Tetrabutylammonium Peroxydisulfate in Organic Synthesis. Part 8. An Efficient and Convenient Nickel-catalyzed Oxidation of Primary Amines to Nitriles with Tetrabutylammonium Peroxydisulfate

1999 ◽  
pp. 726-727 ◽  
Author(s):  
Fen-Er Chen ◽  
Zuo-Zhong Peng ◽  
Han Fu ◽  
Ji-Dong Liu ◽  
Lan-Ying Shao
Keyword(s):  
Organic Synthesis ◽  
Primary Amines ◽  
Catalyzed Oxidation

scholarly journals Tetrabutylammonium Peroxydisulfate in Organic Synthesis. Part 8.1 An Efficient and Convenient Nickel-catalyzed Oxidation of Primary Amines to Nitriles with Tetrabutylammonium Peroxydisulfate

1999 ◽  
Vol 23 (12) ◽  
pp. 726-727
Author(s):  
Fen-Er Chen ◽  
Zuo-Zhong Peng ◽  
Han Fu ◽  
Ji-Dong Liu ◽  
Lan-Ying Shao
Keyword(s):  
Organic Synthesis ◽  
Primary Amines ◽  
Copper Formate ◽  
Nickel Copper ◽  
Aqueous Conditions ◽  
Catalyzed Oxidation

A series of primary amines are oxidized to the corresponding nitriles in excellent yields with tetrabutylammonium peroxydisulfate catalyzed by nickel copper formate under basic aqueous conditions.

Enzymes in organic synthesis. 32. Stereospecific horse liver alcohol dehydrogenase-catalyzed oxidations of exo- and endo-oxabicyclic meso diols

1984 ◽  
Vol 62 (11) ◽  
pp. 2578-2582 ◽  
Author(s):  
J. Bryan Jones ◽  
Christopher J. Francis
Keyword(s):  
Alcohol Dehydrogenase ◽  
Organic Synthesis ◽  
Horse Liver Alcohol Dehydrogenase ◽  
Preparative Scale ◽  
Enantiomerically Pure ◽  
Liver Alcohol Dehydrogenase ◽  
Horse Liver ◽  
One Step ◽  
Catalyzed Oxidation ◽  
Enzymes In Organic Synthesis

Preparative-scale horse liver alcohol dehydrogenase-catalyzed oxidation of mesoexo- and endo-7-oxabicyclo[2.2.1]heptane diols provides a direct one-step route to enantiomerically pure chiral γ-lactones of the oxabicyclic series.

ChemInform Abstract: Ruthenium-Catalyzed Oxidation for Organic Synthesis

ChemInform ◽  
2011 ◽  
Vol 42 (44) ◽  
pp. no-no
Author(s):  
Shun-ichi Murahashi ◽  
Naruyoshi Komiya
Keyword(s):  
Organic Synthesis ◽  
Catalyzed Oxidation

Enzymes in organic synthesis. 23. Effects of organic solvents on horse liver alcohol dehydrogenase-catalyzed oxidation

1982 ◽  
Vol 60 (8) ◽  
pp. 1030-1033 ◽  
Author(s):  
J. Bryan Jones ◽  
Harold M. Schwartz
Keyword(s):  
Alcohol Dehydrogenase ◽  
Organic Synthesis ◽  
Organic Solvents ◽  
Butyl Alcohol ◽  
Horse Liver Alcohol Dehydrogenase ◽  
Liver Alcohol Dehydrogenase ◽  
Tert Butyl Alcohol ◽  
Horse Liver ◽  
Catalyzed Oxidation ◽  
Enzymes In Organic Synthesis

The effects have been evaluated of up to 50% (v/v) of methanol, tert-butyl alcohol, dimethylsulfoxide, sulfolane, acetonitrile, dimethylformamide, N-methyl-2-pyrrolidone, hexamethylphosphoramide, acetone, 2-butanone, tetrahydrofuran, dimethoxyethane, diglyme, and dioxane on horse liver alcohol dehydrogenase (HLADH)-catalyzed oxidation of the representative alcohol substrate cyclohexanol. With the exception of dimethylsulfoxide and dimethylformamide, all solvents tested are suitable for use as cosolvents with HLADH in the oxidative and reductive directions.

Mesoporous carbon derived from vitamin B12: a high-performance bifunctional catalyst for imine formation

2016 ◽  
Vol 52 (3) ◽  
pp. 481-484 ◽  
Author(s):  
Bo Chen ◽  
Sensen Shang ◽  
Lianyue Wang ◽  
Yi Zhang ◽  
Shuang Gao
Keyword(s):  
Vitamin B12 ◽  
Organic Synthesis ◽  
Mesoporous Carbon ◽  
High Performance ◽  
Cross Coupling ◽  
Bifunctional Catalyst ◽  
The Self ◽  
Primary Amines ◽  
Vitamin B ◽  
First Time

Mesoporous carbon derived from natural vitamin B12 is applied for the first time in organic synthesis and exhibits exceptionally high dual activity for imine formation via the cross-coupling of alcohols with amines and the self-coupling of primary amines.

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