Photoswitchable trinuclear transition-metal complexes. Intramolecular triplet–triplet energy transfer from fac-(diimine)ReI(CO)3 chromophores to a stilbene-like bridging ligand

2000 ◽  
pp. 201-202 ◽  
Author(s):  
Shih-Sheng Sun ◽  
Elizabeth Robson ◽  
Nicholas Dunwoody ◽  
Alexsandra S. Silva ◽  
Alistair J. Lees ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Triplet Energy ◽  
Bridging Ligand ◽  
Triplet Energy Transfer

Energy transfer from luminescent transition metal complexes to oxygen

1977 ◽  
Vol 99 (11) ◽  
pp. 3547-3551 ◽  
Author(s):  
J. N. Demas ◽  
E. W. Harris ◽  
R. P. McBride
Keyword(s):  
Energy Transfer ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes

Optisch aktive Übergangsmetall-Komplexe, 97 [1] C5H5Fe(CO)(COMe)-Derivate von Glyphos und Diop / Optically Active Transition Metal Complexes, 97 [1] C5H5Fe(CO)(COMe) Derivatives of Glyphos and Diop

1990 ◽  
Vol 45 (5) ◽  
pp. 579-586 ◽  
Author(s):  
Henri Brunner ◽  
Rudolf Eder
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Column Chromatography ◽  
Optically Active ◽  
Dinuclear Complexes ◽  
Dissociative Mechanism ◽  
Bridging Ligand ◽  
Active Transition ◽  
Derivatives Of

The reaction of CpFe(CO)2Me with (+)-Glyphos and (–)-Diop yields the monosubstitution products 1 and 2, which consist of pairs of diastereomers, differing only in the Fe configuration. With (–)-Diop, additionally dinuclear complexes are formed in which Diop acts as a bridging ligand. The diastereomers can be separated by column chromatography. At higher temperatures the complexes epimerize in solution with respect to the Fe configuration. The formation of free phosphine and CpFe(CO)2Me indicates a dissociative mechanism.

Vibrational energy transfer dynamics in ruthenium polypyridine transition metal complexes

2015 ◽  
Vol 17 (3) ◽  
pp. 1688-1696 ◽  
Author(s):  
Marina Fedoseeva ◽  
Milan Delor ◽  
Simon C. Parker ◽  
Igor V. Sazanovich ◽  
Michael Towrie ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Energy Transfer ◽  
Solar Cell ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Vibrational Energy ◽  
Vibrational Energy Transfer ◽  
Energy Propagation ◽  
Ruthenium Polypyridine

Understanding vibrational energy propagation pathways during and following electron transfer in transition metal complexes, which are of interest for solar cell applications, can provide new insights on the interplay between electronic and vibrational movement within the molecule.

Nitrochloranilic acid: a novel asymmetrically substituted quinoid bridging ligand for design of coordination polymers

CrystEngComm ◽  
2021 ◽  
Vol 23 (11) ◽  
pp. 2304-2315
Author(s):  
Valentina Milašinović ◽  
Marijana Jurić ◽  
Krešimir Molčanov
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Coordination Polymers ◽  
Bridging Ligand ◽  
Alkali Salts

A series of alkali salts and transition metal complexes of a novel asymmetrically substituted quinoid ligand, 3-nitro-6-chloro-2,5-dihydroxyquinone (nitrochloranilic acid, H2NCA) was prepared and characterised.

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