An entry to half-sandwich complexes of first row transition metals (Ni, Co, Mn) containing the Kläui tripodal ligand, LOMe: synthesis and crystal structures of oligomeric, [LOMeM(μ-X)(L)]n (n = 2, 4), and monomeric complexes, LOMeM(L2)(X)

2000 ◽  
pp. 1123-1134 ◽  
Author(s):  
De-qiang Ma ◽  
Shiro Hikichi ◽  
Munetaka Akita ◽  
Yoshihiko Moro-oka
Keyword(s):  
Transition Metals ◽  
Crystal Structures ◽  
Sandwich Complexes ◽  
Tripodal Ligand ◽  
Half Sandwich

Synthesis and Crystal Structures of Dinuclear Trichloro(tetramethylcyclopentadienyl)titanium Complexes

2006 ◽  
Vol 71 (2) ◽  
pp. 164-178 ◽  
Author(s):  
Lenka Lukešová ◽  
Róbert Gyepes ◽  
Vojtech Varga ◽  
Jiří Pinkas ◽  
Michal Horáček ◽  
...  
Keyword(s):  
Diffraction Analysis ◽  
Crystal Structures ◽  
X Ray Diffraction ◽  
Titanium Complexes ◽  
Sandwich Complexes ◽  
Common Procedure ◽  
X Ray ◽  
Half Sandwich

Dinuclear half-sandwich complexes [{TiCl3(η5-C5Me4)}2SiMe2] (2) and [{TiCl3(η5-C5Me4SiMe2CH2)}2] (4) were prepared by synproportionation of ansa-titanocene dichlorides [TiCl2{(η5-C5Me4)2SiMe2}] (1) and [TiCl2(η5-C5Me4SiMe2CH2)2] (3), respectively, with TiCl4. Compound 3 was synthesized from 1,2-bis(chlorodimethylsilyl)ethane, 1,2,3,4-tetramethylcyclopentadienyllithium, and [TiCl3(thf)3] by a common procedure. Crystal structures of 2, 3, and 4 were determined by X-ray diffraction analysis.

Borato−Cyclopentadienyl Half-Sandwich Complexes. Crystal Structures of [NEt4][C5H5B(C6F5)3]·CH2Cl2and [NEt4]2[{C5H4B(C6F5)3}Zr(μ-Cl)Cl2]2

1998 ◽  
Vol 17 (18) ◽  
pp. 3829-3831 ◽  
Author(s):  
Simon J. Lancaster ◽  
Mark Thornton-Pett ◽  
David M. Dawson ◽  
Manfred Bochmann
Keyword(s):  
Crystal Structures ◽  
Sandwich Complexes ◽  
Half Sandwich

scholarly journals Neutral all metal aromatic half-sandwich complexes between alkaline earth and transition metals: an ab initio exploration

2021 ◽  
Author(s):  
Amlan Jyoti Kalita ◽  
Prem Prakash Sahu ◽  
Ritam Raj Borah ◽  
Shahnaz Sultana Rohman ◽  
Chayanika Kashyap ◽  
...  
Keyword(s):  
Transition Metals ◽  
Ab Initio ◽  
Alkaline Earth ◽  
Sandwich Complexes ◽  
Half Sandwich

Half-sandwich complexes of Group 9 metals with N,Nʹ-ligands for CF3-carbenoid alkylation of N-(pyrimidin-2-yl)indole

2021 ◽  
pp. 121899
Author(s):  
Sofya S. Kuvshinova ◽  
Yulia V. Nelyubina ◽  
Vladimir A. Larionov ◽  
Daria V. Vorobyeva ◽  
Sergey N. Osipov ◽  
...  
Keyword(s):  
Sandwich Complexes ◽  
Half Sandwich

scholarly journals Uranium(iv) cyclobutadienyl sandwich compounds: synthesis, structure and chemical bonding

2020 ◽  
Vol 56 (6) ◽  
pp. 944-947 ◽  
Author(s):  
Nikolaos Tsoureas ◽  
Akseli Mansikkamäki ◽  
Richard A. Layfield
Keyword(s):  
Chemical Bonding ◽  
Molecular Structures ◽  
Sandwich Complexes ◽  
Sandwich Complex ◽  
Sandwich Compounds ◽  
Bonding Properties ◽  
Half Sandwich

The synthesis, molecular structures and bonding properties of two uranium(iv) cyclobutadienyl half-sandwich complexes and a doubly activated cyclobutadienyl sandwich complex are described.

scholarly journals Intermolecular interaction energies in transition metal coordination compounds

CrystEngComm ◽  
2015 ◽  
Vol 17 (48) ◽  
pp. 9300-9310 ◽  
Author(s):  
Andrew G. P. Maloney ◽  
Peter A. Wood ◽  
Simon Parsons
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Crystal Structures ◽  
Intermolecular Interaction ◽  
Coordination Compounds ◽  
Metal Coordination ◽  
Interaction Energies

The PIXEL method has been parameterised and validated for transition metals, extending its applicability from ~40% to ~85% of all published crystal structures.

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