Syntheses, crystal structures and non-linear optical responses of two new heteroselenometallic cluster compounds containing dithiocarbamate ligands

2000 ◽  
pp. 605-610 ◽  
Author(s):  
Qian-Feng Zhang ◽  
Mo-Tai Bao ◽  
Mao-Chun Hong ◽  
Rong Cao ◽  
Ying-Lin Song ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Cluster Compounds ◽  
Optical Responses ◽  
Non Linear ◽  
Linear Optical

Synthesis, crystal structures and non-linear optical properties of cluster compounds [MoAu2S4(PAr3)2] and [WAu2S4(PAr3)2] (Ar=p-MeOC6H4)

2003 ◽  
Vol 342 ◽  
pp. 151-157 ◽  
Author(s):  
Mei-Hua Ma ◽  
He-Gen Zheng ◽  
Wei-Lian Tan ◽  
Jian-Liang Zhou ◽  
S.Shanmuga Sundara Raj ◽  
...  
Keyword(s):  
Optical Properties ◽  
Crystal Structures ◽  
Cluster Compounds ◽  
Non Linear ◽  
Linear Optical Properties ◽  
Linear Optical

Designing a new class of excess electron compounds with unique electronic structures and extremely large non-linear optical responses

2020 ◽  
Vol 44 (16) ◽  
pp. 6411-6419
Author(s):  
Xiang-Hui Li ◽  
Li Zhang ◽  
Xiao-Ling Zhang ◽  
Bi-Lian Ni ◽  
Chun-Yan Li ◽  
...  
Keyword(s):  
Electronic Structures ◽  
Excess Electron ◽  
New Class ◽  
Optical Responses ◽  
Non Linear ◽  
Linear Optical ◽  
Electron Compounds

New Ca+-1-M′− (M′ = Li, Na, and K) compounds with typical alkalide features and electride-like characteristics have been obtained.

Synthesis and Characterization of Highly Conjugated Unsymmetrically Substituted Phthalocyanines

1997 ◽  
Vol 01 (03) ◽  
pp. 221-226 ◽  
Author(s):  
GEMA DE LA TORRE ◽  
TOMÁS TORRES
Keyword(s):  
Spectroscopic Properties ◽  
Second Order ◽  
Synthesis And Characterization ◽  
Optical Responses ◽  
Delocalized Electron ◽  
Non Linear ◽  
Linear Optical ◽  
High Degree

Unsymmetric push-pull phthalocyanines with a high degree of conjugation achieved by introducing π-delocalized electron substituents were synthesized by statistical condensation of two different diiminoisoindolines. The characterization and spectroscopic properties of these push-pull phthalocyanines are described. These compounds are targeted for the study of their second-order non-linear optical responses.

scholarly journals Computational Study on Non-linear Optical and Absorption Properties of Benzothiazole based Dyes: Tunable Electron-Withdrawing Strength and Reverse Polarity

2017 ◽  
Vol 15 (1) ◽  
pp. 139-146 ◽  
Author(s):  
Muhammad Ramzan Saeed Ashraf Janjua
Keyword(s):  
Charge Transfer ◽  
Absorption Spectra ◽  
Organic Dyes ◽  
Computational Study ◽  
Energy Charge ◽  
Reverse Polarity ◽  
Optical Responses ◽  
Non Linear ◽  
Electronic Characteristic ◽  
Linear Optical

AbstractVarious organic dyes possessing characteristic D-π-A-A configuration have been designed in this article. The analysis of the relation between polarity of charge transfer and the unsymmetrical nature of the benzothiazole group has been studied. The absorption spectra, electronic characteristic properties and non-linear optical responses were simulated using a quantum chemical approach. The results have indicated that the systems show higher polarizability (α) and hyperpolarizability (β) with commonly used polarity in comparison to the reverse polarity. A red-shifted absorption spectra were observed with systems having common polarities. This study illustrates the rule to design non-linear optical material with low energy charge transfer excited states and high value of oscillation.

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