such reducing agents as H2, Pd/C, hydride reagents [NaBH4, NaBH3CN, NaBH(OAc)3], and CO/Rh2(OAc)4 system were considered. For understanding the selectivity and activity of the reducing agents reviewed herein, different classes of starting materials were tested, including aliphatic and aromatic amines, as well as aliphatic and aromatic aldehydes and ketones. Most important advantages and drawbacks of the methods, such as selectivity of the target amine formation and toxicity of the reducing agents were compared. Methods were also considered from the viewpoint of green chemistry.


1968 ◽  
Vol 243 (4) ◽  
pp. 848-852
Author(s):  
H W Culp ◽  
R E McMahon

ChemInform ◽  
2008 ◽  
Vol 39 (5) ◽  
Author(s):  
Farajollah Mohanazadeh ◽  
Mehdi Forozani ◽  
Azam Taheri

ChemInform ◽  
2011 ◽  
Vol 42 (42) ◽  
pp. no-no
Author(s):  
Ming Zhang ◽  
Hongwei Yang ◽  
Yan Zhang ◽  
Chengjian Zhu ◽  
Wei Li ◽  
...  

Tetrahedron ◽  
2004 ◽  
Vol 60 (36) ◽  
pp. 7899-7906 ◽  
Author(s):  
Shinya Sato ◽  
Takeshi Sakamoto ◽  
Etsuko Miyazawa ◽  
Yasuo Kikugawa

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