Comparison of biota sample pretreatments for arsenic speciation with coupled HPLC-HG-ICP-MS

The Analyst ◽  
2000 ◽  
Vol 125 (3) ◽  
pp. 401-407 ◽  
Author(s):  
J. L. Gómez-Ariza ◽  
D. Sánchez-Rodas ◽  
I. Giráldez ◽  
E. Morales
Keyword(s):  
Arsenic Speciation ◽  
Icp Ms ◽  
Biota Sample

Ionic imprinted polymer – Vortex-assisted dispersive micro-solid phase extraction for inorganic arsenic speciation in rice by HPLC-ICP-MS

Talanta ◽  
2020 ◽  
Vol 220 ◽  
pp. 121418
Author(s):  
Kamal K. Jinadasa ◽  
Elena Peña-Vázquez ◽  
Pilar Bermejo-Barrera ◽  
Antonio Moreda-Piñeiro
Keyword(s):  
Solid Phase Extraction ◽  
Solid Phase ◽  
Arsenic Speciation ◽  
Inorganic Arsenic ◽  
Phase Extraction ◽  
Imprinted Polymer ◽  
Icp Ms

scholarly journals A multinebulization technique for the determination of trace metals in a marine biota sample by on-line isotope dilution inductively coupled plasma mass spectrometry (OID-ICP-MS)

2020 ◽  
Vol 35 (11) ◽  
pp. 2509-2516 ◽  
Author(s):  
Miriam García ◽  
Miguel Ángel Aguirre ◽  
Emilia Vassileva ◽  
Antonio Canals
Keyword(s):  
Mass Spectrometry ◽  
Trace Metals ◽  
Inductively Coupled Plasma ◽  
Marine Biota ◽  
Inductively Coupled ◽  
Icp Ms ◽  
Biota Sample ◽  
Plasma Mass Spectrometry ◽  
On Line

The efficient mixing between the sample and the spike solutions takes place at the inner cavity of the multinebulizer tip.

Arsenic speciation in Chinese seaweeds using HPLC-ICP-MS and HPLC-ES-MS

The Analyst ◽  
2002 ◽  
Vol 127 (5) ◽  
pp. 634-640 ◽  
Author(s):  
Marijn Van Hulle ◽  
Chao Zhang ◽  
Xinrong Zhang ◽  
Rita Cornelis
Keyword(s):  
Arsenic Speciation ◽  
Icp Ms

scholarly journals Routine determination of inorganic arsenic speciation in precipitates from acid mine drainage using orthophosphoric acid extraction followed by HPLC-ICP-MS

2016 ◽  
Vol 8 (40) ◽  
pp. 7420-7426 ◽  
Author(s):  
Resongles E. ◽  
Le Pape P. ◽  
Fernandez-Rojo L. ◽  
Morin G. ◽  
Delpoux S. ◽  
...  
Keyword(s):  
Acid Mine Drainage ◽  
Orthophosphoric Acid ◽  
Mine Drainage ◽  
Arsenic Speciation ◽  
Inorganic Arsenic ◽  
Acid Extraction ◽  
Acid Mine ◽  
Routine Measurement ◽  
Icp Ms

As(iii)/As(v) ratio determined from orthophosphoric acid extraction/HPLC-ICP-MS matched XANES results, allowing routine measurement of As oxidation state in acid mine drainage precipitates.

Development and application of a HPIC-ICP-MS method for the redox arsenic speciation in river sediment pore waters

2015 ◽  
Vol 30 (7) ◽  
pp. 1562-1570 ◽  
Author(s):  
Josselin Gorny ◽  
David Dumoulin ◽  
Ludovic Lesven ◽  
Catherine Noiriel ◽  
Benoît Madé ◽  
...  
Keyword(s):  
River Sediment ◽  
Arsenic Speciation ◽  
Pore Waters ◽  
Icp Ms ◽  
Pre Treatment ◽  
Treatment Step ◽  
Redox Speciation

A HPIC-ICP-MS method has been developed to directly determine As redox speciation in filtered sediment pore waters without pre-treatment step.

scholarly journals Clinimetallomics: Arsenic Speciation in Urine from Patients With Arsenism by HPLC-ICP-MS

2021 ◽  
Vol 42 (5) ◽  
Author(s):  
Huiling Li
Keyword(s):  
Arsenic Speciation ◽  
Speciation Analysis ◽  
Arsenic Species ◽  
The Body ◽  
Urine Samples ◽  
Clinical Samples ◽  
Total Arsenic ◽  
Arsenic Poisoning ◽  
Icp Ms

Clinimetallomics is proposed as a branch of metallomics that focuses on the study of the metallome in clinical samples of urine, blood, and tissues. As the clinical diagnosis of arsenic poisoning is mainly based on the concentration of total arsenic in urine, the toxicity of arsenic varies greatly in different speciation. Analysis of arsenic speciation with excessive total arsenic in urine can provide a basis for precise treatment. It can also be used to understand the fate of arsenic in the body of patients with arsenic poisoning after treatment with sodium dimercaptopropane sulfonate. In this study, a HPLC-ICP-MS method was established for the determination of arsenic species in urine samples from patients diagnosed with arsenism. Use the established method to detect urine samples, which can be directly assayed after simple sample dilution with 20 mmol/L EDTA-2Na. With the concentration of arsenic speciation in the range of 1.0~100.0 ng/mL, the linear correlation coefficient was higher than 0.99996. The recoveries were between 92.4% and 109.0%. The precision of the concentration and retention time (n = 3) were less than 3.0% and 0.3%, respectively, and the detection limit was between 1.42 ng/mL and 1.86 ng/mL. This method can be applied to arsenic speciation in the urine of healthy people, in patients treated for arsenic poisoning, and in patients diagnosed with arsenism.

scholarly journals Arsenic Content, Speciation, and Distribution in Wild Cordyceps sinensis

2021 ◽  
Vol 2021 ◽  
pp. 1-9
Author(s):  
Yuancan Xiao ◽  
Cen Li ◽  
Wei Xu ◽  
Yuzhi Du ◽  
Ming Zhang ◽  
...  
Keyword(s):  
Quality Control ◽  
Imaging Techniques ◽  
Arsenic Speciation ◽  
Chemical Form ◽  
Cordyceps Sinensis ◽  
Arsenic Content ◽  
Chemical Forms ◽  
Total Arsenic ◽  
Icp Ms ◽  
Source Studies

The excessive arsenic content in wild Cordyceps sinensis has caused great concerns on human health. The toxicity of arsenic depends on its concentration, chemical form, and valence. The source studies of arsenic in C. sinensis are essential for safety evolution and quality control. We used ICP-MS and HPLC-ICP-MS methods to determine the total arsenic amount and the arsenic speciation. Synchrotron-based XANES and micro-XRF imaging techniques were used to characterize arsenic valence and distribution. The total arsenic amount range in wild C. sinensis samples was 5.77–13.20 μg/g with an average of 8.85 ± 2.5 μg/g. As(III) and As(V) were the main species in wild C. sinensis samples. The iAs only accounts for 4.47–11.42% of the extracted arsenic. Trivalent and pentavalent forms were the dominant chemical forms of arsenic. Besides, we found that arsenic was accumulated at the digestive tract of the host larva.

Arsenic Speciation in Water and Human Urine by HPLC–ICP-MS and HPLC–MO–HG-AAS

1998 ◽  
Vol 59 (1) ◽  
pp. 89-99 ◽  
Author(s):  
Mariella Moldovan ◽  
M.Milagros Gómez ◽  
M.Antonia Palacios ◽  
Carmen Cámara
Keyword(s):  
Human Urine ◽  
Arsenic Speciation ◽  
Icp Ms
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